Assessment of orange peel waste availability in ghana and potential bio-oil yield using fast pyrolysis

The continuous escalation of crude oil prices coupled with declining food supply as a results of the growing global population and climate change have instigated many countries to look out for alternative means of reducing its fossil fuel dependency. In view of this, the study evaluates the available orange peels in Ghana as potential bio-oil producing feedstock using fast pyrolysis technology in order to supplement the country's overriding fuel demand. The paper therefore reviewed the current advancement in fast pyrolysis bio-oil production and utilization, determined the available orange peel produced from fruit processing industries in Ghana and finally determined the potential yield of fast pyrolysis bio-oil to satisfy the projected fuel demand by 2020 and 2030. From this study, Ghana has the ability to replace just about 0.09% of its diesel and petroleum demand in 2020 and 0.07% in 2030 after processing just 10% of the total oranges produced using 2013 orange production as baseline. However, increasing the area of cultivation of oranges to 1.6 million ha (the area covered by cocoa in Ghana) and considering scenarios where the percentage of oranges processed were increased to 40%, 50% and 60% as observed in Brazil, USA, Mexico and other leading producers showed promising potential. The study observed that increasing the area of cultivation of oranges to the same area occupied by cocoa in 2013 saw a possible replacement of total diesel and petrol demand of 8.73% for processing just 10% increasing to 34.92% for 40% processing, 43.65% for 50% processing and 52.38% for 60% processing by 2020. Similarly, in 2030 the country will be able to replace 6.70% of the total diesel and petrol fuels with bio-oil for processing just 10% of its oranges produced which increases to 26.80% for processing 40%, 33.5% for processing 50% and 40.20% for processing 60% of oranges producing. The country still has the potential to channel some of the produced bio-oil for cooking purposes using improved stoves rather than relying on firewood and petroleum fuels. In order to meet these potentials, the study recommended, that the government creates appropriate platform for private sector collaborations and an improvement in R & D in order to integrate the fast pyrolysis technology on large scale.

[1]  Mohammad. Rasul,et al.  Biofuels Production through Biomass Pyrolysis —A Technological Review , 2012 .

[2]  C. Guzmán,et al.  Characterization of the liquid products in the pyrolysis of residual chañar and palm fruit biomasses , 2014 .

[3]  U. Bacha,et al.  COMPARATIVE ASSESSMENT OF VARIOUS AGRO-INDUSTRIAL WASTES FOR SACCHAROMYCES CEREVISIAE BIOMASS PRODUCTION AND ITS QUALITY EVALUATION AS SINGLE CELL PROTEIN , 2011 .

[4]  A. Bridgwater Review of fast pyrolysis of biomass and product upgrading , 2012 .

[5]  R. Miranda,et al.  Characterization of Pyrolysis Products Obtained During the Preparation of Bio-Oil and Activated Carbon , 2012 .

[6]  G. Zeng,et al.  Study on the solubilization capacity of bio-oil in diesel by microemulsion technology with Span80 as surfactant , 2014 .

[7]  F. Kemausuor,et al.  Assessment of Feedstock Options for Biofuels Production in Ghana , 2013 .

[8]  C. Wongkhorsub,et al.  A Comparison of the Use of Pyrolysis Oils in Diesel Engine , 2013 .

[9]  A. Bridgwater,et al.  Overview of Applications of Biomass Fast Pyrolysis Oil , 2004 .

[10]  E. C. Bensah,et al.  Assessment of biomass residue availability and bioenergy yields in Ghana , 2014 .

[11]  A. Chaala,et al.  Bio-oils obtained by vacuum pyrolysis of softwood bark as a liquid fuel for gas turbines. Part I: Properties of bio-oil and its blends with methanol and a pyrolytic aqueous phase , 2000 .

[12]  Raphael Wentemi Apeaning Energy Efficiency and Management in Industries : a case study of Ghana’s largest industrial area. , 2012 .

[13]  Jesús Arauzo,et al.  Influence of temperature and particle size on the fixed bed pyrolysis of orange peel residues , 2008 .

[14]  Ger Devlin,et al.  A review of recent laboratory research and commercial developments in fast pyrolysis and upgrading , 2011 .

