Iso-Compass: new freeware software for isotopic data reduction of LA-MC-ICP-MS

Currently, laser ablation multi-collector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS) is a prominent and powerful method for in situ isotopic analysis. It provides high precision and spatially resolved isotopic information in solid samples. Data reduction of LA-MC-ICP-MS is inherently challenging owing to the severe mass spectral interferences and complex mass bias behaviors that occur during the analytical process. In this study, we present new freeware software, Iso-Compass, for isotope data reduction in LA-MC-ICP-MS. This software provides highly practical functions, including a simple data input interface, manually defined selection of laser and background signals, background correction, internal or external mass bias correction, interference correction, visual data presentation, and formatted data output. These functions can achieve easier and efficient reduction of LA-MC-ICP-MS data. The flexible formula editing mode enables Iso-Compass to be used in different isotope systems, thereby offering the potential to become a universal isotope data reduction platform for the geochemical community. Moreover, we present two examples (radiogenic Sr isotope analysis and stable Zr isotope analysis) to demonstrate the effectiveness of Iso-Compass.

[1]  I. Horn,et al.  Matrix and energy effects during in-situ determination of Cu isotope ratios by ultraviolet-femtosecond laser ablation multicollector inductively coupled plasma mass spectrometry , 2015 .

[2]  Z. Mester,et al.  Observations of large mass-independent fractionation occurring in MC-ICPMS: implications for determination of accurate isotope amount ratios. , 2011, Analytical chemistry.

[3]  Shan Gao,et al.  Improved in situ Hf isotope ratio analysis of zircon using newly designed X skimmer cone and jet sample cone in combination with the addition of nitrogen by laser ablation multiple collector ICP-MS , 2012 .

[4]  F. Ramos,et al.  Measuring 87Sr/86Sr variations in minerals and groundmass from basalts using LA-MC-ICPMS , 2004 .

[5]  Haishui Jiang,et al.  In situ calcium isotopic ratio determination in calcium carbonate materials and calcium phosphate materials using laser ablation-multiple collector-inductively coupled plasma mass spectrometry , 2019, Chemical Geology.

[6]  Shenghong Hu,et al.  In situ Nd isotope analyses in geological materials with signal enhancement and non-linear mass dependent fractionation reduction using laser ablation MC-ICP-MS , 2015 .

[7]  Chen Kaiyun,et al.  Precise and Accurate In Situ Determination of Lead Isotope Ratios in NIST, USGS, MPI‐DING and CGSG Glass Reference Materials using Femtosecond Laser Ablation MC‐ICP‐MS , 2014 .

[8]  S. Eggins,et al.  LAtools: A data analysis package for the reproducible reduction of LA-ICPMS data , 2019, Chemical Geology.

[9]  H. Zhao,et al.  Improved in situ Sr isotopic analysis by a 257 nm femtosecond laser in combination with the addition of nitrogen for geological minerals , 2017 .

[10]  Marie-Catherine Sforna,et al.  MapIT!: a simple and user-friendly MATLAB script to elaborate elemental distribution images from LA-ICP-MS data , 2017 .

[11]  I. Horn,et al.  First vanadium isotope analyses of V-rich minerals by femtosecond laser ablation and solution-nebulization MC-ICP-MS , 2017 .

[12]  C. Hawkesworth,et al.  Using hafnium and oxygen isotopes in zircons to unravel the record of crustal evolution , 2006 .

[13]  D. Morgan,et al.  Microsampling and Isotopic Analysis of Igneous Rocks: Implications for the Study of Magmatic Systems , 2007 .

[14]  Z. Mester,et al.  A critical review on isotopic fractionation correction methods for accurate isotope amount ratio measurements by MC-ICP-MS , 2018 .

[15]  G. Jiang,et al.  Recent advances in the analysis of non-traditional stable isotopes by multi-collector inductively coupled plasma mass spectrometry , 2017 .

[16]  Shan Gao,et al.  Accurate Determination of Sr Isotopic Compositions in Clinopyroxene and Silicate Glasses by LA‐MC‐ICP‐MS , 2016 .

[17]  J. Wiederhold Metal stable isotope signatures as tracers in environmental geochemistry. , 2015, Environmental science & technology.

[18]  S. Hart,et al.  Strontium isotopes in melt inclusions from Samoan basalts: Implications for heterogeneity in the Samoan plume , 2006 .

[19]  F. Poitrasson,et al.  Femtosecond laser ablation inductively coupled plasma source mass spectrometry for elemental and isotopic analysis: are ultrafast lasers worthwhile? , 2017 .

[20]  Lu Yang Accurate and precise determination of isotopic ratios by MC-ICP-MS: a review. , 2009, Mass spectrometry reviews.

[21]  M. Shaheen,et al.  Femtosecond (fs) lasers coupled with modern ICP-MS instruments provide new and improved potential for in situ elemental and isotopic analyses in the geosciences , 2012 .

[22]  Shan Gao,et al.  Improved Inter‐calibration of Faraday Cup and Ion Counting for In Situ Pb Isotope Measurements Using LA‐MC‐ICP‐MS: Application to the Study of the Origin of the Fangshan Pluton, North China , 2015 .

[23]  F. Moynier,et al.  Determination of Zr isotopic ratios in zircons using laser-ablation multiple-collector inductively coupled-plasma mass-spectrometry , 2019, Journal of Analytical Atomic Spectrometry.

[24]  D. Günther,et al.  Direct lead isotope analysis in Hg-rich sulfides by LA-MC-ICP-MS with a gas exchange device and matrix-matched calibration. , 2016, Analytica chimica acta.

[25]  J. Hellstrom,et al.  Iolite: Freeware for the visualisation and processing of mass spectrometric data , 2011 .

[26]  T. Harrison,et al.  Early (≥ 4.5 Ga) formation of terrestrial crust: Lu–Hf, δ18O, and Ti thermometry results for Hadean zircons , 2008 .

[27]  Peter A. Cawood,et al.  A Change in the Geodynamics of Continental Growth 3 Billion Years Ago , 2012, Science.

[28]  Yue-heng Yang,et al.  Calibration and correction of LA-ICP-MS and LA-MC-ICP-MS analyses for element contents and isotopic ratios , 2016 .

[29]  I. Horn,et al.  High‐Precision Fe and Mg Isotope Ratios of Silicate Reference Glasses Determined In Situ by Femtosecond LA‐MC‐ICP‐MS and by Solution Nebulisation MC‐ICP‐MS , 2014 .

[30]  A. Managh,et al.  A new freeware tool for image processing and its application to high speed LA-ICP-MS imaging , 2019, Journal of Analytical Atomic Spectrometry.