Organic Semiconductors and their Applications in Photovoltaic Devices

In recent years, organic semiconductors have emerged as a promising and, in some situations, viable commercial alternative to traditional inorganic materials such as silicon. Organic-based light emitting diodes, photovoltaic devices, photodetectors, and transistors have attracted intense interest in the scientific community. In this review, we first present a discussion of the fundamental electronic nature of organic semiconductors, processing techniques, and their application to two main classes of optoelectronic devices, light emitting diodes, and photovoltaics. The second part of the review introduces organic photovoltaics in depth, including their operation principles, development history, current state of the art, and routes for further improvement.

[1]  A. J. Heeger,et al.  Semiconducting polymer diodes: Large size, low cost photodetectors with excellent visible‐ultraviolet sensitivity , 1994 .

[2]  Peng,et al.  Charge separation and transport in conjugated-polymer/semiconductor-nanocrystal composites studied by photoluminescence quenching and photoconductivity. , 1996, Physical review. B, Condensed matter.

[3]  Evan L. Williams,et al.  Excimer‐Based White Phosphorescent Organic Light‐Emitting Diodes with Nearly 100 % Internal Quantum Efficiency , 2007 .

[4]  Y. Harima,et al.  Spectral sensitization in an organic p‐n junction photovoltaic cell , 1984 .

[5]  Wei You,et al.  Fluorine substituted conjugated polymer of medium band gap yields 7% efficiency in polymer-fullerene solar cells. , 2011, Journal of the American Chemical Society.

[6]  J. Hummelen,et al.  Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions , 1995, Science.

[7]  J. Xue,et al.  Effects of nanocrystal size and device aging on performance of hybrid poly(3-hexylthiophene):CdSe nanocrystal solar cells , 2011 .

[8]  Paul A. van Hal,et al.  Efficient methano[70]fullerene/MDMO-PPV bulk heterojunction photovoltaic cells. , 2003, Angewandte Chemie.

[9]  Garry Rumbles,et al.  Performance of bulk heterojunction photovoltaic devices prepared by airbrush spray deposition , 2008 .

[10]  Yang Yang,et al.  High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends , 2005 .

[11]  M. Green,et al.  24·5% Efficiency silicon PERT cells on MCZ substrates and 24·7% efficiency PERL cells on FZ substrates , 1999 .

[12]  S. Möller,et al.  A polymer/semiconductor write-once read-many-times memory , 2003, Nature.

[13]  Peter Peumans,et al.  An effective light trapping configuration for thin-film solar cells , 2007 .

[14]  Olle Inganäs,et al.  Trapping light with micro lenses in thin film organic photovoltaic cells. , 2008, Optics express.

[15]  Haruo Tanaka,et al.  Switching effect in Cu:TCNQ charge transfer-complex thin films by vacuum codeposition , 2003 .

[16]  Stephen R. Forrest,et al.  Separation of geminate charge-pairs at donor–acceptor interfaces in disordered solids , 2004 .

[17]  C. H. You,et al.  Electrical bistabilities and memory mechanisms of organic bistable devices based on colloidal ZnO quantum dot-polymethylmethacrylate polymer nanocomposites , 2009 .

[18]  Stephen R. Forrest,et al.  High photovoltage multiple-heterojunction organic solar cells incorporating interfacial metallic nanoclusters , 2002 .

[19]  Tetsuo Tsutsui,et al.  Preparation of organic bulk heterojunction photovoltaic cells by evaporative spray deposition from ultradilute solution , 2004 .

[20]  Bonnie A. Sheriff,et al.  A 160-kilobit molecular electronic memory patterned at 1011 bits per square centimetre , 2007, Nature.

[21]  Gang Li,et al.  For the Bright Future—Bulk Heterojunction Polymer Solar Cells with Power Conversion Efficiency of 7.4% , 2010, Advanced materials.

[22]  Nils-Krister Persson,et al.  Surface plasmon increase absorption in polymer photovoltaic cells , 2007 .

[23]  Kevin Robbie,et al.  Advanced techniques for glancing angle deposition , 1998 .

[24]  Takeo Kawase,et al.  Very high-mobility organic single-crystal transistors with in-crystal conduction channels , 2007 .

[25]  Stephen R. Forrest,et al.  EXCITONIC SINGLET-TRIPLET RATIO IN A SEMICONDUCTING ORGANIC THIN FILM , 1999 .

