Preparation of Aryloxy-aluminoxanes and Their Use as Activators in the Bis(imino)pyridyl Iron-catalyzed Oligomerization of Ethylene

[1]  Z. Wang,et al.  Carbocyclic-fused N,N,N-pincer ligands as ring-strain adjustable supports for iron and cobalt catalysts in ethylene oligo-/polymerization , 2018 .

[2]  Wei Zhang,et al.  Tuning Bis(imino)pyridyl Iron‐Catalyzed Ethylene Oligomerization by Modification of MAO with p‐BrPhOH , 2018 .

[3]  D. O′Hare,et al.  Slurry-Phase Ethylene Polymerization Using Pentafluorophenyl- and Pentafluorophenoxy-Modified Solid Polymethylaluminoxanes , 2018 .

[4]  Jingjing Zhang,et al.  Immobilization of isolated FI catalyst on polyhedral oligomeric silsesquioxane-functionalized silica for the synthesis of weakly entangled polyethylene. , 2016, Chemical communications.

[5]  A. Chernyak,et al.  Hydrolysis of isobutylaluminum aryloxides studied by 1H NMR and quantum chemical methods , 2016, Russian Chemical Bulletin.

[6]  E. O. Perepelitsina,et al.  Isobutylalumoxanes as high-performance activators of rac-Et(2-MeInd)2ZrMe2 in copolymerization of ethylene with propylene and ternary copolymerization of ethylene, propylene, and 5-ethylidene-2-norbornene , 2016, Polymer Bulletin.

[7]  Bin-bo Jiang,et al.  Exploring the effects of phenolic compounds on bis(imino)pyridine iron-catalyzed ethylene oligomerization , 2015 .

[8]  B. Small Discovery and Development of Pyridine-bis(imine) and Related Catalysts for Olefin Polymerization and Oligomerization. , 2015, Accounts of chemical research.

[9]  Wen‐Hua Sun,et al.  Progression of Diiminopyridines: From Single Application to Catalytic Versatility , 2015 .

[10]  H. Olivier-Bourbigou,et al.  Alternative aluminum-based cocatalysts for the iron-catalyzed oligomerization of ethylene. , 2015, Dalton transactions.

[11]  S. Harder,et al.  Methylalumoxane - History, Production, Properties, and Applications , 2015 .

[12]  H. Olivier-Bourbigou,et al.  Role of Homogeneous Catalysis in Oligomerization of Olefins : Focus on Selected Examples Based on Group 4 to Group 10 Transition Metal Complexes , 2015, Catalysis Letters.

[13]  Bin-bo Jiang,et al.  Siloxane-mediated ethylene oligomerization with iron-based catalysts: Retarding the polymer formation , 2014 .

[14]  Helene Olivier-Bourbigou,et al.  Understanding the role of aluminum-based activators in single site iron catalysts for ethylene oligomerization , 2014 .

[15]  Pierre Braunstein,et al.  Ethylene oligomerization using iron complexes: beyond the discovery of bis(imino)pyridine ligands. , 2014, Chemical communications.

[16]  A. Macchioni,et al.  Probing the interactions between all components of the catalytic pool for homogeneous olefin polymerisation by diffusion NMR spectroscopy. , 2013, Dalton transactions.

[17]  F. Ghiotto,et al.  Probing the Structure of Methylalumoxane (MAO) by a Combined Chemical, Spectroscopic, Neutron Scattering, and Computational Approach , 2013 .

[18]  Tingcheng Li,et al.  Highly active and selective ethylene oligomerization catalysts: Asymmetric 2,6-bis(imino)pyridyl iron (II) complexes with alkyl and halogen substitutients , 2010 .

[19]  Guo-Yong Feng,et al.  Influence of the metal centers of 2,6-bis(imino)pyridyl transition metal complexes on ethylene polymerization/ oligomerization catalytic activities , 2010 .

[20]  E. P. Talsi,et al.  Homogeneous catalysts for ethylene polymerization based on bis(imino)pyridine complexes of iron, cobalt, vanadium and chromium , 2009 .

[21]  E. P. Talsi,et al.  Formation and Nature of the Active Sites in Bis(imino)pyridine Iron-Based Polymerization Catalysts , 2009 .

