Luminescence from oriented emitting dipoles in a birefringent medium.

We present an optical model to describe the luminescence from oriented emitting dipoles in a birefringent medium and validate the theoretical model through its applications to a dye doped organic thin film and organic light emitting diodes (OLEDs). We demonstrate that the optical birefringence affects not only far-field radiation characteristics such as the angle-dependent emission spectrum and intensity from the thin film and OLEDs, but also the outcoupling efficiency of OLEDs. The orientation of emitting dipoles in a birefringent medium is successfully analyzed from the far-field radiation pattern of a thin film using the model. In addition, the birefringent model presented here provides a precise analysis of the angle-dependent EL spectra and efficiencies of OLEDs with the determined emitting dipole orientation.

[1]  E. Purcell,et al.  Resonance Absorption by Nuclear Magnetic Moments in a Solid , 1946 .

[2]  Jeroen Beeckman,et al.  Dipole radiation within one-dimensional anisotropic microcavities: a simulation method. , 2011, Optics express.

[3]  Ifor D. W. Samuel,et al.  Effects of dipole orientation and birefringence on the optical emission from thin films , 2000 .

[4]  Kristiaan Neyts,et al.  Determining emissive dipole orientation in organic light emitting devices by decay time measurement , 2012 .

[5]  D. Michaelis,et al.  Evidence for non-isotropic emitter orientation in a red phosphorescent organic light-emitting diode and its implications for determining the emitter’s radiative quantum efficiency , 2011 .

[6]  J. Kido,et al.  Wide‐Range Refractive Index Control of Organic Semiconductor Films Toward Advanced Optical Design of Organic Optoelectronic Devices , 2012, Advanced materials.

[7]  E. Purcell Spontaneous Emission Probabilities at Radio Frequencies , 1995 .

[8]  Karl Leo,et al.  Efficiency and rate of spontaneous emission in organic electroluminescent devices , 2012 .

[9]  Kwon-Hyeon Kim,et al.  Low Roll‐Off and High Efficiency Orange Organic Light Emitting Diodes with Controlled Co‐Doping of Green and Red Phosphorescent Dopants in an Exciplex Forming Co‐Host , 2013 .

[10]  Jang‐Joo Kim,et al.  Highly efficient inverted top emitting organic light emitting diodes using a transparent top electrode with color stability on viewing angle , 2014 .

[11]  Tobias D. Schmidt,et al.  Oriented phosphorescent emitters boost OLED efficiency , 2011 .

[12]  Christian Mayr,et al.  Organic Light‐Emitting Diodes with 30% External Quantum Efficiency Based on a Horizontally Oriented Emitter , 2013 .

[13]  Y. Chien,et al.  Anisotropic optical properties and molecular orientation in vacuum-deposited ter(9,9-diarylfluorene)s thin films using spectroscopic ellipsometry , 2004 .

[14]  W. Barnes,et al.  Fluorescence near interfaces: The role of photonic mode density , 1998 .

[15]  J. Sturm,et al.  Optimization of external coupling and light emission in organic light-emitting devices: modeling and experiment , 2002 .

[16]  Chunliang Lin,et al.  Influences of resonant wavelengths on performances of microcavity organic light-emitting devices , 2007 .

[17]  Wolfgang Brütting,et al.  Determination of molecular dipole orientation in doped fluorescent organic thin films by photoluminescence measurements , 2010 .

[18]  Stephen R. Forrest,et al.  Weak microcavity effects in organic light-emitting devices , 1998 .

[19]  J. Kido,et al.  Influence of Substituted Pyridine Rings on Physical Properties and Electron Mobilities of 2‐Methylpyrimidine Skeleton‐Based Electron Transporters , 2011 .

[20]  Akio Sakaguchi,et al.  Horizontal molecular orientation in vacuum-deposited organic amorphous films of hole and electron transport materials , 2008 .

[21]  Caroline Murawski,et al.  Comparing the emissive dipole orientation of two similar phosphorescent green emitter molecules in highly efficient organic light-emitting diodes , 2012 .

[22]  K. Leo,et al.  Quantification of energy loss mechanisms in organic light-emitting diodes , 2010 .

[23]  Kwon-Hyeon Kim,et al.  Highly Efficient Organic Light‐Emitting Diodes with Phosphorescent Emitters Having High Quantum Yield and Horizontal Orientation of Transition Dipole Moments , 2014, Advanced materials.

[24]  Andreas Bräuer,et al.  Orientation of emissive dipoles in OLEDs: Quantitative in situ analysis , 2010 .

[25]  J. A. E. Wasey,et al.  Efficiency of spontaneous emission from planar microcavities , 2000 .

[26]  Kwon-Hyeon Kim,et al.  A Fluorescent Organic Light‐Emitting Diode with 30% External Quantum Efficiency , 2014, Advanced materials.

[27]  Ifor D. W. Samuel,et al.  Light Out‐Coupling Efficiencies of Organic Light‐Emitting Diode Structures and the Effect of Photoluminescence Quantum Yield , 2005 .

[28]  Kwon-Hyeon Kim,et al.  Exciplex‐Forming Co‐host for Organic Light‐Emitting Diodes with Ultimate Efficiency , 2013 .

[29]  D Murphy,et al.  Highly phosphorescent bis-cyclometalated iridium complexes: synthesis, photophysical characterization, and use in organic light emitting diodes. , 2001, Journal of the American Chemical Society.

[30]  Kwon-Hyeon Kim,et al.  Blue Phosphorescent Organic Light‐Emitting Diodes Using an Exciplex Forming Co‐host with the External Quantum Efficiency of Theoretical Limit , 2014, Advanced materials.

[31]  Ifor D. W. Samuel,et al.  Efficiency of radiative emission from thin films of a light-emitting conjugated polymer , 2001 .

[32]  Kwon-Hyeon Kim,et al.  Langevin and Trap‐Assisted Recombination in Phosphorescent Organic Light Emitting Diodes , 2014 .

[33]  R. Silbey,et al.  Molecular Fluorescence and Energy Transfer Near Interfaces , 2007 .

[34]  Chang-Ki Moon,et al.  Highly Enhanced Light Extraction from Surface Plasmonic Loss Minimized Organic Light‐Emitting Diodes , 2013, Advanced materials.

[35]  Stefan Nowy,et al.  Light extraction and optical loss mechanisms in organic light-emitting diodes: Influence of the emitter quantum efficiency , 2008 .

[36]  D. Yokoyama Molecular orientation in small-molecule organic light-emitting diodes , 2011 .

[37]  Sei-Yong Kim,et al.  Outcoupling efficiency of organic light emitting diodes and the effect of ITO thickness , 2010 .

[38]  Jang‐Joo Kim,et al.  A high performance transparent inverted organic light emitting diode with 1,4,5,8,9,11-hexaazatriphenylenehexacarbonitrile as an organic buffer layer , 2012 .

[39]  Kristiaan Neyts,et al.  Simulation of light emission from thin-film microcavities , 1998 .

[40]  Chung-Chih Wu,et al.  Enhancing light outcoupling of organic light-emitting devices by locating emitters around the second antinode of the reflective metal electrode , 2006 .