Enhanced Hydrophobicity of Polymers for Protective Gloves Achieved by Geometric, Chemical and Plasma—Surface Modification

Gloves are one of the most important elements of personal protective equipment (PPE). To improve gloves properties, a lot of different methods of surface modifications are used. In this work, the application of geometric, chemical, and plasma surface modifications to improve the hydrophobicity of butyl (IIR) and silicone (MVQ) rubber are described. To characterise surface properties contact angle measurements, FT-IR spectroscopy and scanning electron microscopy were used. This study showed that when the chemical modification applied, the contact angle value increases compared to non-modified samples. In addition, plasma modification raised the contact angle value and smoothed the surface morphology. An increase in the polymer surfaces hydrophobicity was the observed effect of the three modifications of rubber.

[1]  E. Korzeniewska,et al.  Enhanced Hydrofobicity of Polymers for Personal Protective Equipment Achieved by Chemical and Physical Modification , 2021, Materials.

[2]  R. Pitchumani,et al.  Fabrication and durability characterization of superhydrophobic and lubricant-infused surfaces. , 2021, Journal of colloid and interface science.

[3]  E. Irzmańska,et al.  Preliminary Research: Validation of the Method of Evaluating Resistance to Surface Wetting with Liquid of Protective Materials Intended for Polymer Protective Gloves , 2021, International journal of environmental research and public health.

[4]  M. A. Kobaisi,et al.  Designing Superhydrophobic Robotic Surfaces: Self-Cleaning, High-Grip Impact, and Bacterial Repelling , 2021 .

[5]  Shuqing Sun,et al.  Hierarchical hydrophobic surfaces with controlled dual transition between rose petal effect and lotus effect via structure tailoring or chemical modification , 2021 .

[6]  M. Carré,et al.  The effects of chlorination, thickness, and moisture on glove donning efficiency , 2021, Ergonomics.

[7]  L. Godderis,et al.  An alternative method to assess permeation through disposable gloves. , 2021, Journal of hazardous materials.

[8]  Liyan Liang,et al.  A less harmful system of preparing robust fabrics for integrated self-cleaning, oil-water separation and water purification. , 2019, Environmental pollution.

[9]  R. Jafari,et al.  Evaluation of atmospheric-pressure plasma parameters to achieve superhydrophobic and self-cleaning HTV silicone rubber surfaces via a single-step, eco-friendly approach , 2019, Surface and Coatings Technology.

[10]  R. Jafari,et al.  Wetting and Self-Cleaning Properties of Silicone Rubber Surfaces Treated by Atmospheric Plasma Jet , 2018, 2018 IEEE Conference on Electrical Insulation and Dielectric Phenomena (CEIDP).

[11]  Zhichao Dong,et al.  Bioinspired Designs of Superhydrophobic and Superhydrophilic Materials , 2018, ACS central science.

[12]  Zhiguang Guo,et al.  Mechanical stability, corrosion resistance of superhydrophobic steel and repairable durability of its slippery surface. , 2018, Journal of colloid and interface science.

[13]  H. Chae,et al.  Superhydrophobic Si surfaces having microscale rod structures prepared in a plasma etching system , 2016 .

[14]  T. Akabane Production Method & Market Trend of Rubber Gloves , 2016 .

[15]  R. A. Jelil,et al.  A review of low-temperature plasma treatment of textile materials , 2015, Journal of Materials Science.

[16]  G. Carbone,et al.  Cassie state robustness of plasma generated randomly nano-rough surfaces , 2014 .

[17]  E. Gogolides,et al.  Biomimetic, antireflective, superhydrophobic and oleophobic PMMA and PMMA-coated glass surfaces fabricated by plasma processing , 2014 .

[18]  E. Irzmańska,et al.  Characteristics of microstructural phenomena occurring on the surface of protective gloves by the action of mechanical and chemical factors , 2014 .

[19]  L. Gao,et al.  Super-hydrophobicity and oleophobicity of silicone rubber modified by CF4 radio frequency plasma , 2011 .

[20]  Bharat Bhushan,et al.  Superhydrophobic surfaces and emerging applications: Non-adhesion, energy, green engineering , 2009 .

[21]  Xi Zhang,et al.  Superhydrophobic surfaces: from structural control to functional application , 2008 .

[22]  Jin Zhai,et al.  Super‐Hydrophobic Surfaces: From Natural to Artificial , 2002 .

[23]  W. Barthlott,et al.  Purity of the sacred lotus, or escape from contamination in biological surfaces , 1997, Planta.

[24]  Harish C. Barshilia,et al.  Superhydrophobic polytetrafluoroethylene surfaces with leaf-like micro-protrusions through Ar + O2 plasma etching process , 2014 .

[25]  Y. Carter,et al.  How to use personal protective equipment. , 2014, Nursing times.