A titanium salicylate, Na 4 [Ti(C 7 H 4 O 3 ) 3 ] 2 ·11H 2 O

The title compound, tetrasodium bis[tris(salicylatotitanate(IV)] undecahydrate, Na 4 [Ti(C 7 H 4 O 3 ) 3 ] 2 ·11H 2 O, crystallizes with two titanium salicylate complex ions, four sodium ions and 11 water molecules in the asymmetric unit. One water O atom is disordered over two positions, having 0.74(5) and 0.26(5) occupancy. Both Ti atoms and three sodium ions adopt a distorted octahedral coordination by O atoms. The fourth sodium ion has a distorted trigonal-bipyramidal coordination by oxygen, sharing one edge with a sodium coordination octahedron.