Doped semiconductors with band-edge plasma frequencies

In this work, the authors demonstrate the potential of epitaxially grown highly doped InSb as an engineered, wavelength-flexible mid-IR plasmonic material. The authors achieve doping concentrations over an order of magnitude larger than previously published results and show that such materials have plasma frequencies corresponding to energies larger than the material's band-gap. These semiconductor-based plasmonic metals open the door to homoepitaxial integration of plasmonic or epsilon-near-zero materials with optoelectronic devices at mid-infrared wavelengths. The materials are characterized by Hall measurements, mid-infrared transmission and reflection spectroscopy, and near-infrared transmission spectroscopy. The opportunities offered and the limitations presented by this material system are discussed and analyzed.

[1]  D. W. Pashley,et al.  Observation and control of the amphoteric behaviour of Si-doped InSb grown on GaAs by MBE , 1989 .

[2]  J. Khurgin,et al.  Reflecting upon the losses in plasmonics and metamaterials , 2012 .

[3]  P. Berini Long-range surface plasmon polaritons , 2009 .

[4]  D. Wasserman,et al.  Strong absorption and selective emission from engineered metals with dielectric coatings. , 2013, Optics express.

[5]  I. Ferguson,et al.  Infrared reflection and transmission of undoped and Si-doped InAs grown on GaAs by molecular beam epitaxy , 1993 .

[6]  Daniel Wasserman,et al.  Towards nano-scale photonics with micro-scale photons: the opportunities and challenges of mid-infrared plasmonics , 2013 .

[7]  S. Zukotynski,et al.  The Thermoelectric Power in InSb in the Presence of an External Magnetic Field , 1963 .

[8]  David G. Seiler,et al.  Temperature dependence of the energy gap of InSb using nonlinear optical techniques , 1985 .

[9]  David M. Slocum,et al.  Funneling light through a subwavelength aperture using epsilon-near-zero materials , 2011, CLEO: 2011 - Laser Science to Photonic Applications.

[10]  Fouad Karouta,et al.  Lasing in metal-insulator-metal sub-wavelength plasmonic waveguides. , 2009, Optics express.

[11]  Daniel Wasserman,et al.  All-semiconductor plasmonic nanoantennas for infrared sensing. , 2013, Nano letters.

[12]  S Krishna,et al.  Quantum dot infrared photodetector enhanced by surface plasma wave excitation. , 2009, Optics express.

[13]  Viktor A. Podolskiy,et al.  All-semiconductor negative-index plasmonic absorbers. , 2014 .

[14]  D. Wasserman,et al.  Mid-infrared designer metals , 2012, IEEE Photonics Conference 2012.

[15]  Hooman Mohseni,et al.  Plasmonic enhanced quantum well infrared photodetector with high detectivity , 2010 .

[16]  Qi Jie Wang,et al.  Small-divergence semiconductor lasers by plasmonic collimation , 2008 .

[17]  Diana L. Huffaker,et al.  Strain relief by periodic misfit arrays for low defect density GaSb on GaAs , 2006 .

[18]  Albert Polman,et al.  Evolution of light-induced vapor generation at a liquid-immersed metallic nanoparticle. , 2013, Nano letters.

[19]  J. West,et al.  Near-infrared resonant nanoshells for combined optical imaging and photothermal cancer therapy. , 2007, Nano letters.

[20]  E. Ozbay Plasmonics: Merging Photonics and Electronics at Nanoscale Dimensions , 2006, Science.

[21]  Moon-Ho Jo,et al.  Near-field electrical detection of optical plasmons and single plasmon sources , 2009, Proceedings of the Fourth European Conference on Antennas and Propagation.

[22]  Richard A. Soref,et al.  Infrared surface plasmons on heavily doped silicon , 2011 .

[23]  Robert L. Jarecki,et al.  Infrared plasmons on heavily-doped silicon , 2011 .

[24]  Sadao Adachi,et al.  Band gaps and refractive indices of AlGaAsSb, GaInAsSb, and InPAsSb: Key properties for a variety of the 2–4‐μm optoelectronic device applications , 1987 .

[25]  R. V. Van Duyne,et al.  Localized surface plasmon resonance spectroscopy and sensing. , 2007, Annual review of physical chemistry.

[26]  B. Joyce,et al.  A generalized model for the reconstruction of {001} surfaces of III–V compound semiconductors based on a RHEED study of InSb(001) , 1990 .

[27]  Leonid Alekseyev,et al.  Supplementary Information for “ Negative refraction in semiconductor metamaterials ” , 2007 .

[28]  Daniel Wasserman,et al.  Epitaxial growth of engineered metals for mid-infrared plasmonics , 2013 .

[29]  T. Moss The Interpretation of the Properties of Indium Antimonide , 1954 .

[30]  J. Söderström,et al.  Molecular beam epitaxy growth and characterization of InSb layers on GaAs substrates , 1992 .

[31]  S. Zhang,et al.  The microscopic origin of the doping limits in semiconductors and wide-gap materials and recent developments in overcoming these limits: a review , 2002 .

[32]  E. Burstein Anomalous Optical Absorption Limit in InSb , 1954 .

[33]  T. Taliercio,et al.  Localized surface plasmon resonances in highly doped semiconductors nanostructures , 2012 .

[34]  I. Ferguson,et al.  MOLECULAR BEAM EPITAXIAL GROWTH OF HIGH QUALITY INSB , 1994 .

[35]  Eisuke Tokumitsu,et al.  Correlation between Fermi Level Stabilization Positions and Maximum Free Carrier Concentrations in III–V Compound Semiconductors , 1990 .