[26]  Stephen R. Forrest,et al.  Organic photodetector arrays with indium tin oxide electrodes patterned using directly transferred metal masks , 2009 .

[27]  Frederik C. Krebs,et al.  Polymer solar cell modules prepared using roll-to-roll methods: Knife-over-edge coating, slot-die coating and screen printing , 2009 .

[28]  Richa Pandey,et al.  Graded Donor‐Acceptor Heterojunctions for Efficient Organic Photovoltaic Cells , 2010, Advanced materials.

[29]  A Paul Alivisatos,et al.  Photovoltaic devices employing ternary PbSxSe1-x nanocrystals. , 2009, Nano letters.

[30]  C. Brabec,et al.  Influence of Molecular Weight Distribution on the Gelation of P3HT and Its Impact on the Photovoltaic Performance , 2009 .

[31]  Maxim Shkunov,et al.  High ambipolar and balanced carrier mobility in regioregular poly(3-hexylthiophene) , 2004 .

[32]  Hiroshi Fujiwara,et al.  p‐i‐n like behavior in three‐layered organic solar cells having a co‐deposited interlayer of pigments , 1992 .

[33]  Junji Kido,et al.  Highly Efficient Organic Blue‐and White‐Light‐Emitting Devices Having a Carrier‐ and Exciton‐Confining Structure for Reduced Efficiency Roll‐Off , 2008 .

[34]  Manikandan Jayaraman,et al.  Self-orienting head-to-tail poly(3-alkylthiophenes): new insights on structure-property relationships in conducting polymers , 1993 .

[35]  N. Greenham,et al.  Improved efficiency of photovoltaics based on CdSe nanorods and poly(3-hexylthiophene) nanofibers. , 2006, Physical chemistry chemical physics : PCCP.

[36]  F. So,et al.  White phosphorescent organic light-emitting devices with dual triple-doped emissive layers , 2009 .

[37]  Donal D. C. Bradley,et al.  Studies of Highly Regioregular Poly(3‐hexylselenophene) for Photovoltaic Applications , 2007 .

[38]  Stephen R. Forrest,et al.  Open circuit voltage enhancement due to reduced dark current in small molecule photovoltaic cells , 2009 .

[39]  Guo-Qiang Lo,et al.  Efficient tandem organic solar cells with an Al/MoO3 intermediate layer , 2008 .

[40]  Richard S. Potember,et al.  Electrical switching and memory phenomena in Cu‐TCNQ thin films , 1979 .

[41]  C. Tang Two‐layer organic photovoltaic cell , 1986 .

[42]  Stephen R. Forrest,et al.  Management of singlet and triplet excitons for efficient white organic light-emitting devices , 2006, Nature.

[43]  George G. Malliaras,et al.  Temperature- and field-dependent electron and hole mobilities in polymer light-emitting diodes , 1999 .

[44]  J. C. Scott,et al.  Nonvolatile Memory Elements Based on Organic Materials , 2007 .

[45]  David Braun,et al.  Semiconducting polymer‐buckminsterfullerene heterojunctions: Diodes, photodiodes, and photovoltaic cells , 1993 .

[46]  Ardie D. Walser,et al.  Bimolecular reactions of singlet excitons in tris(8-hydroxyquinoline) aluminum , 1996 .

[47]  A J Heeger,et al.  Efficiency enhancement in low-bandgap polymer solar cells by processing with alkane dithiols. , 2007, Nature materials.

[48]  S. Forrest,et al.  Inverted organic photovoltaic cells with high open-circuit voltage , 2010 .

[49]  Richard H. Friend,et al.  General observation of n-type field-effect behaviour in organic semiconductors , 2005, Nature.

[50]  S. Forrest,et al.  Highly efficient phosphorescent emission from organic electroluminescent devices , 1998, Nature.

[51]  Nelson E. Coates,et al.  Bulk heterojunction solar cells with internal quantum efficiency approaching 100 , 2009 .

[52]  R. Service,et al.  Solar energy. Outlook brightens for plastic solar cells. , 2011, Science.

[53]  P. Holloway,et al.  Down‐Conversion White Organic Light‐Emitting Diodes Using Microcavity Structure , 2011 .

[54]  Wei You,et al.  Development of fluorinated benzothiadiazole as a structural unit for a polymer solar cell of 7 % efficiency. , 2011, Angewandte Chemie.