[22]  Martin J. Hanton,et al.  Bis(imino)pyridine Complexes of the First-Row Transition Metals: Alternative Methods of Activation , 2008 .

[23]  A. Ionkin,et al.  High-Temperature Catalysts for the Production of α-Olefins Based on Iron(II) and Cobalt(II) Tridentate Bis(imino)pyridine Complexes with a Double Pattern of Substitution: o-Methyl plus o-Fluorine in the Same Imino Arm† , 2008 .

[24]  G. Solan,et al.  Bis(imino)pyridines: surprisingly reactive ligands and a gateway to new families of catalysts. , 2007, Chemical reviews.

[25]  H. Brintzinger,et al.  Distinct methylalumoxane(MAO)-derived Me-MAO- anions in contact with a zirconocenium cation--a 13C-NMR study. , 2006, Dalton transactions.

[26]  J. Chai,et al.  Sterically Hindered Aluminum Alkyls: Weakly Interacting Scavenging Agents of Use in Olefin Polymerization , 2006 .

[27]  G. Mantovani,et al.  Ethylene oligomerization, homopolymerization and copolymerization by iron and cobalt catalysts with 2,6-(bis-organylimino)pyridyl ligands , 2006 .

[28]  H. Brintzinger,et al.  Methylalumoxane (MAO)-derived MeMAO − anions in zirconocene-based polymerization catalyst systems – a UV-Vis spectroscopic study , 2006 .

[29]  Shibo Wang,et al.  Studies on the activation and polymerization mechanism of ethylene polymerization catalyzed by bis(imino)pyridyl iron(II) precatalyst with alkylaluminum , 2006 .

[30]  E. P. Talsi,et al.  Activation of rac‐Me2Si(ind)2ZrCl2 by Methylalumoxane Modified by Aluminum Alkyls: An EPR Spin‐Probe, 1H NMR, and Polymerization Study , 2006 .

[31]  R. Fröhlich,et al.  Iron complexes bearing 2-imino-1,10-phenanthrolinyl ligands as highly active catalysts for ethylene oligomerization , 2006 .

[32]  A. A. Barabanov,et al.  Kinetic Peculiarities of Ethylene Polymerization over Homogeneous Bis(imino)pyridine Fe(II) Catalysts with Different Activators , 2005 .

[33]  B. de Bruin,et al.  Formation of a paramagnetic Al complex and extrusion of Fe during the reaction of (diiminepyridine)Fe with AlR3 (R = Me, Et). , 2005, Journal of the American Chemical Society.

[34]  Yue-sheng Li,et al.  Ethylene polymerization with silica-supported bis(imino)pyridyl iron(II) catalysts , 2005 .

[35]  Lidong Li,et al.  Effects of tetraalkylaluminoxane activators on ethylene polymerization catalyzed by iron-based complexes , 2005 .

[36]  Zhicheng Zhang,et al.  A series of novel 2,6-bis(imino)pyridyl iron catalysts: synthesis, characterization and ethylene oligomerization , 2005 .

[37]  E. P. Talsi,et al.  Active Intermediates of Ethylene Polymerization over 2,6-Bis(imino)pyridyl Iron Complex Activated with Aluminum Trialkyls and Methylaluminoxane , 2004 .

[38]  Zhicheng Zhang,et al.  Ethylene oligomerization catalyzed by a novel iron complex containing fluoro and methyl substituents , 2004 .

[39]  Y. Kissin Catalyst Systems for Alkene Polymerization Based on Metallocene Complexes and Phenoxy Alumoxane with a Perfluorinated Phenyl Group , 2004 .

[40]  Lidong Li,et al.  Polyethylene with bimodal molecular weight distribution synthesized by 2,6-bis(imino)pyridyl complexes of Fe(II) activated with various activators , 2004 .

[41]  Qi Wang,et al.  Performance of various activators in ethylene polymerization based on an iron(II) catalyst system , 2004 .

[42]  B. Wang,et al.  Improving the performance of methylalumoxane: a facile and efficient method to trap "free" trimethylaluminum. , 2003, Journal of the American Chemical Society.

