Heterogeneity of the Lower Silurian Longmaxi marine shale in the southeast Sichuan Basin of China

This study characterizes the vertical heterogeneity of the Lower Silurian Longmaxi marine shale in the southeast Sichuan Basin based on core description, thin sections observation, geological chemistry data interrogation, and QEMSCAN image analysis. Lithofacies associations, mineralogy, graptolite species occurrence, rock fabrics, as well as TOC (Total Organic Carbon) and gas content, change noticeably and regularly in the Lower Silurian Longmaxi marine shale within sequence stratigraphic framework. Lithofacies associations mainly include in-situ graptolite rich and siliceous shale in the transgressive systems tract (TST), micro-offsite graptolite rich shale and shale interbedded with siltstone laminaes in the early highstand systems tract (EHST), and micro-offsite graptolite rich and carbonate rich shale in the late highstand systems tract (LHST). The TST has a greater abundance of Diplogratus than EHST and LHST, and has a lesser level of Monograptus, which is conversely higher in the EHST and LHST. The TST shale is silica rich, while the LHST shale is generally clay rich. The EHST shale is more balanced in its silica and clay content than the TST and LHST are. The sedimentary structure and fabric of shale shows that shale is homogenous in the TST, with laminaes well developed in the EHST but decreasing in the LHST. TOC and gas content are highest in the TST and decrease upward. The TST, with high TOC, high gas content, high brittle minerals (silica rich) and anoxic-suboxic to dysoxic sedimentary environment, is the most potential shale gas target interval in the study area. Our research also shows that the TOC mainly controls shale gas accumulation and that the redox conditions mainly control the preservation of organic matter. The silica also plays a significant role in shale gas content due to its contribution to hydraulic fracturing. Finally, the study proposes a depositional and heterogeneity model for the Lower Silurian Longmaxi marine shale in the study area.

[1]  Wang Jia Shale gas exploration prospect of Lower Paleozoic in southeastern Sichuan and western Hubei-eastern Chongqing areas,China , 2011 .

[2]  Xiangliang Zeng,et al.  Characteristics of the Shale Gas Reservoir Rocks in the Lower Silurian Longmaxi Formation, East Sichuan Basin, China , 2013 .

[3]  T. Engelder,et al.  Sequence stratigraphy and depositional environments of the Shamokin (Union Springs) Member, Marcellus Formation, and associated strata in the middle Appalachian Basin , 2014 .

[4]  Fang Junhua,et al.  Characteristics and significance of mineral compositions of Lower Silurian Longmaxi Formation shale gas reservoir in the southern margin of Sichuan Basin , 2011 .

[5]  D. Kaljo On the bathymetric distribution of graptolites , 1978 .

[6]  Yang Jun-bin Source Rock Characteristics of Marine Strata,Sichuan Basin , 2011 .

[7]  J. Davies,et al.  Organic-carbon deposition and coastal upwelling at mid-latitude during the Upper Ordovician late Katian; a case study from the Welsh Basin, UK , 2009 .

[8]  Hua Yang,et al.  Quantitative characterization of reservoir space in the Lower Silurian Longmaxi Shale, southern Sichuan, China , 2014, Science China Earth Sciences.

[9]  A. Riboulleau,et al.  Palynology, organic geochemistry and carbon isotope analysis of a latest Ordovician through Silurian clastic succession from borehole Tt1, Ghadamis Basin, southern Tunisia, North Africa: Palaeoenvironmental interpretation , 2009 .

[10]  W. Berry GRAPTOLITE OCCURRENCE AND ECOLOGY , 1962 .

[11]  Fang Junhua Structure characteristics and accumulation significance of nanopores in Longmaxi shale gas reservoir in the southern Sichuan Basin , 2012 .

[12]  Feiyu Wang,et al.  Evolution of overmature marine shale porosity and implication to the free gas volume , 2013 .

[13]  Rob L. Gawthorpe,et al.  High-Resolution Facies Analyses of Mudstones: Implications for Paleoenvironmental and Sequence Stratigraphic Interpretations of Offshore Ancient Mud-Dominated Successions , 2007 .

[14]  T. Fan,et al.  Characterization of the Upper Ordovician and Lower Silurian Marine Shale in Northwestern Guizhou Province of the Upper Yangtze Block, South China: Implication for Shale Gas Potential , 2014 .

[15]  R. Bustin,et al.  Characterizing the shale gas resource potential of Devonian–Mississippian strata in the Western Canada sedimentary basin: Application of an integrated formation evaluation , 2008 .

[16]  R. Rickards PALAEOECOLOGY OF THE GRAPTOLITHINA, AN EXTINCT CLASS OF THE PHYLUM HEMICHORDATA , 1975 .

[17]  Liu Xinjin,et al.  Reservoir-forming conditions and favorable exploration zones of shale gas in Lower Silurian Longmaxi Formation of Sichuan Basin , 2010 .

[18]  D. Jarvie,et al.  Unconventional shale-gas systems: The Mississippian Barnett Shale of north-central Texas as one model for thermogenic shale-gas assessment , 2007 .