[55]  J. Takeya Organic Single-Crystal Field-Effect Transistors , 2009 .

[56]  S. Forrest,et al.  Molecular and morphological influences on the open circuit voltages of organic photovoltaic devices. , 2009, Journal of the American Chemical Society.

[57]  S. Forrest,et al.  Carrier transport in multilayer organic photodetectors: I. Effects of layer structure on dark current and photoresponse , 2004 .

[58]  Jian Xu,et al.  Harvest of near infrared light in PbSe nanocrystal-polymer hybrid photovoltaic cells , 2006 .

[59]  Christoph J. Brabec,et al.  Polymer photovoltaic detectors: progress and recent developments , 2004 .

[60]  G. Horowitz,et al.  Electrochemically grown polythiophene and poly(3-methylthiophene) organic photovoltaic cells , 1984 .

[61]  Torahiko Ando,et al.  Macromolecular electronic device: Field-effect transistor with a polythiophene thin film , 1986 .

[62]  L. Feldman,et al.  Observation of long-range exciton diffusion in highly ordered organic semiconductors. , 2010, Nature materials.

[63]  Donald W. Brenner,et al.  A second-generation reactive empirical bond order (REBO) potential energy expression for hydrocarbons , 2002 .

[64]  Luping Yu,et al.  Development of new semiconducting polymers for high performance solar cells. , 2009, Journal of the American Chemical Society.

[65]  Mario Leclerc,et al.  Design and synthesis of conjugated polymers , 2010 .

[66]  Wilhelm Warta,et al.  High-field saturation of charge carrier drift velocities in ultrapurified organic photoconductors , 1991 .

[67]  S. Forrest,et al.  Organic solar cells with sensitivity extending into the near infrared , 2005 .

[68]  Stephen R. Forrest,et al.  Efficient, high-bandwidth organic multilayer photodetectors , 2000 .

[69]  S. Forrest,et al.  Bipolar doping between a molecular organic donor-acceptor couple , 2004 .

[70]  G. Hadziioannou,et al.  Organic co-evaporated films of a PPV-pentamer and C60: model systems for donor/acceptor polymer blends , 2002 .

[71]  Kamal Asadi,et al.  Organic non-volatile memories from ferroelectric phase-separated blends. , 2008, Nature materials.

[72]  A. Heeger,et al.  Nanostructure of the Interpenetrating Networks in Poly(3‐hexylthiophene)/fullerene Bulk Heterojunction Materials: Implications for Charge Transport , 2007 .

[73]  Wei Lin Leong,et al.  Charging phenomena in pentacene-gold nanoparticle memory device , 2007 .

[74]  M. Pope,et al.  Photovoltaic Effect in Organic Crystals , 1959 .

[75]  G. Wegner,et al.  Structural analysis of poly(3‐alkylthiophene)s , 1989 .

[76]  Ying Zheng,et al.  Organic photovoltaic cells with vertically aligned crystalline molecular nanorods , 2009 .

[77]  Stephen R. Forrest,et al.  Asymmetric tandem organic photovoltaic cells with hybrid planar-mixed molecular heterojunctions , 2004 .

[78]  Yi Cui,et al.  Solution-processed metal nanowire mesh transparent electrodes. , 2008, Nano letters.

[79]  Paul Heremans,et al.  Structural evolution of evaporated lead phthalocyanine thin films for near-infrared sensitive solar cells , 2011 .

[80]  D. Ginger,et al.  Plasmon-enhanced charge carrier generation in organic photovoltaic films using silver nanoprisms. , 2010, Nano letters.

[81]  D. Vuillaume,et al.  Metal∕organic∕metal bistable memory devices , 2004, cond-mat/0409758.

[82]  I. Hill,et al.  Improved organic thin-film transistor performance using novel self-assembled monolayers , 2006 .

[83]  Y. Shirota Organic materials for electronic and optoelectronic devices , 2000 .

[84]  Ghassan E. Jabbour,et al.  Organic-Based Photovoltaics: Toward Low-Cost Power Generation , 2005 .

[85]  Sam-Shajing Sun,et al.  Organic Photovoltaics : Mechanisms, Materials, and Devices , 2005 .

[86]  Kai-Ming Ho,et al.  On Realizing Higher Efficiency Polymer Solar Cells Using a Textured Substrate Platform , 2011, Advanced materials.

