Quantum Hall edge channels at integer filling factor provide a unique test bench to understand the decoherence and relaxation of single-electron excitations in a ballistic quantum conductor. In this Letter, we obtain a full visualization of the decoherence scenario of energy (Landau)- and time (Levitov)-resolved single-electron excitations at filling factor ν = 2. We show that the Landau excitation exhibits a fast relaxation followed by spin-charge separation whereas the Levitov excitation only experiences spin-charge separation. We finally suggest to use Hong-Ou-Mandel-type experiments to probe specific signatures of these different scenarios.