Prediction of time dependent chloride transport in concrete structures exposed to a marine environment

Abstract A survey of 11 concrete bridges located in a marine environment at 0.65–48.65 years was examined in terms of chloride transport. As a result, the apparent diffusion coefficient ( D ) and the surface chloride concentration ( C S ) are time dependent; the D exponentially decreased with time and the C S increased in the form of a logarithm function to time. Using these data, governing equations for the D and C S were derived to predict the chloride transport in a long term. The time dependent model indicated the higher chloride ingresses in ordinary Portland cement (OPC) concrete than the time independent model, due to a build-up of the C S with time, but ground granulated blast furnace slag (GGBS) concrete indicated a similar range of the chloride ingresses, due to the rapid decrease in the D . To ensure the accuracy of the model that the present study suggested, the fitted model was compared to the well known model of the LIFE 365 together with a chloride profile obtained from an in-situ examination. Then it was found that the model in the present study well predicted the rate of chloride transport, while the LIFE 365 indicated a poor description of the chloride ingress in a long term, due to a constant C S and an overwhelming rapid decrease in the D .

[1]  Seung-Woo Han,et al.  Service life estimation of concrete bridge decks , 2006 .

[2]  P. B. Bamforth,et al.  The derivation of input data for modelling chloride ingress from eight-year UK coastal exposure trials , 1999 .

[3]  C. Page,et al.  Aspects of the electrochemistry of steel in concrete , 1982, Nature.

[4]  K C Clear,et al.  Effectiveness of epoxy-coated reinforcing steel , 1992 .

[5]  K. Scrivener,et al.  What causes differences of C-S-H gel grey levels in backscattered electron images? , 2002 .

[6]  Hyung-seop Shim Corner effect on chloride ion diffusion in rectangular concrete media , 2002 .

[7]  William Feller,et al.  An Introduction to Probability Theory and Its Applications , 1967 .

[8]  J. C. Jaeger,et al.  Conduction of Heat in Solids , 1952 .

[9]  C. L. Page,et al.  The influence of different cements on chloride-induced corrosion of reinforcing steel , 1986 .

[10]  G. Glass,et al.  The influence of chloride binding on the chloride induced corrosion risk in reinforced concrete , 2000 .

[11]  Rasheeduzzafar,et al.  Corrosion Resistance Performance of Fly Ash Blended Cement Concrete , 1994 .

[12]  Richard E. Weyers,et al.  CONCRETE BRIDGE PROTECTION AND REHABILITATION: CHEMICAL AND PHYSICAL TECHNIQUES. SERVICE LIFE ESTIMATES , 1993 .

[13]  Ravindra K. Dhir,et al.  Chloride binding in GGBS concrete , 1996 .

[14]  K. C. Liam,et al.  Chloride ingress measurements and corrosion potential mapping study of a 24-year-old reinforced concrete jetty structure in a tropical marine environment , 1992 .

[15]  A. P. Crane Corrosion of reinforcement in concrete construction , 1983 .

[16]  C. Page Mechanism of corrosion protection in reinforced concrete marine structures , 1975, Nature.

[17]  M. Collepardi,et al.  Penetration of Chloride Ions into Cement Pastes and Concretes , 1972 .

[18]  Matthew A. Miltenberger,et al.  PREDICTING THE SERVICE LIFE OF CONCRETE MARINE STRUCTURES: AN ENVIRONMENTAL METHODOLOGY , 1998 .

[19]  K. Ann,et al.  Factors influencing chloride transport in concrete structures exposed to marine environments , 2008 .

[20]  G. Glass,et al.  Chloride‐induced corrosion of steel in concrete , 2000 .

[21]  Y. Cai,et al.  Study of chloride binding and diffusion in GGBS concrete , 2003 .

[22]  William Feller,et al.  An Introduction to Probability Theory and Its Applications , 1951 .

[23]  Michel Ghosn,et al.  Chloride-induced corrosion of reinforced concrete bridge decks , 2002 .

[24]  E. Garboczi,et al.  Computer simulation of the diffusivity of cement-based materials , 1992 .

[25]  B. T. Molloy,et al.  Prediction of long term chloride concentration in concrete , 1994 .

[26]  P. K. Mehta Concrete: Structure, Properties, and Materials , 1992 .

[27]  S. Jang,et al.  Experimental investigation of the threshold chloride concentration for corrosion initiation in reinforced concrete structures , 2003 .

[28]  Michael D. A. Thomas,et al.  Modelling chloride diffusion in concrete: Effect of fly ash and slag , 1999 .

[29]  Nick R. Buenfeld,et al.  EFFECT OF CEMENT CONTENT ON TRANSPORT IN CONCRETE , 1998 .

[30]  Pd Cady,et al.  Chloride Penetration and the Deterioration of Concrete Bridge Decks , 1983 .

[31]  Michael D.A. Thomas,et al.  A study of the effect of chloride binding on service life predictions , 2000 .