High-Quality Graphene Ribbons Prepared from Graphene Oxide Hydrogels and Their Application for Strain Sensors.

Reduced graphene oxide (rGO) ribbons with arbitrary lengths were prepared by dry spinning of the hydrogels of graphene oxide (GO) formed via thermal annealing GO dispersions, and followed by chemical reduction. These rGO ribbons are flexible, having ultrahigh tensile strengths of 582 ± 17 MPa, ultrahigh fracture energies of 18.29 ± 2.47 MJ m(-3), high conductivities of 662 ± 41 S cm(-1), and an extremely large breakdown current density of about 11,500 A cm(-2). Strain sensors based on the meshes of these ribbons showed sensitive recoverable responses to different tensile strains with excellent cycling stability, promising for the applications in wearable devices.

[1]  Chang Liu,et al.  Advanced Materials for Energy Storage , 2010, Advanced materials.

[2]  Ping Wang,et al.  Wet-spinning assembly of continuous, neat, and macroscopic graphene fibers , 2012, Scientific Reports.

[3]  R. Car,et al.  Raman spectra of graphite oxide and functionalized graphene sheets. , 2008, Nano letters.

[4]  Lan Jiang,et al.  Facile Fabrication of Light, Flexible and Multifunctional Graphene Fibers , 2012, Advanced materials.

[5]  Michael Sennett,et al.  High-Performance Carbon Nanotube Fiber , 2007, Science.

[6]  J. Tascón,et al.  Atomic force and scanning tunneling microscopy imaging of graphene nanosheets derived from graphite oxide. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[7]  Jisoo Park,et al.  Easy Preparation of Readily Self-Assembled High-Performance Graphene Oxide Fibers , 2014 .

[8]  D. Mooney,et al.  Hydrogels for tissue engineering. , 2001, Chemical reviews.

[9]  Mark E. Davis Ordered Porous Materials for Emerging Applications , 2002 .

[10]  Chun Li,et al.  Functional Gels Based on Chemically Modified Graphenes , 2014, Advanced materials.

[11]  T. Chou,et al.  Graphene‐Based Fibers: A Review , 2015, Advanced materials.

[12]  Liangti Qu,et al.  Graphene fiber: a new material platform for unique applications , 2014 .

[13]  J. Meindl,et al.  Breakdown current density of graphene nanoribbons , 2009, 0906.4156.

[14]  Chao Gao,et al.  Highly Electrically Conductive Ag‐Doped Graphene Fibers as Stretchable Conductors , 2013, Advanced materials.

[15]  Seulah Lee,et al.  Ag Nanowire Reinforced Highly Stretchable Conductive Fibers for Wearable Electronics , 2015 .

[16]  Jun Chen,et al.  Scalable One‐Step Wet‐Spinning of Graphene Fibers and Yarns from Liquid Crystalline Dispersions of Graphene Oxide: Towards Multifunctional Textiles , 2013 .

[17]  G. Shi,et al.  Multifunctional Pristine Chemically Modified Graphene Films as Strong as Stainless Steel , 2015, Advanced materials.

[18]  C. Papp,et al.  Wet Chemical Synthesis of Graphene , 2013, Advanced materials.

[19]  A. Ferrari,et al.  Raman spectroscopy of graphene and graphite: Disorder, electron phonon coupling, doping and nonadiabatic effects , 2007 .

[20]  Chao Gao,et al.  Ultrastrong Fibers Assembled from Giant Graphene Oxide Sheets , 2013, Advanced materials.

[21]  Chao Gao,et al.  Macroscopic assembled, ultrastrong and H2SO4-resistant fibres of polymer-grafted graphene oxide , 2013, Scientific Reports.

[22]  Q. Fu,et al.  Toward high performance graphene fibers. , 2013, Nanoscale.

[23]  Neelkanth M. Bardhan,et al.  Scalable enhancement of graphene oxide properties by thermally driven phase transformation. , 2014, Nature chemistry.

[24]  Xiaozhen Hu,et al.  Wet-Spun Continuous Graphene Films , 2014 .

[25]  G. Shi,et al.  Ultratough, Ultrastrong, and Highly Conductive Graphene Films with Arbitrary Sizes , 2014, Advanced materials.

[26]  Zheng Yan,et al.  Large Flake Graphene Oxide Fibers with Unconventional 100% Knot Efficiency and Highly Aligned Small Flake Graphene Oxide Fibers , 2013, Advanced materials.

[27]  Lan Jiang,et al.  Graphene fibers with predetermined deformation as moisture-triggered actuators and robots. , 2013, Angewandte Chemie.

[28]  Hua Bai,et al.  Functional Composite Materials Based on Chemically Converted Graphene , 2011, Advanced materials.

[29]  Chenguang Zhang,et al.  Graphene nanoribbons as an advanced precursor for making carbon fiber. , 2013, ACS nano.

[30]  Chao Gao,et al.  Graphene in macroscopic order: liquid crystals and wet-spun fibers. , 2014, Accounts of chemical research.

[31]  M. Kozlov,et al.  Fibers of reduced graphene oxide nanoribbons , 2012, Nanotechnology.

[32]  Shing‐Jong Huang,et al.  Supplementary Information for , 2013 .

[33]  R. Ruoff,et al.  Stretchable and highly sensitive graphene-on-polymer strain sensors , 2012, Scientific Reports.

[34]  Jonghwan Suhr,et al.  Super-stretchable graphene oxide macroscopic fibers with outstanding knotability fabricated by dry film scrolling. , 2014, ACS nano.

[35]  R. Ruoff,et al.  The chemistry of graphene oxide. , 2010, Chemical Society reviews.

[36]  S. Stankovich,et al.  Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide , 2007 .