Improvement in Mechanical Properties and Electromagnetic Interference Shielding Effectiveness of PVA-Based Composites: Synergistic Effect Between Graphene Nano-Sheets and Multi-Walled Carbon Nanotubes

In this study, polyvinyl alcohol (PVA)/graphene nano-sheets (GNs) composites are produced via solution mixing and melt compounding methods, where multi-walled carbon nanotubes (MWCNTs) are added during process. After that, the test results show that PVA/GNs composites composed of 0.25 wt% GNs possess the optimal tensile strength, while the others composed of 2 wt% GNs have a higher thermal stability, electrical conductivity, and electromagnetic interference shielding effectiveness (EMI SE). The addition of MWCNTs provides the PVA/GNs composites with better synergy that can enhance the tensile properties, thermal stability, electrical conductivity, and EMI SE of composites. In comparison to the melt compounding method, the solution mixing method can yield improved properties.

[1]  Yu-Sheng Wang,et al.  Effect of covalent modification of graphene nanosheets on the electrical property and electromagnetic interference shielding performance of a water-borne polyurethane composite. , 2015, ACS applied materials & interfaces.

[2]  M. Vincent,et al.  Influence of injection molding on the electrical properties of polyamide 12 filled with multi-walled carbon nanotubes , 2014 .

[3]  Wenhua Chen,et al.  Thermal melt processing to prepare halogen-free flame retardant poly(vinyl alcohol) , 2014 .

[4]  Ica Manas-Zloczower,et al.  Epoxy composites with carbon nanotubes and graphene nanoplatelets – Dispersion and synergy effects , 2014 .

[5]  Yanjun Jean Wan,et al.  Mechanical properties of epoxy composites filled with silane-functionalized graphene oxide , 2014 .

[6]  M. S. Sarto,et al.  Electromagnetic absorbing properties of graphene–polymer composite shields , 2014 .

[7]  C. Hopmann,et al.  Morphology and tensile properties of unreinforced and short carbon fibre reinforced Nylon 6/multiwalled carbon nanotube-composites , 2014 .

[8]  C. Macosko,et al.  Melt crystallization of poly(ethylene terephthalate): Comparing addition of graphene vs. carbon nanotubes , 2014 .

[9]  Pingan Song,et al.  Combination effect of carbon nanotubes with graphene on intumescent flame-retardant polypropylene nanocomposites , 2014 .

[10]  A. Docoslis,et al.  A noncovalent compatibilization approach to improve the filler dispersion and properties of polyethylene/graphene composites. , 2014, ACS applied materials & interfaces.

[11]  P. Cassagnau,et al.  Pentadecane functionalized graphite oxide sheets as a tool for the preparation of electrical conductive polyethylene/graphite oxide composites , 2014 .

[12]  Sung-hoon Ahn,et al.  Synergistic effects of carbon nanotubes and exfoliated graphite nanoplatelets for electromagnetic interference shielding and soundproofing , 2013 .

[13]  S. K. Dolui,et al.  Strong and conductive reduced graphene oxide/polyester resin composite films with improved mechanical strength, thermal stability and its antibacterial activity , 2013 .

[14]  Zhenhua Jiang,et al.  Synergistic effects of functionalized graphene and functionalized multi-walled carbon nanotubes on the electrical and mechanical properties of poly(ether sulfone) composites , 2013 .

[15]  Uttandaraman Sundararaj,et al.  EMI shielding effectiveness of carbon based nanostructured polymeric materials: A comparative study , 2013 .

[16]  I. Huynen,et al.  Polymer/carbon based composites as electromagnetic interference (EMI) shielding materials , 2013 .

[17]  F. Sharif,et al.  Highly aligned, ultralarge-size reduced graphene oxide/polyurethane nanocomposites: Mechanical properties and moisture permeability , 2013 .

[18]  Safa Jamali,et al.  Dispersion and re-agglomeration phenomena during melt mixing of polypropylene with multi-wall carbon nanotubes , 2013 .

[19]  Tianxi Liu,et al.  One-step hybridization of graphene nanoribbons with carbon nanotubes and its strong-yet-ductile thermoplastic polyurethane composites , 2013 .