[87]  Stephen R. Forrest,et al.  Direct mask-free patterning of molecular organic semiconductors using organic vapor jet printing , 2004 .

[88]  Chihaya Adachi,et al.  100% phosphorescence quantum efficiency of Ir(III) complexes in organic semiconductor films , 2005 .

[89]  Tobin J. Marks,et al.  Gate Dielectrics for Organic Field‐Effect Transistors: New Opportunities for Organic Electronics , 2005 .

[90]  Gang Li,et al.  Efficient light harvesting in multiple-device stacked structure for polymer solar cells , 2006 .

[91]  Olle Inganäs,et al.  Fabrication of a light trapping system for organic solar cells , 2009 .

[92]  Stephen R. Forrest,et al.  Small molecular weight organic thin-film photodetectors and solar cells , 2003 .

[93]  N. Greenham,et al.  Photovoltaic Devices Using Blends of Branched CdSe Nanoparticles and Conjugated Polymers , 2003 .

[94]  S. M. Sze,et al.  Physics of semiconductor devices , 1969 .

[95]  O. Inganäs,et al.  Multifolded Polymer Solar Cells on Flexible Substrates , 2008 .

[96]  Wolfgang Brütting,et al.  Physics of organic semiconductors , 2004 .

[97]  A. Pal,et al.  Multilevel conductance and memory in ultrathin organic films , 2004 .

[98]  N. E. Coates,et al.  Efficient Tandem Polymer Solar Cells Fabricated by All-Solution Processing , 2007, Science.

[99]  Kimoon Lee,et al.  Flexible low voltage nonvolatile memory transistors with pentacene channel and ferroelectric polymer , 2009 .

[100]  Valentin D. Mihailetchi,et al.  Device Physics of Polymer:Fullerene Bulk Heterojunction Solar Cells , 2007 .

[101]  G. Chamberlain,et al.  Photovoltaic properties of merocyanine solid-state photocells , 1981, Nature.

[102]  Zhenan Bao,et al.  Organic solar cells with solution-processed graphene transparent electrodes , 2008 .

[103]  R. Holmes,et al.  Investigation of Energy Transfer in Organic Photovoltaic Cells and Impact on Exciton Diffusion Length Measurements , 2011 .

[104]  Stephen R. Forrest,et al.  Efficient bulk heterojunction photovoltaic cells using small-molecular-weight organic thin films , 2003, Nature.

[105]  Stephen R. Forrest,et al.  Ultrathin Organic Films Grown by Organic Molecular Beam Deposition and Related Techniques. , 1997, Chemical reviews.

[106]  M. Heuken,et al.  Organic Vapor Phase Deposition , 2006 .

[107]  T. Kawase,et al.  High-mobility double-gate organic single-crystal transistors with organic crystal gate insulators , 2007 .

[108]  U. Kortshagen,et al.  Hybrid solar cells from P3HT and silicon nanocrystals. , 2009, Nano letters.

[109]  Stephen R. Forrest,et al.  Transient analysis of organic electrophosphorescence: I. Transient analysis of triplet energy transfer , 2000 .

[110]  Jianyong Ouyang,et al.  Nonvolatile electrical bistability of organic/metal-nanocluster/organic system , 2003 .

[111]  C. Tang,et al.  Organic Electroluminescent Diodes , 1987 .

[112]  D. Ginley,et al.  Photovoltaic devices with a low band gap polymer and CdSe nanostructures exceeding 3% efficiency. , 2010, Nano letters.

[113]  Richard R. Lunt,et al.  Transparent, near-infrared organic photovoltaic solar cells for window and energy-scavenging applications , 2011 .

[114]  Juhwan Kim,et al.  Fabrication of organic bulk heterojunction solar cells by a spray deposition method for low-cost power generation , 2007 .

[115]  J. Kasahara,et al.  A high-performance short-channel bottom-contact OTFT and its application to AM-TN-LCD , 2005, IEEE Transactions on Electron Devices.

[116]  S. Forrest,et al.  Carrier transport in multilayer organic photodetectors: II. Effects of anode preparation , 2004 .

[117]  Stephen R. Forrest,et al.  Very-high-efficiency double-heterostructure copper phthalocyanine/C60 photovoltaic cells , 2001 .

[118]  Moses,et al.  Ultrafast spectroscopic studies of photoinduced electron transfer from semiconducting polymers to C60. , 1994, Physical review. B, Condensed matter.

