Transformations of β-dicarbonyl compounds by reactions of their transition metal complexes with carbon and oxygen electrophiles

[1]  S. Godleski.  3.3 – Nucleophiles with Allyl–Metal Complexes , 1991 .

[2]  R. C. Mehrotra,et al.  Metal β-diketonates and allied derivatives , 1978 .

[3]  H. Musso,et al.  Organische Metallkomplexe, XIII: Anisotropieeffekte in den NMR‐Spektren 3‐mesityl‐ und 3‐(9‐anthryl)‐substituierter Acetylaceton‐Metallchelate , 1976 .

[4]  D. P. Graddon.  Divalent transition metal β-keto-enolate complexes as lewis acids , 1969 .

[5]  P. Perlmutter.  Conjugate Addition Reactions in Organic Synthesis , 1992 .

[6]  H. Brunner,et al.  Asymmetric catalysis: Part 411: Enantioselective michael additions catalyzed by Co(II)/1,2-diphenylethylenediamine , 1989 .

[7]  R. Manske,et al.  Synthesis and Reactions of Some Dibenzoxepins , 1950 .

[8]  J. Eilmes.  New ?,?'-disubstituted derivatives of macrocyclic Jger-type Ni(II) complexes , 1987 .

[9]  M. Moreno-Mañas,et al.  Copper and cobalt mediated regioselective alkylation of polyketide models: methyl 3,5-dioxohexanoate and triacetic acid lactone , 1990 .

[10]  A. Vallribera,et al.  Preparation and conformational analysis of severely hindered β-diketones. Dipole moment determinations and theoretical calculations. , 1991 .

[11]  J. Lindley.  Tetrahedron report number 163 , 1984 .

[12]  A. Vallribera,et al.  A dual mechanistic pathway in the alkylation of pentane-2,4-dione through its Co(II) complex , 1988 .

[13]  B. Corain,et al.  Michael addition of β-dicarbonyls to α,β-unsaturated ketones catalyzed by mixed sphere β-carbonylenolate diphosphino metal complexes , 1987 .

[14]  G. Zanotti,et al.  Metal-promoted reactivity of cyanogen toward compounds containing active hydrogen atoms on carbon. 2. Synthesis of a fully functionalized substituted pyrimidine from cyanogen and acetylacetone catalyzed by acetylacetonate complexes of transition metals , 1981 .

[15]  D. Busch,et al.  Synthesis and characterization of new cobalt dioxygen carriers based on a familiar macrocyclic ligand , 1990 .

[16]  M. Julia,et al.  Influence du cuivre sur la substitution des énolates stables par divers halogénures allyliques , 1987 .

[17]  J. Eilmes.  Benzoylation of macrocyclic jäger type Ni(II) complexes and an efficient demetalation of γ,γ′-dibenzoylated products , 1985 .

[18]  R. A. Henry,et al.  Reactions of copper(II) and nickel(II) .beta.-keto imine complexes. 3 , 1977 .

[19]  D. Dvořák,et al.  Transition-metal catalysis in michael addition of β-dicarbonyls : Tuning of the reaction conditions , 1986 .

[20]  G. Zanotti,et al.  Metal-promoted reactivity of cyanogen toward compounds containing active hydrogens on carbon. 1. Reaction of cyanogen with bis(2,4-pentanedionato)nickel(II) , 1979 .

[21]  A. Vallribera,et al.  Stereochemical and Regiochemical studies on the alkylation of pentane-2,4-dione through its Co(II) complex , 1993 .

[22]  G. Zanotti,et al.  Metal-catalyzed synthesis of cyano enaminediones from .beta.-dicarbonyl compounds and cyanogen. Identification of Traube's isomers , 1984 .

[23]  K. Narasaka,et al.  Reactions of bivalent sulfur compounds-copper(II) complexes , 1969 .

[24]  M. Moreno-Mañas,et al.  Cobalt(II) chloride bistriphenylphosphine catalyzed alkylations of β-dicarbonyl compounds , 1988 .

[25]  J. Collman.  Reactions of Metal Acetylacetonates , 1965 .

[26]  D. Caine.  Alkylations of Enols and Enolates , 1991 .

[27]  K. Sakata,et al.  Synthesis and spectroscopic properties for six 7,16-dibenzoylated tetraaza[14]annulene nickel(II) complexes , 1995 .

[28]  M. Moreno-Mañas,et al.  Reactions of copper(II) β-diketonates under free radical conditions. II. Diazonium salts as aryl radicals source in the arylation of β-diketones , 1992 .

[29]  M. Moreno-Mañas,et al.  Alxylations of α-methyl substituted β-diketones throught their Cu(II) complexes. Preparation of sterically congested β-diketones. , 1990 .

[30]  B. Corain,et al.  Simple Metal-Catalyzed Synthesis of Functionalized Pyrimidines from Dicyanogen and 1,3-Dicarbonyl Compounds† , 1981 .

[31]  F. Güell,et al.  Alkylation of β-diketones through their co(II), co(III) and zn(II) complexes. 1-Bromoadamantane as alkylating agent. , 1985 .

[32]  G. Desimoni,et al.  Copper (II) in organic synthesis. XI. Evaluation of the ligand architecture on the efficiency of a copper (II) catalyst for enantioselective Michael reactions , 1995 .

[33]  G. Desimoni,et al.  Copper(II) in organic synthesis. VIII enantioselective michael reactions with chiral copper(II) complexes as catalysts , 1990 .

[34]  H. Brunner,et al.  Enantioselective Michael Additions with Optically Active CoII/Diamine Catalysts , 1984 .

[35]  A. Vallribera,et al.  Mechanistic studies on the alkylation of pentane-2,4-dione through its Co(II) complex , 1993 .

[36]  Makoto Tanaka,et al.  Bis(acetylacetonato)metal(II)-Catalyzed Addition of Acceptor Molecules to Acetylacetone , 1976 .

[37]  R. A. Henry,et al.  Nickel-catalyzed Michael additions of .beta.-dicarbonyls , 1980 .

[38]  M. Moreno-Mañas,et al.  Hindered Rotation around Csp2–Csp3 Bonds in the Enol Forms of α-(9-Fluorenyl)-β-diketones and in 3,5-Disubstituted 4-(9-Fluorenyl)pyrazoles. An 1H NMR Study , 1988 .

[39]  M. Moreno-Mañas,et al.  Copper protection in the palladium catalyzed regioselective allylation of a model polyketide: Methyl 3,5-dioxohexanoate , 1989 .

[40]  C. Botteghi,et al.  Asymmetric Michael additions catalysed by Ni(II) and Co(II) complexes with homochiral ligands , 1991 .

[41]  M. Moreno-Mañas,et al.  Metal complexes in organic synthesis—V , 1981 .

[42]  M. Moreno-Mañas,et al.  Diastereoselection in the LiA1H4 reduction of severely hindered β-diketones examples of -curtin-hammett preequilibrium conditions , 1992 .

[43]  M. Moreno-Mañas,et al.  A radical-organometallic glycine synthon. Preparation of homochiral heterocyclic α-amino acids , 1993 .

[44]  J. Iqbal,et al.  Cobalt catalyzed regioselective allylation of 1,3-dicarbonyl compounds , 1994 .

[45]  K. Sakata,et al.  Synthesis and characterization of 7,16-dinicotinoyl- and 7,16-diisonicotinoyltetraaza[14]annulene and their nickel(II) and copper(II) complexes , 1992 .