Hollow Silica Particles: A Novel Strategy for Cost Reduction

Thermal insulation materials are highly sought after for applications such as building envelopes, refrigerators, cryogenic fuel storage chambers, and water supply piping. However, current insulation materials either do not provide sufficient insulation or are costly. A new class of insulation materials, hollow silica particles, has attracted tremendous attention due to its potential to provide a very high degree of thermal insulation. However, current synthesis strategies provide hollow silica particles at very low yields and at high cost, thus, making the particles unsuitable for real-world applications. In the present work, a synthesis process that produces hollow silica particles at very high yields and at a lower cost is presented. The effect of an infrared heat absorber, carbon black, on the thermal conductivity of hollow silica particles is also investigated and it is inferred that a carbon black–hollow silica particle mixture can be a better insulating material than hollow silica particles alone.

[1]  P. Alves,et al.  Progress in silica aerogel-containing materials for buildings’ thermal insulation , 2021 .

[2]  Phansiri Suktha,et al.  Graphene Aerogels with Ultrahigh Pore Volume for Organic Dye Adsorption and High-Energy Lithium Batteries , 2020 .

[3]  Donald Petit,et al.  Transparent thermal insulation silica aerogels , 2020, Nanoscale advances.

[4]  D. Hun,et al.  Low cost and scalable method for modifying surfaces of hollow particles from hydrophilic to hydrophobic , 2020, RSC advances.

[5]  A. Bonnin,et al.  Additive manufacturing of silica aerogels , 2020, Nature.

[6]  G. Polizos,et al.  Hollow Silica Particles: Recent Progress and Future Perspectives , 2020, Nanomaterials.

[7]  Liangbing Hu,et al.  Super Elastic and Thermally Insulating Carbon Aerogel: Go Tubular Like Polar Bear Hair , 2019, Matter.

[8]  Siyu Wu,et al.  Hollow‐Structured Materials for Thermal Insulation , 2018, Advanced materials.

[9]  Jaime A. Mesa,et al.  Cellulose Aerogels for Thermal Insulation in Buildings: Trends and Challenges , 2018, Coatings.

[10]  Pramod V. Badyankal,et al.  Thermal Properties Characterization of Glass Fiber Hybrid Polymer Composite Materials , 2018 .

[11]  Q. Meng,et al.  Synthesis of Hollow Silica Particles Using Acid Dissolvable Resorcinol-Formaldehyde Resin Particles as Template , 2018, ChemistrySelect.

[12]  Gustav Nyström,et al.  Biopolymer Aerogels and Foams: Chemistry, Properties, and Applications. , 2018, Angewandte Chemie.

[13]  Yu-Zhong Wang,et al.  Cellulose Aerogels: Synthesis, Applications, and Prospects , 2018, Polymers.

[14]  L. Bergström,et al.  Fire-Retardant and Thermally Insulating Phenolic-Silica Aerogels. , 2018, Angewandte Chemie.

[15]  M. Fuji,et al.  Synthesis of ultra-small hollow silica nanoparticles using the prepared amorphous calcium carbonate in one-pot process , 2018 .

[16]  L. Yu,et al.  Ultralight Graphene/Carbon Nanotubes Aerogels with Compressibility and Oil Absorption Properties , 2018, Materials.

[17]  Yong Yi,et al.  Simulation and Analysis of Mechanical Properties of Silica Aerogels: From Rationalization to Prediction , 2018, Materials.

[18]  Hongyi Gao,et al.  Shape‐Stabilized Phase Change Materials Based on Stearic Acid and Mesoporous Hollow SiO2 Microspheres (SA/SiO2) for Thermal Energy Storage , 2017 .

[19]  Jose C. F. Pereira,et al.  A methodology for thermal analysis of complex integrated systems: Application to a micro-CHP plant , 2017 .

[20]  Wei Pan,et al.  Hollow Mesoporous Silica Nanoparticles with Tunable Structures for Controlled Drug Delivery. , 2017, ACS applied materials & interfaces.

[21]  A. Chauhan,et al.  Influence of carbon fillers on the thermal conductivity of Poly (methyl methacrylate)/carbon composites , 2016 .

[22]  Xi Cao,et al.  Hollow Silica Spheres Embedded in a Porous Carbon Matrix and Its Superior Performance as the Anode for Lithium‐Ion Batteries , 2016 .

[23]  W. Stark,et al.  Hollow Silica as an Optically Transparent and Thermally Insulating Polymer Additive. , 2016, Langmuir : the ACS journal of surfaces and colloids.

[24]  Young‐Sang Cho Fabrication of Hollow or Macroporous Silica Particles by Spray Drying of Colloidal Dispersion , 2016 .

[25]  S. Bai,et al.  Synergic enhancement of thermal properties of polymer composites by graphene foam and carbon black , 2016 .

[26]  Synthesis and Characterization of Hollow Mesoporous Silica Spheres Using Negative-Charged Polystyrene Particles as Templates , 2016, Journal of Inorganic and Organometallic Polymers and Materials.