[119]  C. Brabec,et al.  2.5% efficient organic plastic solar cells , 2001 .

[120]  Stephen R. Forrest,et al.  Micropatterning of small molecular weight organic semiconductor thin films using organic vapor phase deposition , 2003 .

[121]  H. Klauk,et al.  Organic thin-film transistors for organic light-emitting flat-panel display backplanes , 1998 .

[122]  B. Derby Inkjet Printing of Functional and Structural Materials: Fluid Property Requirements, Feature Stability, and Resolution , 2010 .

[123]  Donghang Yan,et al.  Organic photovoltaic cells with near infrared absorption spectrum , 2007 .

[124]  Galileo Sarasqueta,et al.  SnPc:C60 bulk heterojunction organic photovoltaic cells with MoO3 interlayer , 2009 .

[125]  Viktor Andersson,et al.  Folded reflective tandem polymer solar cell doubles efficiency , 2007 .

[126]  Bernard Geffroy,et al.  Implementation of submicrometric periodic surface structures toward improvement of organic-solar-cell performances , 2006 .

[127]  M. I. Khan,et al.  Study of Carrier Generation in Titanyl Phthalocyanine (TiOPc) by Electric-Field-Induced Quenching of Integrated and Time-Resolved Fluorescence , 1998 .

[128]  F. So,et al.  Effect of the charge balance on high-efficiency blue-phosphorescent organic light-emitting diodes. , 2009, ACS applied materials & interfaces.

[129]  Gong Gu,et al.  Electron traps and hysteresis in pentacene-based organic thin-film transistors , 2005 .

[130]  Stephen R. Forrest,et al.  Direct patterning of organic light-emitting devices by organic-vapor jet printing , 2005 .

[131]  Stephen R. Forrest,et al.  A Hybrid Planar–Mixed Molecular Heterojunction Photovoltaic Cell , 2005 .

[132]  P. Sullivan,et al.  Structural templating as a route to improved photovoltaic performance in copper phthalocyanine/fullerene (C60) heterojunctions , 2007 .

[133]  J. Xue,et al.  Photocarrier behavior in organic heterojunction photovoltaic cells , 2009 .

[134]  Martijn Lenes,et al.  Small Bandgap Polymers for Organic Solar Cells (Polymer Material Development in the Last 5 Years) , 2008 .

[135]  Yang Yang,et al.  Polymer solar cells with enhanced open-circuit voltage and efficiency , 2009 .

[136]  Yoon-Chae Nah,et al.  Plasmon enhanced performance of organic solar cells using electrodeposited Ag nanoparticles , 2008 .

[137]  Stephen R. Forrest,et al.  White Organic Light‐Emitting Devices for Solid‐State Lighting , 2004 .

[138]  A. Heeger,et al.  High Sensitivity Polymer Photosensors for Image Sensing Applications , 1999 .

[139]  Mario Leclerc,et al.  A Low‐Bandgap Poly(2,7‐Carbazole) Derivative for Use in High‐Performance Solar Cells , 2007 .

[140]  A. J. Heeger,et al.  Photoinduced Electron Transfer from a Conducting Polymer to Buckminsterfullerene , 1992, Science.

[141]  A. Heeger,et al.  The Role of Processing in the Fabrication and Optimization of Plastic Solar Cells , 2009 .

[142]  Amal K. Ghosh,et al.  Merocyanine organic solar cells , 1978 .

[143]  Helmut Neugebauer,et al.  A new encapsulation solution for flexible organic solar cells , 2006 .

[144]  Masahiro Hiramoto,et al.  Effect of Thin Gold Interstitial-layer on the Photovoltaic Properties of Tandem Organic Solar Cell , 1990 .

[145]  Tracey M. Clarke,et al.  Understanding the Influence of Morphology on Poly(3-hexylselenothiophene):PCBM Solar Cells , 2010 .

[146]  N. Karl Organic Semiconductors: Purification and Crystal Growth , 1989 .

[147]  Xiong Gong,et al.  Thermally Stable, Efficient Polymer Solar Cells with Nanoscale Control of the Interpenetrating Network Morphology , 2005 .

[148]  Tetsuo Takahashi,et al.  Electron transport in rubrene single-crystal transistors , 2010 .

[149]  D. Meissner,et al.  Monochromatic versus solar efficiencies of organic solar cells , 2000 .

