Coconut coir dust extract: a novel eco-friendly corrosion inhibitor for Al in HCl solutions

Abstract Corrosion inhibition of aluminium in 1 M HCl by coconut coir dust extract (CCDE) was studied using weight loss and hydrogen evolution techniques at 30 and 60°C. It was found that the studied extract exhibits a very good performance as inhibitor for aluminium corrosion in 1 M HCl. Results show that the inhibition efficiency increases with increasing temperature and concentration of the extract. Inhibitive effect was afforded by adsorption of the extracts' components which was found to accord with Langmuir adsorption isotherm. Inhibition mechanism is deduced from the temperature dependence of the inhibition efficiency and was further corroborated by the values of activation parameters obtained from the experimental data.

[1]  K. F. Khaled,et al.  Experimental, Monte Carlo and molecular dynamics simulations to investigate corrosion inhibition of mild steel in hydrochloric acid solutions , 2014 .

[2]  I. Obot,et al.  Spondias mombin L. as a green corrosion inhibitor for aluminium in sulphuric acid: Correlation between inhibitive effect and electronic properties of extracts major constituents using density functional theory , 2012 .

[3]  M. Ibrahim,et al.  Corrosion and corrosion control of mild steel in concentrated H2SO4 solutions by a newly synthesized glycine derivative , 2011 .

[4]  S. Umoren Synergistic inhibition effect of polyethylene glycol–polyvinyl pyrrolidone blends for mild steel corrosion in sulphuric acid medium , 2011 .

[5]  A. Aytaç Cu(II), Co(II) and Ni(II) complexes of –Br and –OCH2CH3 substituted Schiff bases as corrosion inhibitors for aluminium in acidic media , 2010 .

[6]  I. Obot,et al.  An interesting and efficient green corrosion inhibitor for aluminium from extracts of Chlomolaena odorata L. in acidic solution , 2010 .

[7]  E. Ebenso,et al.  Leaves extract of Ananas sativum as green corrosion inhibitor for aluminium in hydrochloric acid solutions , 2010 .

[8]  I. Udousoro,et al.  Inhibition of mild steel corrosion in HCl using pineapple leaves (Ananas comosus L.) extract , 2010 .

[9]  S. Chitra,et al.  Sulpha Schiff Bases as Corrosion Inhibitors for Mild Steel in 1M Sulphuric Acid , 2010 .

[10]  Jiajun Fu,et al.  l-Tryptophan as green corrosion inhibitor for low carbon steel in hydrochloric acid solution , 2010 .

[11]  Y. Hua,et al.  Corrosion inhibition of aluminum in hydrochloric acid solution by alkylimidazolium ionic liquids , 2010 .

[12]  A. Mohamad,et al.  Kinetic behavior of mild steel corrosion inhibition by 4-amino-5-phenyl-4H-1,2,4-trizole-3-thiol , 2010 .

[13]  W. Nik,et al.  Improvement of corrosion resistance of AA6061 alloy by tapioca starch in seawater , 2010 .

[14]  A. S. Yaro,et al.  Corrosion inhibition by naphthylamine and phenylenediamine for the corrosion of copper–nickel alloy in hydrochloric acid , 2010 .

[15]  Kumar Amit,et al.  Corrosion inhibition by Justicia gendarussa plant extract in hydrochloric acid solution , 2009 .

[16]  J. Otaigbe,et al.  The effects of Phyllanthus amarus extract on corrosion and kinetics of corrosion process of aluminum in alkaline solution , 2009 .

[17]  E. Ebenso,et al.  The inhibition of aluminium corrosion in hydrochloric acid solution by exudate gum from Raphia hookeri. , 2009 .

[18]  I. Obot,et al.  Antifungal drugs as corrosion inhibitors for aluminium in 0.1 M HCl , 2009 .

[19]  O. J. Kio,et al.  Gossipium hirsutum L. extracts as green corrosion inhibitor for aluminum in NaOH solution , 2009 .

[20]  E. A. Noor Evaluation of inhibitive action of some quaternary N-heterocyclic compounds on the corrosion of Al–Cu alloy in hydrochloric acid , 2009 .

[21]  I. Obot,et al.  Raphia hookeri gum as a potential eco-friendly inhibitor for mild steel in sulfuric acid , 2009 .

[22]  I. Obot,et al.  Fluconazole as an inhibitor for aluminium corrosion in 0.1 M HCl , 2008 .

[23]  A. A. Rahim,et al.  Recent Development of Vegetal Tannins in Corrosion Protection of Iron and Steel , 2008 .

[24]  E. Khamis,et al.  Inhibition of aluminium corrosion in alkaline solutions using natural compound , 2008 .

[25]  S. Umoren Inhibition of aluminium and mild steel corrosion in acidic medium using Gum Arabic , 2008 .

[26]  R. Balasubramaniam,et al.  Uncoupled non-linear equations method for determining kinetic parameters in case of hydrogen evolution reaction following Volmer–Heyrovsky–Tafel mechanism and Volmer–Heyrovsky mechanism , 2008 .

