Effect of reinforcing particles on the wear rate of low-pressure cold-sprayed WC-based MMC coatings

Abstract Tungsten carbide (WC)-based metal matrix composite (MMC) coatings fabricated using a low-cost, low-pressure cold spray unit were subjected to ASTM standard G65 dry abrasion wear testing. A linear relationship was observed between the wear rate and hardness of the various MMC coatings. Rule of mixtures (ROM) and a modified wear theory was used to explain the wear rate and material removal from the various WC-based MMC coatings. In general, the MMC coatings had wear rates closer to the values predicted by the modified wear theory. Although the MMC coatings had low wear rates close to values predicted by the equal wear theory, the cross-sectional images of the worn coatings suggested that material removal may have occurred by mechanisms governed by the equal pressure theory, where portions of, or even, the entire reinforcing particle were removed with the nickel matrix. The mean free path between the WC-based reinforcing particles was used to explain the improvements in wear rate as a function of increasing WC content in the coating. The coatings with the highest WC content and lower mean free path between the reinforcing particles had the lowest wear rates that were comparable to high-velocity oxy-fuel (HVOF)-sprayed and high-pressure cold-sprayed WC-based coatings.

[1]  P. H. Shipway,et al.  Influence of heat treatment on the abrasive wear behaviour of HVOF sprayed WC–Co coatings , 1998 .

[2]  E. Çeli̇k,et al.  Assessment of microstructural and mechanical properties of HVOF sprayed WC-based cermet coatings for a roller cylinder , 2006 .

[3]  Chang-jiu Li,et al.  Characterization of Nanostructured WC-Co Deposited by Cold Spraying , 2007, International Thermal Spray Conference.

[4]  A. Gerlich,et al.  Interfacial heating during low-pressure cold-gas dynamic spraying of aluminum coatings , 2011, Journal of Materials Science.

[5]  M. M. Khruschov Principles of abrasive wear , 1974 .

[6]  Pornthep Chivavibul,et al.  Effect of Powder Characteristics on Properties of Warm-Sprayed WC-Co Coatings , 2009, International Thermal Spray Conference.

[7]  A. McDonald,et al.  Development of WC-based metal matrix composite coatings using low-pressure cold gas dynamic spraying , 2013 .

[8]  Jiajun Liu,et al.  Micro-scale abrasive wear behaviour of HVOF sprayed and laser-remelted conventional and nanostructured WC-Co coatings , 2005 .

[9]  Pornthep Chivavibul,et al.  Effects of carbide size and Co content on the microstructure and mechanical properties of HVOF-sprayed WC–Co coatings , 2007 .

[10]  J. Nutting,et al.  Characterization of the W2C phase formed during the high velocity oxygen fuel spraying of a WC + 12 pct Co powder , 1999 .

[11]  B. Marple,et al.  Process–property–performance relationships for titanium dioxide coatings engineered from nanostructured and conventional powders , 2008 .

[12]  R. Chromik,et al.  Characterization of Ti cold spray coatings by indentation methods , 2011 .

[13]  Hui Wang,et al.  A study on abrasive resistance of Ni-based coatings with a WC hard phase , 1996 .

[14]  P. Shipway,et al.  Sliding wear behaviour of HVOF sprayed WC-Co coatings deposited with both gas-fuelled and liquid-fuelled systems , 2003 .

[15]  Anatolii Papyrin,et al.  Cold Spray Technology , 2006 .

[16]  Kevin J. Hodder,et al.  Fabrication of Aluminum-Alumina Metal Matrix Composite Coatings Via Cold Gas Dynamic Spraying at Low Pressure Followed by Friction-Stir Processing , 2012, International Thermal Spray Conference.

[17]  E. Lavernia,et al.  Near-nanostructured WC-18 pct Co coatings with low amounts of non-WC carbide phase: Part II. Hardness and resistance to sliding and abrasive wear , 2002 .

[18]  Zhen-hua Chen,et al.  The parameters optimization and abrasion wear mechanism of liquid fuel HVOF sprayed bimodal WC–12Co coating , 2012 .

[19]  Christian Coddet,et al.  Influence of coating microstructure on the abrasive wear resistance of WC/Co cermet coatings , 2000 .

[20]  G. Kim,et al.  Successful Application of Nanostructured Titanium Dioxide Coating for High-Pressure Acid-Leach Application , 2007 .

[21]  Pornthep Chivavibul,et al.  Development of WC-Co Coatings Deposited by Warm Spray Process , 2008, International Thermal Spray Conference.

[22]  M. Gee,et al.  Wear of tungsten carbide–cobalt hardmetals and hot isostatically pressed high speed steels under dry abrasive conditions , 2001 .

[23]  P. Leech,et al.  Comparison of abrasive wear of a complex high alloy hardfacing deposit and WC–Ni based metal matrix composite , 2012 .

[24]  A. C. Bozzi,et al.  Wear resistance and wear mechanisms of WC–12%Co thermal sprayed coatings in three-body abrasion , 1999 .

[25]  Lidong Zhao,et al.  Influence of spray parameters on the particle in-flight properties and the properties of HVOF coating of WC-CoCr , 2004 .

[26]  J. Legoux,et al.  Mechanical behavior of Ti cold spray coatings determined by a multi-scale indentation method , 2011 .

[27]  Julian A. Wharton,et al.  Effect of abrasive particle size and the influence of microstructure on the wear mechanisms in wear-resistant materials , 2012 .