[43]  Y. Kissin Catalyst systems for alkene polymerization based on metallocene complexes and sterically hindered organoaluminates , 2003 .

[44]  W. Youngs,et al.  Bulky aluminum alkyl scavengers in olefin polymerization with group 4 catalysts. , 2003, Journal of the American Chemical Society.

[45]  Zhi Ma,et al.  Ethylene Polymerization with a Silica-Supported Iron- Based Diimine Catalyst , 2003 .

[46]  H. Cramail,et al.  Influence of Alkylaluminium Activators and Mixtures thereof on Ethylene Polymerization with a Tridentate Bis(imino)pyridinyliron Complex , 2003 .

[47]  Jie Sun,et al.  Fluoro-Substituted 2,6-Bis(imino)pyridyl Iron and Cobalt Complexes: High-Activity Ethylene Oligomerization Catalysts , 2003 .

[48]  Qi Wang,et al.  Efficient Activators for an Iron Catalyst in the Polymerization of Ethylene , 2002 .

[49]  A. Sobolev,et al.  Study of the ethylene polymerization over homogeneous and supported catalysts based on 2,6-bis(imino)pyridyl complexes of Fe(II) and Co(II) , 2002 .

[50]  H. Alt,et al.  Heterogenized iron(II) complexes as highly active ethene polymerization catalysts , 2002 .

[51]  B. Bott,et al.  Aluminum Alkoxides as Synthons for Methylalumoxane (MAO): Product-Catalyzed Thermal Decomposition of [Me2Al(μ-OCPh3)]2 , 2001 .

[52]  E. P. Talsi,et al.  Polymerization of Ethylene Catalyzed by Iron Complex Bearing 2,6‐Bis(imine)pyridyl Ligand: 1H and 2H NMR Monitoring of Ferrous Species Formed via Catalyst Activation with AlMe3, MAO, AlMe3/B(C6F5)3 and AlMe3/CPh3(C6F5)4 , 2001 .

[53]  M. C. Sacchi,et al.  NMR investigations of the reactivity between zirconocenes and β-alkyl-substituted aluminoxanes , 2000 .

[54]  K. Kumar,et al.  Ethylene polymerization using iron(II)bis(imino) pyridyl and nickel (diimine) catalysts: effect of cocatalysts and reaction parameters , 2000 .

[55]  White,et al.  Oligomerisation of ethylene by bis(imino)pyridyliron and -cobalt complexes , 2000, Chemistry.

[56]  Lin-Xian Feng,et al.  Study on polymerization of ethylene with Cp2ZrCl2/aluminoxanes , 2000 .

[57]  T. Marks,et al.  Cocatalysts for metal-catalyzed olefin polymerization: activators, activation processes, and structure-activity relationships. , 2000, Chemical reviews.

[58]  T. Ziegler,et al.  MECHANISTIC ASPECTS OF ETHYLENE POLYMERIZATION BY IRON(II)-BISIMINE PYRIDINE CATALYSTS : A COMBINED DENSITY FUNCTIONAL THEORY AND MOLECULAR MECHANICS STUDY , 1999 .

[59]  M. Brookhart,et al.  Iron-Based Catalysts with Exceptionally High Activities and Selectivities for Oligomerization of Ethylene to Linear α-Olefins , 1998 .

[60]  L. Simeral,et al.  Characterization of Methylaluminoxanes and Determination of Trimethylaluminum Using Proton NMR , 1998 .

[61]  Andrew J. P. White,et al.  Novel olefin polymerization catalysts based on iron and cobalt , 1998 .

[62]  E. P. Talsi,et al.  Multinuclear NMR investigation of methylaluminoxane , 1997 .

[63]  H. Sinn Proposals for structure and effect of methylalumoxane based on mass balances and phase separation experiments , 1995 .

[64]  K. Matsubara,et al.  Characterization of alumoxanes by 27Al-NMR spectra , 1993 .

[65]  G. Bondarenko,et al.  IR and NMR studies on zirconocene dichloride/methylalumoxane systemscatalysts for olefin polymerization , 1991 .

[66]  T. Harada Production, Properties, and Application of Curdlan , 1977 .