Conductivity stability of carbon nanofiber/unsaturated polyester nanocomposites

Carbon nanofiber (CNF)/unsaturated polyester resin (UPR) was prepared by a solvent evaporation method, and the temperature dependency of electrical conductivity was investigated. The CNF/UPR composites had quite a low percolation threshold due to CNF having a larger aspect ratio and being well dispersed in the UPR matrix. The positive temperature coefficient (PTC) was found in the CNF/UPR composites and it showed stronger effect around the percolation threshold. The electrical resistance of the CNF/UPR composites decreased and had lower temperature dependency with increasing numbers of thermal cycles.

[1]  M. Sumita,et al.  Electrical properties of epoxy resin filled with carbon fibers , 1999 .

[2]  Ping Sheng,et al.  Fluctuation-Induced Tunneling Conduction in Carbon-Polyvinylchloride Composites , 1978 .

[3]  Rémy Dendievel,et al.  Carbon nanotube-filled polymer composites. Numerical simulation of electrical conductivity in three-dimensional entangled fibrous networks , 2006 .

[4]  Lang Liu,et al.  The dependence of resistivity of carbon fibers/ABS resin composites on the temperature , 2000 .

[5]  Guo Zhang,et al.  Resistivity‐temperature behavior of carbon fiber filled semicrystalline composites , 2004 .

[6]  J. Keith,et al.  Shielding-Effectiveness Modeling of Carbon-Fiber/Nylon- 6,6 Composites , 2005 .

[7]  J. P. Donohoe,et al.  Preparation, electrical and mechanical properties of vapor grown carbon fiber (VGCF)/vinyl ester composites , 2004 .

[8]  Bumsuk Kim,et al.  Electrical properties of single-wall carbon nanotube and epoxy composites , 2003 .

[9]  F. El-Tantawy New double negative and positive temperature coefficients of conductive EPDM rubber TiC ceramic composites , 2002 .

[10]  T. Fuchigami,et al.  Highly-regulated nanocoatings of polymer films on carbon nanofibers using ultrasonic irradiation. , 2006, Chemical communications.

[11]  Ping Wang,et al.  Temperature dependence of electrical resistivity for carbon black filled ultra-high molecular weight polyethylene composites prepared by hot compaction , 2005 .

[12]  Xiaojun Wang,et al.  Positive‐temperature‐coefficient/negative‐temperature‐coefficient effect of low‐density polyethylene filled with a mixture of carbon black and carbon fiber , 2003 .

[13]  M. Sumita,et al.  Carbon black-loading induced phase fluctuations in PVDF/PMMA miscible blends: dynamic percolation measurements , 2001 .

[14]  M. Rong,et al.  Performance stabilization of conductive polymer composites , 2003 .

[15]  Wei Zhou,et al.  Nanotube Networks in Polymer Nanocomposites: Rheology and Electrical Conductivity , 2004 .

[16]  S. Shekhar,et al.  Transport properties of conducting amorphous carbon–poly(vinyl chloride) composite , 2006 .

[17]  M. Sumita,et al.  Temperature and time dependence of conductive network formation: Dynamic percolation and percolation time , 2006 .

[18]  O. Chauvet,et al.  Localization, Coulomb interactions, and electrical heating in single-wall carbon nanotubes/polymer composites , 2002, cond-mat/0204520.

[19]  F. Carmona,et al.  Temperature-dependent resistivity and conduction mechanism in carbon particle-filled polymers , 1992 .

[20]  I. Balberg,et al.  Tunneling and percolation in metal-insulator composite materials , 2003, cond-mat/0306059.

[21]  Edward J. Garboczi,et al.  Analysis of the impedance spectra of short conductive fiber-reinforced composites , 2001 .

[22]  Hsu-Chiang Kuan,et al.  Preparation and electromagnetic interference shielding characteristics of novel carbon‐nanotube/siloxane/poly‐(urea urethane) nanocomposites , 2005 .

[23]  T. Nishi,et al.  Conductive-filler-filled poly(≥-caprolactone)/poly(vinyl butyral) blends. II. Electric properties (positive temperature coefficient phenomenon) , 1997 .

[24]  M. Sumita,et al.  Dynamic percolation phenomenon of poly(methyl methacrylate)/surface fluorinated carbon black composite , 2003 .