[15]  Tiejun Wang,et al.  A review of thermal-chemical conversion of lignocellulosic biomass in China. , 2012, Biotechnology advances.

[16]  I. S. Horváth,et al.  Production of biofuels, limonene and pectin from citrus wastes. , 2010, Bioresource technology.

[17]  M. Antal,et al.  The Art, Science, and Technology of Charcoal Production† , 2003 .

[18]  R. Saxena,et al.  Bio-fuels from thermochemical conversion of renewable resources: A review , 2008 .

[19]  K. Rezzadori,et al.  Proposals for the residues recovery: Orange waste as raw material for new products , 2012 .

[20]  K. Grohmann,et al.  Fractionation and pretreatment of orange peel by dilute acid hydrolysis , 1995 .

[21]  P. Addo‐Fordjour,et al.  Microbiological and Sensory Analysis of Imported Fruit Juices in Kumasi, Ghana , 2008 .

[22]  M. Taherzadeh,et al.  Protective Effect of Encapsulation in Fermentation of Limonene-contained Media and Orange Peel Hydrolyzate , 2007, International Journal of Molecular Sciences.

[23]  M. Fatih Demirbas,et al.  Biorefineries for biofuel upgrading: A critical review , 2009 .

[24]  Y. Solantausta,et al.  Fuel oil quality and combustion of fast pyrolysis bio-oils , 2013 .

[25]  M. Parish,et al.  Minimum inhibitory concentrations of antimicrobials against micro-organisms related to citrus juice , 1997 .

[26]  Qiang Lu,et al.  Overview of fuel properties of biomass fast pyrolysis oils , 2009 .

[27]  Acheampong,et al.  Prevalence Of Mistletoe On Citrus Trees In The Abura-Asebu-Kwamankese District Of The Central Region Of Ghana , 2013 .

[28]  S. Tsubaki,et al.  Isolation of hesperidin from peels of thinned Citrus unshiu fruits by microwave-assisted extraction. , 2010 .

[29]  P. Christakopoulos,et al.  Fungal multienzyme production on industrial by-products of the citrus-processing industry. , 2008, Bioresource technology.

[30]  D. Meier,et al.  State of the art of applied fast pyrolysis of lignocellulosic materials - a review , 1999 .

[31]  R. Miranda,et al.  Pyrolysis of sweet orange (Citrus sinensis) dry peel , 2009 .

[32]  M. Woo,et al.  Physicochemical and comparative properties of pectins extracted from Akebia trifoliata var. australis peel , 2012 .

[33]  M. Mazutti,et al.  Thermochemical processes for biofuels production from biomass , 2013 .

[34]  S. Rezzoug,et al.  Thermomechanical process intensification for oil extraction from orange peels , 2009 .

[35]  M. Taherzadeh,et al.  Improvement of Biogas Production from Orange Peel Waste by Leaching of Limonene , 2015, BioMed research international.

[36]  E. Baldwin,et al.  Hydrolysis of orange peel with pectinase and cellulase enzymes , 1992, Biotechnology Letters.

[37]  E. Baldwin,et al.  Production of ethanol from enzymatically hydrolyzed orange peel by the yeastSaccharomyces cerevisiae , 1994, Applied biochemistry and biotechnology.

[38]  A. Faaij,et al.  A bottom-up assessment and review of global bio-energy potentials to 2050 , 2007 .

[39]  Richard Arthur,et al.  Harnessing methane generated from livestock manure in Ghana, Nigeria, Mali and Burkina Faso. , 2011 .

[40]  Gisela Prasad,et al.  Improving access to energy in sub-Saharan Africa , 2011 .

[41]  C. Soler-Rivas,et al.  By-products from different citrus processes as a source of customized functional fibres , 2007 .

[42]  Abolghasem Shahbazi,et al.  Bio-oil production and upgrading research: A review , 2012 .

[43]  Anthony V. Bridgwater,et al.  Upgrading biomass fast pyrolysis liquids , 2012 .

[44]  Dongtak Lee,et al.  Optimization of narirutin extraction during washing step of the pectin production from citrus peels , 2004 .

[45]  S. Yaman Pyrolysis of biomass to produce fuels and chemical feedstocks , 2004 .