[28]  B. S. Murty Advanced Materials and Processes , 2010 .

[29]  Tobias Schmidt,et al.  Development of a generalized parameter window for cold spray deposition , 2006 .

[30]  E. Lavernia,et al.  Near-nanostructured WC-18 pct Co coatings with low amounts of non-WC carbide phase: Part I. Synthesis and characterization , 2002 .

[31]  Andreas Mortensen,et al.  Size dependent strengthening in particle reinforced aluminium , 2002 .

[32]  J. Suchánek,et al.  Microstructure and properties of HVOF-sprayed chromium alloyed WC–Co and WC–Ni coatings , 2008 .

[33]  T. Fischer,et al.  Abrasion resistance of nanostructured and conventional cemented carbides , 1996 .

[34]  C. Berndt,et al.  Microstructural characteristics of cold-sprayed nanostructured WC-Co coatings , 2002 .

[35]  P. H. Shipway,et al.  Abrasive wear behaviour of conventional and nanocomposite HVOF-sprayed WC–Co coatings , 1999 .

[36]  J. Guilemany,et al.  Cold Spray Deposition of a WC-25Co Cermet onto Al7075-T6 and Carbon Steel Substrates , 2014, International Thermal Spray Conference.

[37]  Mark D. Semon,et al.  POSTUSE REVIEW: An Introduction to Error Analysis: The Study of Uncertainties in Physical Measurements , 1982 .

[38]  S. Wayne,et al.  Structure/property relationships in sintered and thermally sprayed WC-Co , 1992 .

[39]  B. Mellor,et al.  Fracture toughness and crack morphologies in eroded WC-Co-Cr thermally sprayed coatings , 1998 .

[40]  E. Sansoucy,et al.  WC-based cermet coatings produced by cold gas dynamic and pulsed gas dynamic spraying processes , 2007 .

[41]  Chang-Jiu Li,et al.  Influence of Powder Porous Structure on the Deposition Behavior of Cold-Sprayed WC-12Co Coatings , 2008, International Thermal Spray Conference.

[42]  P. Shipway,et al.  Bonding Mechanisms in Cold Spraying: The Contributions of Metallurgical and Mechanical Components , 2009 .

[43]  C. Moreau,et al.  Investigation of Al-Al2O3 Cold Spray Coating Formation and Properties , 2007, International Thermal Spray Conference.

[44]  Š. Houdková,et al.  Comparative Study of Thermally Sprayed Coatings Under Different Types of Wear Conditions for Hard Chromium Replacement , 2011 .

[45]  H. Liao,et al.  Effect of standoff distance on coating deposition characteristics in cold spraying , 2008 .

[46]  P. Fauchais,et al.  Mechanical and tribological performance of Al2O3-TiO2 coatings elaborated by flame and plasma spraying , 2010 .

[47]  Hamid Assadi,et al.  Bonding mechanism in cold gas spraying , 2003 .

[48]  J. Gates,et al.  Resistance to Abrasive Wear and Metallurgical Property Assessment of Nine Casing-Friendly Hard-Banding Alloy Chemistries: Abrasion Resistance Assessment Using ASTM G65 Methodology (Standard Test Method for Measuring Abrasion with Dry Sand/Rubber Wheel Apparatus) , 2014 .

[49]  Chang-jiu Li,et al.  Influence of substrate hardness transition on built-up of nanostructured WC-12Co by cold spraying , 2010 .

[50]  Kanchan Kumari,et al.  Effect of microstructure on abrasive wear behavior of thermally sprayed WC–10Co–4Cr coatings , 2010 .

[51]  Daniel Fabijanic,et al.  The use of Al–Al2O3 cold spray coatings to improve the surface properties of magnesium alloys , 2009 .

[52]  P. Shipway,et al.  Particle motion and modes of wear in the dry sand-rubber wheel abrasion test , 2009 .

[53]  Changhee Lee,et al.  Fabrication of WC–Co coatings by cold spray deposition , 2005 .

[54]  Staffan Jacobson,et al.  A model for the abrasive wear resistance of multiphase materials , 1994 .

[55]  S. Yue,et al.  Microstructure and nanohardness of cold-sprayed coatings: Electron backscattered diffraction and nanoindentation studies , 2010 .

[56]  J. Guilemany,et al.  The enhancement of the properties of WC-Co HVOF coatings through the use of nanostructured and microstructured feedstock powders , 2006 .

[57]  Robert O. Ritchie,et al.  A physically-based abrasive wear model for composite materials , 2002 .

[58]  G. Palumbo,et al.  The relationship between hardness and abrasive wear resistance of electrodeposited nanocrystalline Ni–P coatings , 2003 .

[59]  R. Heimann,et al.  Development and testing of HVOF-sprayed tungsten carbide coatings applied to moulds for concrete roof tiles , 2004 .

[60]  J. Martín,et al.  A study of high velocity oxy-fuel thermally sprayed tungsten carbide based coatings. Part 1: Microstructures , 1998 .

[61]  K. Khor,et al.  Effect of solid carbide particle size on deposition behaviour, microstructure and wear performance of HVOF cermet coatings , 2004 .

[62]  A. Gerlich,et al.  Microstructures and abrasive wear performance of PTAW deposited Ni–WC overlays using different Ni-alloy chemistries , 2012 .