Materials for energy conservation and storage

Some areas of energy use where improved materials could lead to energy savings are surveyed. Current energy use patterns and their likely evolution to the end of the century are also reviewed so that particular applications may be seen in perspective against overall energy consumption and other energy conservation measures. Energy conservation is viewed both from the point of view of energy inputs to materials and how process improvements might permit savings, and also by considering general modes of energy use--transport and combustion in particular--and assessing some general ways in which conservation could be achieved. Areas such as improved engine-management of internal combustion engined vehicles and improved batteries for electric vehicles, where progress depends very much on materials developments, are surveyed in more detail. The need for improved sensors to measure exhaust gas composition in vehicles is one particular aspect of a general need for improved monitoring to permit better quality control and hence optimal fuel input for industrial processes requiring heat. Energy storage procedures are surveyed, together with a discussion of electricity generating methods and future electricity use. Attention is given to current fuel cell programmes, which offer the potential of increased conversion efficiency of fossil fuel to electricity compared with conventional power stations but where materials problems are critical in determining commercial success, to heat storage materials, and to water electrolysis and hydrogen production as a means of energy storage. The utilisation of electrochemical processes in solids or at surfaces or interfaces is a general theme underlying many of the technologies discussed.

[1]  Donald N. Dewees Energy conservation in home furnaces , 1979 .

[2]  J. Dawson Prospects for hydrogen as an energy resource , 1974, Nature.

[3]  E. Hayes Energy, environment and conservation. , 1976, Science.

[4]  M. Stanley Whittingham,et al.  Chemistry of intercalation compounds: Metal guests in chalcogenide hosts , 1978 .

[5]  Earl T. Hayes,et al.  Energy Implications of Materials Processing , 1976 .

[6]  A. J. Appleby,et al.  High efficiency water electrolysis in alkaline solution , 1978 .

[7]  H. Hong,et al.  Crystal structure and ionic conductivity of Li14Zn(GeO4)4 and other new Li+ superionic conductors☆ , 1978 .

[8]  M. Breiter,et al.  Ionic conductivity in H3O+ beta alumina , 1978 .

[9]  Yasuhiko Ito,et al.  A new method for the electrolysis of sodium chloride using a β-alumina-molten salt system , 1976 .

[10]  J. Coetzer High temperature lithium/sulphur batteries: a preliminary investigation of a zeolite—sulphur cathode , 1978 .

[11]  S. M. Caulder,et al.  Structural transformations of the PbO/sub 2//active material during cycling , 1975 .

[12]  A. Howe,et al.  Rapid H+ conductivity in hydrogen uranyl phosphate-A solid H+ electrolyte , 1977 .

[13]  A. D. Tullett,et al.  Computer-aided heat treatment , 1978 .

[14]  D. Fray,et al.  Instantaneous determination of hydrogen content in molten aluminum and its alloys , 1978 .

[15]  K. Bartle,et al.  Chemical nature of a supercritical-gas extract of coal at 350 °C , 1975 .

[16]  E. Cook Perspectives on needs and supplies of resources. , 1976, Science.

[17]  G. Sethia,et al.  The solar wind influences plasmasphere electron content , 1978, Nature.

[18]  Arthur J. Nozik,et al.  Electrode materials for photoelectrochemical devices , 1977 .

[19]  A. M. Squires Chemicals from coal. , 1976, Science.

[20]  G Charlesworth,et al.  Future transport fuels , 1976 .

[21]  R. Leakey,et al.  The hominids of East Turkana. , 1978, Scientific American.

[22]  Richard Dell,et al.  Batteries for solar electricity , 1979 .

[23]  A. Stoneham,et al.  A model for the fast ionic diffusion in alumina-doped LiI , 1979 .

[24]  Oxygen evolution on semiconducting oxides , 1977 .

[25]  David S. Newman,et al.  Solid Electrolytes General Principles, Charecterization, Materials, Applications , 1980 .

[26]  C. Liang,et al.  Solid-state storage batteries , 1978 .

[27]  J. Wahl Ionic conductivity of lithium nitride doped with hydrogen , 1979 .

[28]  D. Weaire,et al.  Recent progress in thin-film solar cells , 1978 .

[29]  P. Rai-Choudhury,et al.  Materials for low-cost solar cells , 1978 .

[30]  E. Logothetis,et al.  Oxygen Sensing with Co1 − x Mg x O Ceramics , 1977 .

[31]  William J. Fleming,et al.  Physical Principles Governing Nonideal Behavior of the Zirconia Oxygen Sensor , 1977 .

[32]  A. Rabenau,et al.  Ionic conductivity in Li3N single crystals , 1977 .