[150]  Donal D. C. Bradley,et al.  The photovoltaic response in poly(p-phenylene vinylene) thin-film devices , 1994 .

[151]  F. So,et al.  Effect of electron injection and transport materials on efficiency of deep-blue phosphorescent organic light-emitting devices , 2009 .

[152]  H. Kuroda,et al.  Structure of lead phthalocyanine (triclinic form) , 1982 .

[153]  Timothy D Heidel,et al.  High-Efficiency Organic Solar Concentrators for Photovoltaics , 2008, Science.

[154]  J. Kanicki,et al.  Electrical and photovoltaic properties of trans-polyacetylene , 1984 .

[155]  Wje Waldo Beek,et al.  Hybrid Solar Cells from Regioregular Polythiophene and ZnO Nanoparticles , 2006 .

[156]  A. Gombert,et al.  Functional microprism substrate for organic solar cells , 2006 .

[157]  M. Grell,et al.  Determination of the linear optical constants of poly(9,9-dioctylfluorene) , 2001 .

[158]  Martin A. Green,et al.  Solar cell efficiency tables (version 37) , 2011 .

[159]  Stephen R. Forrest,et al.  Direct, Mask‐ and Solvent‐Free Printing of Molecular Organic Semiconductors , 2004 .

[160]  Gregor Schwartz,et al.  White organic light-emitting diodes with fluorescent tube efficiency , 2009, Nature.

[161]  Gang Li,et al.  Highly efficient solar cell polymers developed via fine-tuning of structural and electronic properties. , 2009, Journal of the American Chemical Society.

[162]  C. A. Walsh,et al.  Efficient photodiodes from interpenetrating polymer networks , 1995, Nature.

[163]  Jiangeng Xue,et al.  Perspectives on Organic Photovoltaics , 2010 .

[164]  Barry P Rand,et al.  Near-infrared sensitive small molecule organic photovoltaic cells based on chloroaluminum phthalocyanine , 2007 .

[165]  T. Jackson,et al.  Stacked pentacene layer organic thin-film transistors with improved characteristics , 1997, IEEE Electron Device Letters.

[166]  P. Heremans,et al.  Strategies for Increasing the Efficiency of Heterojunction Organic Solar Cells: Material Selection and Device Architecture , 2010 .

[167]  Dongho Lee,et al.  Efficient Heterojunction Photovoltaic Cell Utilizing Nanocomposites of Lead Sulfide Nanocrystals and a Low‐Bandgap Polymer , 2011, Advanced materials.

[168]  Fan Yang,et al.  Photocurrent generation in nanostructured organic solar cells. , 2008, ACS nano.

[169]  Jie Yao,et al.  Preparation and Characterization of Fulleroid and Methanofullerene Derivatives , 1995 .

[170]  R. Yuan,et al.  Characteristics of heterojunction diode of C60/chloroindium phthalocyanine , 1995 .

[171]  C. Brabec,et al.  Effect of LiF/metal electrodes on the performance of plastic solar cells , 2002 .

[172]  K. Schulten,et al.  The crystal structure of the light-harvesting complex II (B800-850) from Rhodospirillum molischianum. , 1996, Structure.

[173]  Srinivas Sista,et al.  Highly Efficient Tandem Polymer Photovoltaic Cells , 2010, Advanced materials.

[174]  S. Forrest,et al.  Nearly 100% internal phosphorescence efficiency in an organic light emitting device , 2001 .

[175]  Charles R. Szmanda,et al.  Programmable polymer thin film and non-volatile memory device , 2004, Nature materials.

[176]  Stephen R. Forrest,et al.  Long-range absorption enhancement in organic tandem thin-film solar cells containing silver nanoclusters , 2004 .

[177]  Uli Lemmer,et al.  Organic tandem solar cells comprising polymer and small-molecule subcells , 2006 .

[178]  Mario Leclerc,et al.  Processable Low-Bandgap Polymers for Photovoltaic Applications† , 2011 .

[179]  S. Forrest,et al.  Direct transfer patterning on three dimensionally deformed surfaces at micrometer resolutions and its application to hemispherical focal plane detector arrays , 2008 .

[180]  Barry P Rand,et al.  Enhanced open-circuit voltage in subphthalocyanine/C60 organic photovoltaic cells. , 2006, Journal of the American Chemical Society.