[19]  Li Zhi-ming,et al.  Distribution of Black Shale in the Wufeng-Longmaxi Formations (Ordovician-Silurian),South China: Major Controlling Factors and Implications , 2007 .

[20]  J. Hower,et al.  High-resolution geochemistry and sequence stratigraphy of the Hushpuckney Shale (Swope Formation, eastern Kansas): implications for climato-environmental dynamics of the Late Pennsylvanian Midcontinent Seaway , 2004 .

[21]  R. Slatt,et al.  Lithofacies and sequence stratigraphy of the Barnett Shale in east-central Fort Worth Basin, Texas , 2012 .

[22]  R. Marc Bustin,et al.  Lower Cretaceous gas shales in northeastern British Columbia, Part I: geological controls on methane sorption capacity , 2008 .

[23]  Junhua Fang,et al.  Shale gas reservoir characterisation: A typical case in the southern Sichuan Basin of China , 2011 .

[24]  Roger M. Slatt,et al.  Merging sequence stratigraphy and geomechanics for unconventional gas shales , 2011 .

[25]  Li Wan-Mao Mineral compositions and organic matter occurrence modes of Lower Silurian Longmaxi Formation of Sichuan Basin , 2013 .

[26]  Daniel M. Jarvie,et al.  Mississippian Barnett Shale, Fort Worth basin, north-central Texas: Gas-shale play with multi–trillion cubic foot potential , 2005 .

[27]  Tongwei Zhang,et al.  Grain assemblages and strong diagenetic overprinting in siliceous mudrocks, Barnett Shale (Mississippian), Fort Worth Basin, Texas , 2012 .

[28]  Liu Shu-ge Characteristics of black shale in Wufeng Formation and Longmaxi Formation in Sichuan Basin and its peripheral areas , 2013 .

[29]  J. Macquaker,et al.  Mudstone Lithofacies in the Kimmeridge Clay Formation, Wessex Basin, Southern England: Implications for the Origin and Controls of the Distribution of Mudstones , 1994 .

[30]  Chen Xu,et al.  HIRNANTIAN (LATEST ORDOVICIAN) GRAPTOLITES FROM THE UPPER YANGTZE REGION, CHINA , 2005 .

[31]  Zhaoping Meng,et al.  A preliminary study on the pore characterization of Lower Silurian black shales in the Chuandong Thrust Fold Belt, southwestern China using low pressure N2 adsorption and FE-SEM methods , 2013 .

[32]  C. Liang,et al.  Shale lithofacies and reservoir space of the Wufeng–Longmaxi Formation, Sichuan Basin, China , 2012 .

[33]  R. Slatt,et al.  Comparative sequence stratigraphy and organic geochemistry of gas shales: Commonality or coincidence? , 2012 .

[34]  Christopher E. Harris,et al.  Understanding geophysical responses of shale-gas plays , 2011 .

[35]  Y. Sun. Graptolite‐Bearing Strata of China , 2009 .

[36]  A. Schimmelmann,et al.  Geochemical constraints on the origin and volume of gas in the New Albany Shale (Devonian–Mississippian), eastern Illinois Basin , 2010 .

[37]  Cheryl A. Mnich,et al.  A sequence-stratigraphic framework for the Upper Devonian Woodford Shale, Permian Basin, west Texas , 2014 .

[38]  C. Mitchell,et al.  Late Ordovician to earliest Silurian graptolite and brachiopod biozonation from the Yangtze region, South China, with a global correlation , 2000, Geological Magazine.

[39]  J. Curtis Fractured shale-gas systems , 2002 .

[40]  Hu Lin Classification of pore structures in shale gas reservoir at the Longmaxi Formation in the south of Sichuan Basin , 2013 .

[41]  Luo Yue,et al.  The geologic background of the Siluric shale-gas reservoiring in Szechwan, China , 2010 .

[42]  J. Breyer Shale Reservoirs: Giant Resources for the 21st Century , 2012 .

[43]  C. Mitchell,et al.  Ashgillian graptolite fauna of the Yangtze region and the biogeographical distribution of diversity in the latest Ordovician , 2003 .

[44]  G. Frébourg,et al.  Haynesville and Bossier mudrocks: A facies and sequence stratigraphic investigation, East Texas and Louisiana, USA , 2012 .

[45]  J. H. S. MACQUAKER,et al.  Small-scale (<5.0 m) vertical heterogeneity in mudstones: implications for high-resolution stratigraphy in siliciclastic mudstone successions , 1999, Journal of the Geological Society.

[46]  Prerna Singh,et al.  Lithofacies and Sequence Stratigraphic framework of the Barnett Shale, Northeast Texas , 2008 .

[47]  Hanrong Zhang,et al.  Formation and enrichment mode of Jiaoshiba shale gas field, Sichuan Basin , 2014 .

[48]  K. Bowker Barnett Shale gas production, Fort Worth Basin: Issues and discussion , 2007 .

[49]  J. McIntosh,et al.  Identification of microbial and thermogenic gas components from Upper Devonian black shale cores, Illinois and Michigan basins , 2008 .

[50]  D. Manning,et al.  Comparison of geochemical indices used for the interpretation of palaeoredox conditions in ancient mudstones , 1994 .