Low-temperature solid oxide fuel cells with bioalcohol fuels

Abstract Energy and environmental issues become key factors for sustainable development of society and national economy. Sustainable energy targeting opportunities for economic friendly growth of a country are commonly recognized. The growing interest is focused on the renewable energy resources because of the global energy demands increasing day by day. To meet the demands, an extensive research is aimed to develop sustainable energy devices such as solar cells, rechargeable batteries, and fuel cells. In recent years, solid oxide fuel cell (SOFC) among fuel-cell types has got more attention especially due to its fuel flexibility (e.g., different hydrocarbons, alcohols, and gasoline/diesel), high efficiency, and low emission. Thus, LTSOFC fed by direct bioethanol is receiving considerable attention as a clean, highly efficient for the production of both electricity and high-grade waste heat. These multifuel advantages provide the opportunities to develop an advanced SOFC system especially bioalcohol SOFC systems. This is a very dynamic area for SOFC applications with a promising future. It may create great energy savings and pollution reductions, if the bioalcohol fuel-based-technologies in these applications come into practical use. This chapter is focused on the development of LTSOFC operated by direct bioalcohol (bioethanol and biomethanol) for sustainable development. The content of this chapter is divided into three parts: (i) development of materials, (ii) characterization and analysis, (iii) demonstration of the nanocomposite materials in a bioalcohol FC, and (iv) case studies. Such bioalcohol FC research and development can enhance the use of sustainable/renewable energy for the society, and results achieved for applications have great potential to revolutionize the energy technology in an environmentally friendly and sustainable way.

[1]  Hubert A. Gasteiger,et al.  Handbook of fuel cells : fundamentals technology and applications , 2003 .

[2]  R. Elander,et al.  Process and economic analysis of pretreatment technologies. , 2005, Bioresource technology.

[3]  Rizwan Raza,et al.  Improved ceria-carbonate composite electrolytes , 2010 .

[4]  Kamel Halouani,et al.  Bio-methanol fueled intermediate temperature solid oxide fuel cell: A future solution as component in auxiliary power unit for eco-transportation , 2016 .

[5]  Massimiliano Cimenti,et al.  Thermodynamic analysis of solid oxide fuel cells operated with methanol and ethanol under direct utilization, steam reforming, dry reforming or partial oxidation conditions , 2009 .

[6]  Brian C. H. Steele,et al.  Intermediate temperature solid oxide fuel cells operated with methanol fuels , 2000 .

[7]  Wei Wang,et al.  Coking suppression in solid oxide fuel cells operating on ethanol by applying pyridine as fuel additive , 2014 .

[8]  Ryan O'Hayre,et al.  A review on direct methanol fuel cells–In the perspective of energy and sustainability , 2015 .

[9]  Prabhakar Singh,et al.  Direct methanol utilization in intermediate temperature liquid-tin anode solid oxide fuel cells , 2014 .

[10]  Qin Xin,et al.  Preparation and Characterization of Multiwalled Carbon Nanotube-Supported Platinum for Cathode Catalysts of Direct Methanol Fuel Cells , 2003 .

[11]  Jun Woo Kim,et al.  Bimetallic Nickel/Ruthenium Catalysts Synthesized by Atomic Layer Deposition for Low-Temperature Direct Methanol Solid Oxide Fuel Cells. , 2016, ACS applied materials & interfaces.

[12]  Antonino S. Aricò,et al.  Direct utilization of methanol in solid oxide fuel cells: An electrochemical and catalytic study , 2011 .

[13]  B. Zhu,et al.  Study on nanocomposites based on carbonate@ceria. , 2010, Journal of nanoscience and nanotechnology.

[14]  S. Srinivasan,et al.  Fuel Cells: From Fundamentals to Applications , 2006 .

[15]  Rizwan Raza,et al.  Thermal stability study of SDC/Na2CO3 nanocomposite electrolyte for low-temperature SOFCs , 2010 .

[16]  Volkmar M. Schmidt and,et al.  Electrochemical Reactivity of Ethanol on Porous Pt and PtRu: Oxidation/Reduction Reactions in 1 M HClO4 , 1996 .

[17]  Dehua Dong,et al.  Direct liquid methanol-fueled solid oxide fuel cell , 2008 .

[18]  Karl T. Chuang,et al.  Improved coking resistance of direct ethanol solid oxide fuel cells with a Ni–Sx anode , 2014 .

[19]  Panagiotis Tsiakaras,et al.  Recent progress in direct ethanol proton exchange membrane fuel cells (DE-PEMFCs) , 2006 .

[20]  R. B. Lima,et al.  Advanced Multi‐Fuelled Solid Oxide Fuel Cells (ASOFCs) Using Functional Nanocomposites for Polygeneration , 2011 .

[21]  Zhigang Zhu,et al.  Development of cathodes for methanol and ethanol fuelled low temperature (300–600 °C) solid oxide fuel cells , 2007 .

[22]  Xiang Li,et al.  Modification of coal as a fuel for the direct carbon fuel cell. , 2010, The journal of physical chemistry. A.

[23]  J. Bockris The hydrogen economy: Its history , 2013 .

[24]  Rizwan Raza,et al.  Development of methanol‐fueled low‐temperature solid oxide fuel cells , 2011 .

[25]  Wei Wang,et al.  Enhanced electrochemical performance, water storage capability and coking resistance of a Ni+BaZr0.1Ce0.7Y0.1Yb0.1O3−δ anode for solid oxide fuel cells operating on ethanol , 2015 .

[26]  Ferran Espiell,et al.  Improvement of performance in low temperature solid oxide fuel cells operated on ethanol and air mixtures using Cu–ZnO–Al2O3 catalyst layer , 2015 .

[27]  Marina Mastragostino,et al.  Electrodeposited PtRu on cryogel carbon-Nafion supports for DMFC anodes , 2006 .

[28]  Rizwan Raza,et al.  Characterization and Development of Bio-Ethanol Solid Oxide Fuel Cell , 2011 .

[29]  S. Georges,et al.  Direct ethanol solid oxide fuel cell operating in gradual internal reforming , 2012 .