[20]  K. Liao,et al.  Synergistic toughening of epoxy with carbon nanotubes and graphene oxide for improved long-term performance , 2013 .

[21]  G. de With,et al.  High performance graphene- and MWCNTs-based PS/PPO composites obtained via organic solvent dispersion , 2013 .

[22]  Qihua Wang,et al.  In situ polymerization and mechanical, thermal properties of polyurethane/graphene oxide/epoxy nanocomposites , 2013 .

[23]  A. Qaiss,et al.  Processing and properties of polyethylene reinforced by graphene nanosheets and carbon nanotubes , 2013 .

[24]  Anthony Dichiara,et al.  Carbon nanotube-graphene nanoplatelet hybrids as high-performance multifunctional reinforcements in epoxy composites , 2013 .

[25]  Yu-Sheng Wang,et al.  Effect of molecular chain length on the mechanical and thermal properties of amine-functionalized graphene oxide/polyimide composite films prepared by in situ polymerization. , 2013, ACS applied materials & interfaces.

[26]  J. Vuorinen,et al.  Review on the effects of injection moulding parameters on the electrical resistivity of carbon nanotube filled polymer parts , 2012 .

[27]  Jun Luo,et al.  Enhanced dispersion of carbon nanotube in silicone rubber assisted by graphene , 2012 .

[28]  Lin Li,et al.  Poly(vinyl alcohol) nanocomposites filled with poly(vinyl alcohol)-grafted graphene oxide. , 2012, ACS applied materials & interfaces.

[29]  C. Zhang,et al.  Facile preparation of water-dispersible graphene sheets stabilized by acid-treated multi-walled carbon nanotubes and their poly(vinyl alcohol) composites† , 2012 .

[30]  Mohammed H Al-Saleh,et al.  Review of the mechanical properties of carbon nanofiber/polymer composites , 2011 .

[31]  Lin Li,et al.  Noncovalently functionalized multiwalled carbon nanotubes by chitosan-grafted reduced graphene oxide and their synergistic reinforcing effects in chitosan films. , 2011, ACS applied materials & interfaces.

[32]  Minzhen Cai,et al.  In Situ Reduction of Graphene Oxide in Polymers , 2011 .

[33]  L. Drzal,et al.  Improving electrical conductivity and mechanical properties of high density polyethylene through incorporation of paraffin wax coated exfoliated graphene nanoplatelets and multi-wall carbon nano-tubes , 2011 .

[34]  Liping Zhao,et al.  Fabrication of exfoliated graphene-based polypropylene nanocomposites with enhanced mechanical and thermal properties , 2011 .

[35]  Tianyi Yang,et al.  Synergistic effect of hybrid carbon nantube–graphene oxide as a nanofiller in enhancing the mechanical properties of PVA composites , 2011 .

[36]  Chen-Chi M. Ma,et al.  Synergetic effects of graphene platelets and carbon nanotubes on the mechanical and thermal properties of epoxy composites , 2011 .

[37]  R. Ruoff,et al.  Graphene-based polymer nanocomposites , 2011 .

[38]  S. Bose,et al.  Recent advances in graphene based polymer composites , 2010 .

[39]  N. A. Siddiqui,et al.  DISPERSION AND FUNCTIONALIZATION OF CARBON NANOTUBES FOR POLYMER-BASED NANOCOMPOSITES: A REVIEW , 2010 .

[40]  W. Rahman,et al.  Thermal behaviour and interactions of cassava starch filled with glycerol plasticized polyvinyl alcohol blends , 2010 .

[41]  C. Macosko,et al.  Graphene/Polymer Nanocomposites , 2010 .

[42]  W. Rahman,et al.  Rheology and thermal transition state of polyvinyl alcohol-cassava starch blends , 2010 .

[43]  Lin Li,et al.  POLYMER NANOCOMPOSITES BASED ON FUNCTIONALIZED CARBON NANOTUBES , 2010 .