[27]  Bijan Adl-Zarrabi,et al.  Assessing the Thermal Performance of District Heating Twin Pipes with Vacuum Insulation Panels , 2015 .

[28]  Haijiao Zhang,et al.  A soft-hard template approach towards hollow mesoporous silica nanoparticles with rough surfaces for controlled drug delivery and protein adsorption. , 2015, Journal of materials chemistry. B.

[29]  F. Asdrubali,et al.  A review of unconventional sustainable building insulation materials , 2015 .

[30]  Markus Antonietti,et al.  Thermally insulating and fire-retardant lightweight anisotropic foams based on nanocellulose and graphene oxide. , 2015, Nature nanotechnology.

[31]  Chifei Wu,et al.  Thermal Conductivity and Mechanical Properties of Carbon Black Filled Silicone Rubber , 2014 .

[32]  P. Thapliyal,et al.  Aerogels as Promising Thermal Insulating Materials: An Overview , 2014 .

[33]  M. Sasidharan,et al.  Core-shell-corona polymeric micelles as a versatile template for synthesis of inorganic hollow nanospheres. , 2014, Accounts of chemical research.

[34]  P. Datskos,et al.  Synthesis of segmented silica rods by regulation of the growth temperature. , 2014, Angewandte Chemie.

[35]  Jens Krause,et al.  Polyurethanes: versatile materials and sustainable problem solvers for today's challenges. , 2013, Angewandte Chemie.

[36]  Xiao-dong Wang,et al.  Optical and radiative properties of infrared opacifier particles loaded in silica aerogels for high temperature thermal insulation , 2013 .

[37]  Zhaoqun Wang,et al.  One-step synthesis of silica hollow particles in a W/O inverse emulsion , 2013, Colloid and Polymer Science.

[38]  Arild Gustavsen,et al.  Synthesis of Hollow Silica Nanospheres by Sacrificial Polystyrene Templates for Thermal Insulation Applications , 2013 .

[39]  Arild Gustavsen,et al.  Monodisperse hollow silica nanospheres for nano insulation materials: synthesis, characterization, and life cycle assessment. , 2013, ACS applied materials & interfaces.

[40]  P. Xue,et al.  A facile two-step etching method to fabricate porous hollow silica particles. , 2012, Journal of colloid and interface science.

[41]  Hideo Watanabe,et al.  Shape-controlled hollow silica nanoparticles synthesized by an inorganic particle template method , 2012 .

[42]  D. Akins,et al.  Synthesis of hollow ellipsoidal silica nanostructures using a wet-chemical etching approach. , 2012, Journal of colloid and interface science.

[43]  K. Okuyama,et al.  Mesopore-free hollow silica particles with controllable diameter and shell thickness via additive-free synthesis. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[44]  L. Gang,et al.  Composite thin film of silica hollow spheres and waterborne polyurethane: Excellent thermal insulation and light transmission performances , 2012 .

[45]  Xiao-feng Wu,et al.  Thermal conductivity of powder silica hollow spheres , 2011 .

[46]  Bjørn Petter Jelle,et al.  Traditional, state-of-the-art and future thermal building insulation materials and solutions Prope , 2011 .

[47]  P. Blower,et al.  Synthesis of porous hollow silica nanostructures using hydroxyapatite nanoparticle templates. , 2011, Chemical communications.

[48]  H. Sakai,et al.  On the stability of surfactant-free water-in-oil emulsions and synthesis of hollow SiO2 nanospheres , 2010 .

[49]  Kunn Hadinoto,et al.  Spray drying formulation of hollow spherical aggregates of silica nanoparticles by experimental design , 2010 .

[50]  Hyung‐Ho Park,et al.  Silica aerogel: synthesis and applications , 2010 .

[51]  J. Bae,et al.  Fabrication of hollow silica particles using copolymeric spheres prepared in supercritical carbon dioxide , 2009 .

[52]  Y. Konishi,et al.  Fabrication of silica hollow particles using Escherichia coli as a template , 2008 .

[53]  Xiao-feng Wu,et al.  Raspberry-like silica hollow spheres: Hierarchical structures by dual latex-surfactant templating route , 2007 .

[54]  M. Fuji,et al.  Surface properties of nanosize hollow silica particles on the molecular level , 2007 .

[55]  J. Gore,et al.  A Review of Heat Transfer Issues in Hydrogen Storage Technologies , 2005 .

[56]  Jianfeng Chen,et al.  A novel pathway for synthesis of silica hollow spheres with mesostructured walls , 2004 .

[57]  A. Pierre,et al.  Chemistry of aerogels and their applications. , 2002, Chemical reviews.

[58]  J. Fricke,et al.  Thermal conductivity of silica aerogel powders at temperatures from 10 to 275 K , 1995 .

[59]  A. Hunt,et al.  Thermal characterization of carbon-opacified silica aerogels☆ , 1995 .

[60]  X. Lu,et al.  Optimization of monolithic silica aerogel insulants , 1992 .