[181]  I. Samuel,et al.  Exciton Diffusion Measurements in Poly(3‐hexylthiophene) , 2008 .

[182]  R. D. Mccullough,et al.  Advanced Functional Regioregular Polythiophenes , 2010 .

[183]  J. Xue,et al.  Enhancing light harvesting in organic solar cells with pyramidal rear reflectors , 2011 .

[184]  Barry P Rand,et al.  4.2% efficient organic photovoltaic cells with low series resistances , 2004 .

[185]  Stephen R. Forrest,et al.  Mixed donor-acceptor molecular heterojunctions for photovoltaic applications. I. Material properties , 2005 .

[186]  J A Rogers,et al.  Intrinsic charge transport on the surface of organic semiconductors. , 2004, Physical review letters.

[187]  Stephen R. Forrest,et al.  The path to ubiquitous and low-cost organic electronic appliances on plastic , 2004, Nature.

[188]  Martin A. Green,et al.  Third generation photovoltaics , 2002, 2002 Conference on Optoelectronic and Microelectronic Materials and Devices. COMMAD 2002. Proceedings (Cat. No.02EX601).

[189]  Charles E. Swenberg,et al.  Electronic Processes in Organic Crystals and Polymers , 1999 .

[190]  Arno F. Stassen,et al.  Organic small molecule field-effect transistors with Cytop™ gate dielectric: Eliminating gate bias stress effects , 2007 .

[191]  J. Moon,et al.  High-Detectivity Polymer Photodetectors with Spectral Response from 300 nm to 1450 nm , 2009, Science.

[192]  Donal D. C. Bradley,et al.  A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene:fullerene solar cells , 2006 .

[193]  Frederik C. Krebs,et al.  All solution roll-to-roll processed polymer solar cells free from indium-tin-oxide and vacuum coating steps , 2009 .

[194]  S. Jeon,et al.  Organic bistable memory device using MoO3 nanocrystal as a charge trapping center , 2009 .

[195]  Stephen R. Forrest,et al.  Organic small molecule solar cells with a homogeneously mixed copper phthalocyanine: C60 active layer , 2004 .

[196]  Peidong Yang,et al.  ZnO-TiO2 Core-Shell Nanorod/P3HT Solar Cells , 2007 .

[197]  J. Xue,et al.  Interdigitated Bulk Heterojunction Organic Photovoltaic Cells With Aligned Copper Phthalocyanine Nanorods , 2010, IEEE Journal of Selected Topics in Quantum Electronics.

[198]  Yong Cao,et al.  Development of novel conjugated donor polymers for high-efficiency bulk-heterojunction photovoltaic devices. , 2009, Accounts of chemical research.

[199]  Neal R. Armstrong,et al.  Planar and textured heterojunction organic photovoltaics based on chloroindium phthalocyanine (ClInPc) versus titanyl phthalocyanine (TiOPc) donor layers , 2011 .

[200]  A. Alivisatos,et al.  Hybrid Nanorod-Polymer Solar Cells , 2002, Science.

[201]  Wolfgang Kowalsky,et al.  Highly efficient organic tandem solar cells using an improved connecting architecture , 2007 .

[202]  Tae Whan Kim,et al.  Multilevel nonvolatile memory effects in hybrid devices containing CdSe∕ZnS nanoparticle double arrays embedded in the C60 matrices , 2008 .

[203]  J. Meiss,et al.  Improved bulk heterojunction organic solar cells employing C70 fullerenes , 2009 .

[204]  S. Sinnott,et al.  Computational and experimental studies of phase separation in pentacene:C60 mixtures , 2009 .

[205]  Jea-Gun Park,et al.  Multilevel nonvolatile small-molecule memory cell embedded with Ni nanocrystals surrounded by a NiO tunneling barrier. , 2009, Nano letters.

[206]  U. Schubert,et al.  Inkjet Printing of Polymers: State of the Art and Future Developments , 2004 .

[207]  J. Xue,et al.  Organic Photovoltaic Cells Based on Molecular Donor-Acceptor Heterojunctions , 2010 .

[208]  J. Xue,et al.  Organic heterojunction photodiodes exhibiting low voltage, imaging-speed photocurrent gain , 2010 .

[209]  Michael A. Haase,et al.  Pentacene-based radio-frequency identification circuitry , 2003 .

[210]  Vishal Shrotriya,et al.  Organic photovoltaics: Polymer power , 2009 .