[44]  Xiao-yan Wang,et al.  Graphene Oxide-Assisted Dispersion of Pristine Multiwalled Carbon Nanotubes in Aqueous Media , 2010 .

[45]  Zhong-Zhen Yu,et al.  Electrically conductive polyethylene terephthalate/graphene nanocomposites prepared by melt compounding , 2010 .

[46]  D. Tasis,et al.  Carbon nanotube–polymer composites: Chemistry, processing, mechanical and electrical properties , 2010 .

[47]  Dajun Chen,et al.  Enhanced Mechanical Properties of Graphene-Based Poly(vinyl alcohol) Composites , 2010 .

[48]  G. Shi,et al.  Strong and ductile poly(vinyl alcohol)/graphene oxide composite films with a layered structure , 2009 .

[49]  J. Tour,et al.  Graphite oxide flame-retardant polymer nanocomposites. , 2009, ACS applied materials & interfaces.

[50]  Yan Wang,et al.  Molecular‐Level Dispersion of Graphene into Poly(vinyl alcohol) and Effective Reinforcement of their Nanocomposites , 2009 .

[51]  Uttandaraman Sundararaj,et al.  Electromagnetic interference shielding mechanisms of CNT/polymer composites , 2009 .

[52]  D. C. Trivedi,et al.  EMI shielding: Methods and materials—A review , 2009 .

[53]  Inderpreet Kaur,et al.  Comparative study of carbon nanotube dispersion using surfactants. , 2008, Journal of colloid and interface science.

[54]  Yubai Pan,et al.  Ordered Mesoporous Carbon/Fused Silica Composites , 2008 .

[55]  Q. Fu,et al.  Enhanced compatibilization and orientation of polyvinyl alcohol/gelatin composite fibers using carbon nanotubes , 2008 .

[56]  Petra Pötschke,et al.  Dispersion, agglomeration, and network formation of multiwalled carbon nanotubes in polycarbonate melts , 2008 .

[57]  E. Chiellini,et al.  Biodegradable thermoplastic composites based on polyvinyl alcohol and algae. , 2008, Biomacromolecules.

[58]  Nadia Grossiord,et al.  Controlling the dispersion of multi-wall carbon nanotubes in aqueous surfactant solution , 2007 .

[59]  Masaru Matsuo,et al.  Morphology and mechanical and electrical properties of oriented PVA–VGCF and PVA–MWNT composites , 2006 .

[60]  J. Coleman,et al.  Multiwalled carbon nanotube nucleated crystallization and reinforcement in poly (vinyl alcohol) composites , 2006 .

[61]  Xinli Jing,et al.  Intrinsically conducting polymers for electromagnetic interference shielding , 2005 .

[62]  Qi Wang,et al.  Evaporation behaviour of water and its plasticizing effect in modified poly(vinyl alcohol) systems , 2003 .

[63]  J. Jang,et al.  Plasticizer effect on the melting and crystallization behavior of polyvinyl alcohol , 2003 .

[64]  D. Chung Electromagnetic interference shielding effectiveness of carbon materials , 2001 .

[65]  David Markham,et al.  Shielding: quantifying the shielding requirements for portable electronic design and providing new solutions by using a combination of materials and design , 1999 .

[66]  S. Manoochehri,et al.  Material and geometry factors in joint design of electronic equipment to minimize electromagnetic interference , 1997 .

[67]  Jian Xu,et al.  Implication of multi-walled carbon nanotubes on polymer/graphene composites , 2015 .

[68]  Xingping Zhou,et al.  Electroactive shape memory polymer based on optimized multi-walled carbon nanotubes/polyvinyl alcohol nanocomposites , 2015 .

[69]  C. Das,et al.  Combined effect of expanded graphite and multiwall carbon nanotubes on the thermo mechanical, morphological as well as electrical conductivity of in situ bulk polymerized polystyrene composites , 2014 .

[70]  Uttandaraman Sundararaj,et al.  A review of vapor grown carbon nanofiber/polymer conductive composites , 2009 .

[71]  D. Bakoš,et al.  Poly(vinyl alcohol) stabilisation in thermoplastic processing , 2002 .