An Internet-of-Things Enabled Smart Sensing System for Nitrate Monitoring

Monitoring the nitrate concentration in the field is an excellent ability for a water-monitoring study. We report an interdigital FR4-based capacitive sensor, which is characterized for nitrate concentration. The concentration range of nitrate is 0–40 ppm (mg/L). Different unknown samples were measured and validated with standard UV-Spectrometry. A smart sensing node has been developed which can collect water from a lake, stream, or river, measure the instantaneous nitrate concentration, and transfer the data through the gateway to a user-defined cloud server. The system is completely autonomous and solar powered, robust, and trialed in the field successfully. A simple moving-average algorithm is used to smooth the collected data in the cloud side. The LoRa protocol and WiFi protocol are compared in terms of power consumption. The proposed system is trialed in the field continuously and the result validated with standard UV-Spectrometry. The developed smart system can be easily deployable and friendly to use, and offers new possibilities for both spatial and temporal analysis for nitrate concentration.

[1]  M. Gartia,et al.  The microelectronic wireless nitrate sensor network for environmental water monitoring. , 2012, Journal of environmental monitoring : JEM.

[2]  Gang Zhao,et al.  Wireless Sensor Networks for Industrial Process Monitoring and Control: A Survey , 2011, Netw. Protoc. Algorithms.

[3]  Stephen C. Riser,et al.  Chemical Sensor Networks for the Aquatic Environment , 2007 .

[4]  Luiz Affonso Guedes,et al.  Reliability and Availability Evaluation of Wireless Sensor Networks for Industrial Applications , 2012, Sensors.

[5]  André Weber,et al.  Electrochemical impedance spectroscopy , 2010 .

[6]  J B Kaneene,et al.  The effects of nitrate, nitrite and N-nitroso compounds on human health: a review. , 1993, Veterinary and human toxicology.

[7]  Peng Jiang,et al.  Design of a Water Environment Monitoring System Based on Wireless Sensor Networks , 2009, Sensors.

[8]  C L Walters,et al.  The exposure to humans to nitrite. , 1980, Oncology.

[9]  Subhas Mukhopadhyay,et al.  Highly selective ion imprinted polymer based interdigital sensor for nitrite detection , 2016, 2016 10th International Conference on Sensing Technology (ICST).

[10]  Peter F Swann Environmental Carcinogenesis: Contributions of Basic Research , 1977 .

[11]  Chinthaka P. Gooneratne,et al.  A low-cost sensing system for quality monitoring of dairy products , 2006, IEEE Transactions on Instrumentation and Measurement.

[12]  Subhas Mukhopadhyay,et al.  A Temperature Compensated Smart Nitrate-Sensor for Agricultural Industry , 2017, IEEE Transactions on Industrial Electronics.

[13]  Lixing Ding,et al.  Study on precision agriculture monitoring framework based on WSN , 2008, 2008 2nd International Conference on Anti-counterfeiting, Security and Identification.

[14]  B. Sattelmacher Addiscott, T. M., A. P. Whitmore and D. S. Powlson: Farming, Fertilizers and the Nitrate Problem. CAB International, 1991; 176 Seiten. Paperback, £ 12.95. ISBN 0 85198 658 7 , 1993 .

[15]  Xianbin Wang,et al.  Applications of Wireless Sensor Networks in Marine Environment Monitoring: A Survey , 2014, Sensors.

[16]  H. Di,et al.  Nitrate leaching losses and pasture yields as affected by different rates of animal urine nitrogen returns and application of a nitrification inhibitor—a lysimeter study , 2007, Nutrient Cycling in Agroecosystems.

[17]  Petar Solic,et al.  LoRaWAN — A low power WAN protocol for Internet of Things: A review and opportunities , 2017, 2017 2nd International Multidisciplinary Conference on Computer and Energy Science (SpliTech).

[18]  Subhas Chandra Mukhopadhyay,et al.  A temperature-compensated graphene sensor for nitrate monitoring in real-time application , 2018 .

[19]  Patrick Armengaud,et al.  From the soil to the seeds: the long journey of nitrate in plants. , 2011, Journal of experimental botany.

[20]  R. Compton,et al.  Detection and determination of nitrate and nitrite: a review. , 2001, Talanta.

[21]  G. Ellis,et al.  Nitrite and nitrate analyses: a clinical biochemistry perspective. , 1998, Clinical biochemistry.

[22]  Özgür Ulusoy,et al.  A framework for use of wireless sensor networks in forest fire detection and monitoring , 2012, Comput. Environ. Urban Syst..

[23]  Chung-Ta King,et al.  Design of a Multifunctional Wireless Sensor for In-Situ Monitoring of Debris Flows , 2010, IEEE Transactions on Instrumentation and Measurement.

[24]  Kishore Sundara-Rajan,et al.  Interdigital sensors and transducers , 2004, Proceedings of the IEEE.

[25]  Santiago Celma,et al.  Early detection and monitoring of forest fire with a wireless sensor network system , 2010 .

[26]  Li Xie,et al.  Practical nitrate sensor based on electrochemical impedance measurement , 2016, 2016 IEEE International Instrumentation and Measurement Technology Conference Proceedings.

[27]  Juan Vicente Capella,et al.  In line river monitoring of nitrate concentration by means of a Wireless Sensor Network with energy harvesting , 2013 .

[28]  O BODANSKY,et al.  Methemoglobinemia and methemoglobin-producing compounds. , 1951, Pharmacological reviews.

[29]  Marios M. Polycarpou,et al.  A Low-Cost Sensor Network for Real-Time Monitoring and Contamination Detection in Drinking Water Distribution Systems , 2014, IEEE Sensors Journal.

[30]  Paulo J. S. G. Ferreira,et al.  Sun, wind and water flow as energy supply for small stationary data acquisition platforms , 2008 .