Titanocene(III) catalyzed homogeneous hydrosilation-hydrogenation of pyridines

The homogeneous catalytic hydrosilation-hydrogenation of pyridines is observed in the presence of Cp2TiMe2 (Cp = η5-C5H5) and CpCp*TiMe2 (Cp* = η5-C5Me5) as catalysts and using PhSiH3 or PhMeSiH2 a...

[1]  Ronghua Shu,et al.  Catalytic reduction of benzoate esters and lactones in the presence of PhMeSiH2 and a titanocene-based catalyst , 2002 .

[2]  陆军,et al.  二茂铁基1,4—Dihydropyridine类似物的合成 , 2002 .

[3]  Y. Mu,et al.  Homogeneous Catalytic Hydrosilylation of Pyridines. , 1998, Angewandte Chemie.

[4]  H. Woo,et al.  Synthesis and Crystal Structure of Some Novel Titanocene Phosphido Compounds by P−H Activation in the Presence of Hydrosilanes , 1997 .

[5]  S. Buchwald,et al.  Development of a Method for the Reductive Cyclization of Enones by a Titanium Catalyst , 1996 .

[6]  J. Harrod,et al.  Reactions of silanes with allylic alcohols catalyzed by titanocene derivatives: an approach to catalytic cross dehydrocoupling/co-intramolecular hydrosilation , 1995 .

[7]  J. Harrod,et al.  A novel catalyst system for the production of polyacetylene and of blends of polyacetylene with some silicon‐containing polymers , 1994 .

[8]  D. Herschlag Ribonuclease Revisited: Catalysis via the Classical General Acid-Base Mechanism or a Triester-like Mechanism? , 1994 .

[9]  G. Parkin,et al.  Terminal oxo, sulfido, selenido, and tellurido complexes of zirconium, ([eta][sup 5]-C[sub 5]Me[sub 4]R)[sub 2]Zr(E)(NC[sub 5]H[sub 5]). Comparison of terminal Zr-E single and Zr=E double bond lengths , 1994 .

[10]  Jili He,et al.  Dehydrocoupling reactions of organosilanes with hydrazines , 1994 .

[11]  I. Ojima,et al.  Catalytic Asymmetric Synthesis , 1993 .

[12]  J. Y. Corey,et al.  Conversion of hydrosilanes to alkoxysilanes catalyzed by Cp2TiCl2/nBuLi , 1992 .

[13]  H. Liu,et al.  Dehydrocoupling of ammonia and silanes catalyzed by dimethyltitanocene , 1992 .

[14]  B. Marciniec Comprehensive handbook on hydrosilylation , 1992 .

[15]  S. Buchwald,et al.  A catalytic method for the reduction of esters to alcohols , 1991 .

[16]  H. Liu,et al.  Copper(I) chloride catalyzed cross-dehydrocoupling reactions between silanes and ethynyl compounds. A new method for the copolymerization of silanes and alkynes , 1990 .

[17]  A. Djebli,et al.  A stable titanacyclo-2-pentene: synthesis and structure of 3,3-bis(.eta.5-cyclopentadienyl)-4,5-diphenyl-3-titanatetracyclo[5.5.1.02,6.08,12]trideca-4,8,11-triene , 1990 .

[18]  N. Baenziger,et al.  Synthesis and insertion chemistry of cationic zirconium(IV) pyridyl complexes. Productive .sigma.-bond metathesis , 1990 .

[19]  Y. Mu,et al.  Synthesis and properties of some novel bis(cyclopentadienyl)silyltitanium(III) complexes , 1990 .

[20]  Yitzhak Apeloig,et al.  The chemistry of organic silicon compounds , 1989 .

[21]  A. Malek,et al.  Oligomerization of phenylgermanes by catalytic dehydrocoupling , 1988 .

[22]  J. H. Teuben,et al.  Reactions of yttrium-carbon bonds with active hydrogen-containing molecules. A useful synthetic method for permethylyttrocene derivatives , 1987 .

[23]  S. Yun,et al.  Silyltitanocene complexes as catalysts for the hydrogenation, isomerization, and hydrosilylation of olefins , 1987 .

[24]  W. Schaefer,et al.  .sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bonds , 1987 .

[25]  J. Harrod,et al.  Polymerization of primary silanes to linear polysilanes catalyzed by titanocene derivatives , 1985 .

[26]  J. H. Teuben,et al.  REACTION OF TITANOCENE ALKYLS WITH PYRIDINES - A NOVEL TYPE OF CYCLOMETALLATION REACTION , 1981 .

[27]  G. Stucky,et al.  Electronic properties of bis(.eta.5-cyclopentadienyl)titanium 2,2'-bipyridyl. A singlet molecule with a low-lying triplet excited state , 1979 .

[28]  G. Stucky,et al.  Molecular structure of .mu.-pyrazole-bis(.eta.5-cyclopentadienyl)titanium(III), a dimeric titanium(III) compound with a bridging organic group , 1978 .

[29]  G. Stucky,et al.  Synthesis, electron paramagnetic resonance, and magnetic studies of binuclear bis(.eta.5-cyclopentadienyl)titanium(III) compounds with bridging pyrazolate, biimidazolate, and bibenzimidazolate anions , 1978 .

[30]  R. Jungst,et al.  Structural and magnetic properties of di-.mu.-chloro-bis[bis(.eta.5-cyclopentadienyl)titanium(III)] and di-.mu.-bromo-bis[bis(.eta.5-methylcyclopentadienyl)titanium(III)] , 1977 .

[31]  J. Mccowan,et al.  The thermal decomposition of dicyclopentadienyldimethyltitanium(IV) , 1976 .

[32]  Toshi-aki Kobayashi,et al.  Chemistry of organosilicon compounds , 1976 .

[33]  Lloyd J. Guggenberger,et al.  Aluminotitanium hydrides [(C5H5)Ti]2(H)(H2AlEt2)C10H8) and [(C5H4)TiHAlEt2]2(C10H8) , 1973 .

[34]  M. Rausch,et al.  .pi.-Cyclopentadienyl and .pi.-indenyl compounds of titanium, zirconium, and hafnium containing .sigma.-bonded organic substituents , 1973 .

[35]  I. Wender,et al.  Organic syntheses via metal carbonyls , 1968 .

[36]  R. A. Benkeser,et al.  The Formation of Arylsilylpotassium Compounds , 1952 .