[27]  Katarina Berković,et al.  Natural honey and black radish juice as tin corrosion inhibitors , 2008 .

[28]  A. El-Etre Inhibition of C-steel corrosion in acidic solution using the aqueous extract of zallouh root , 2008 .

[29]  S. A. Salih,et al.  Corrosion Inhibition of Zn-Al-Cu Alloy by 2-Aminothiazole , 2008 .

[30]  W. B. Wan Nik,et al.  The effect of inhibitor on the corrosion of aluminum alloys in acidic solutions , 2008 .

[31]  A. El-Etre Inhibition of acid corrosion of carbon steel using aqueous extract of olive leaves. , 2007, Journal of colloid and interface science.

[32]  E. Ebenso,et al.  Polyethylene glycol and polyvinyl alcohol as corrosion inhibitors for aluminium in acidic medium , 2007 .

[33]  T. Hoar,et al.  The inhibition by quinolines and thioureas of the acid dissolution of mild steel , 2007 .

[34]  Emeka Emanuel Oguzie Corrosion inhibition of aluminium in acidic and alkaline media by Sansevieria trifasciata extract , 2007 .

[35]  G. Gunasekaran,et al.  Corrosion inhibition of mild steel by plant extract in dilute HCl medium , 2007 .

[36]  M. S. Ibrahim,et al.  Mangrove tannins and their flavanoid monomers as alternative steel corrosion inhibitors in acidic medium , 2007 .

[37]  E. Ebenso,et al.  Studies on the Inhibitive Effect of Exudate Gum from Dacroydes edulis on the Acid Corrosion of Aluminium , 2007 .

[38]  A. El-Etre,et al.  Khillah extract as inhibitor for acid corrosion of SX 316 steel , 2006 .

[39]  Belkheir Hammouti,et al.  Pennyroyal oil from Mentha pulegium as corrosion inhibitor for steel in 1 M HCl , 2006 .

[40]  B. Hammouti,et al.  Thermodynamic properties of 2,5-bis(4-methoxyphenyl)-1,3,4-oxadiazole as a corrosion inhibitor for mild steel in normal sulfuric acid medium , 2006 .

[41]  E. Ebenso,et al.  Gum arabic as a potential corrosion inhibitor for aluminium in alkaline medium and its adsorption characteristics , 2006 .

[42]  Fatih Köleli,et al.  Hydrogen evolution on conducting polymer electrodes in acidic media , 2006 .

[43]  H. Ashassi-Sorkhabi,et al.  The effect of some Schiff bases on the corrosion of aluminum in hydrochloric acid solution , 2006 .

[44]  A. K. Maayta,et al.  Inhibition of acidic corrosion of pure aluminum by some organic compounds , 2004 .

[45]  M. Deyab,et al.  Studies on corrosion inhibition of aluminum in 1.0 M HCl and 1.0 M H2SO4 solutions by ethoxylated fatty acids , 2003 .

[46]  A. El-Etre,et al.  Inhibition of aluminum corrosion using Opuntia extract , 2003 .

[47]  M. Amin,et al.  The corrosion inhibition study of sodium dodecyl benzene sulphonate to aluminium and its alloys in 1.0 M HCl solution , 2003 .

[48]  Á. Maquieira,et al.  Coconut coir waste, a new and viable ecologically-friendly peat substitute. , 2000 .

[49]  C. Offord,et al.  Growth of selected Australian plants in soilless media using coir as a substitute for peat , 1998 .

[50]  L. Arachchi,et al.  USE OF COIR DUST ON THE PRODUCTIVITY OF COCONUT ON SANDY SOILS , 2010 .

[51]  S. Aziz,et al.  Kinetic‐Thermodynamic and Adsorption Isotherms Analyses for the Inhibition of the Acid Corrosion of Steel by Cyclic and Open‐Chain Amines , 1992 .

[52]  R. Latanision,et al.  Acid Corrosion Inhibition of Nickel by 2-(Triphenosphoranylidene) Succinic Anhydride , 1991 .

[53]  N. Nayar Coconut research and development. , 1983 .

[54]  G. Schmid,et al.  Spectro-electrochemical studies of the inhibition effect of 4, 7-diphenyl -1, 10-phenanthroline on the corrosion of 304 stainless steel , 1980 .

[55]  J. Chweya,et al.  Preliminary Studies on Some Local Materials for Propagation Media: 2.-Trials with Mixtures Containing Local Materials , 1978 .

[56]  S. Reynolds PRELIMINARY STUDIES IN WESTERN SAMOA USING VARIOUS PARTS OF THE COCONUT PALM (COCOS NUCIFERA L.) AS GROWING MEDIA , 1974 .

[57]  M. Pourbaix Atlas of Electrochemical Equilibria in Aqueous Solutions , 1974 .

[58]  I. A. Ammar,et al.  Adsorbability of Thiourea on Iron Cathodes , 1973 .

[59]  R. M. Hurd,et al.  Temperature Coefficient of Corrosion Inhibition , 1967 .

[60]  Farrington Daniels,et al.  Physical Chemistry, 2nd Ed. , 1961 .