Nuclei-mode particulate emissions and their response to fuel sulfur content and primary dilution during transient operations of old and modern diesel engines.

The effects of fuel sulfur content and primary dilution on PM number emissions were investigated during transient operations of an old and a modern diesel engine. Emissions were also studied during steady-state operations in order to confirm consistency with previous findings. Testing methods were concurrent with those implemented by the EPA to regulate PM mass emissions, including the use of the Federal Transient Testing Procedure-Heavy Duty cycle to simulate transient conditions and the use of a Critical Flow Venturi-Constant Volume System to provide primary dilution. Steady-state results were found to be consistent with previous studies in that nuclei-mode particulate emissions were largely reduced when lower-sulfur content fuel was used in the newer engine, while the nuclei-mode PM emissions from the older engine were much less affected by fuel sulfur content. The transient results, however, show that the total number of nuclei-mode PM emissions from both engines increases with fuel sulfur content, although this effect is only seen under the higher primary dilution ratios with the older engine. Transient results further show that higher primary dilution ratios increase total nuclei-mode PM number emissions in both engines.

[1]  Principal Investigator,et al.  DIESEL AEROSOL SAMPLING METHODOLOGY - CRC E-43 , 2002 .

[2]  D. Kittelson Engines and nanoparticles: a review , 1998 .

[3]  Michael J. Kleeman,et al.  SIZE AND COMPOSITION DISTRIBUTION OF FINE PARTICULATE MATTER EMITTED FROM MOTOR VEHICLES , 2000 .

[4]  Z. Gerald Liu,et al.  Measuring the Fractional Efficiency of Diesel Particulate Filters , 2002 .

[5]  R. W. Waytulonis,et al.  Chemical analysis of diesel engine nanoparticles using a nano-DMA/thermal desorption particle beam mass spectrometer. , 2001, Environmental science & technology.

[6]  John B. Heywood,et al.  Internal combustion engine fundamentals , 1988 .

[7]  K. Baumgard,et al.  Characterization of fuel and aftertreatment device effects on diesel emissions. , 1996, Research report.

[8]  B. Lehnert,et al.  Correlation between particle size, in vivo particle persistence, and lung injury. , 1994, Environmental health perspectives.

[9]  K. Lehtinen,et al.  Modelling binary homogeneous nucleation of water-sulfuric acid vapours: parameterisation for high temperature emissions. , 2003, Environmental science & technology.

[10]  Leonidas Ntziachristos,et al.  Modelling of diesel exhaust aerosol during laboratory sampling , 2005 .

[11]  David B. Kittelson,et al.  On-road and laboratory evaluation of combustion aerosols-Part1: Summary of diesel engine results , 2006 .

[12]  D. Kittelson,et al.  A New Electrical Mobility Particle Sizer Spectrometer for Engine Exhaust Particle Measurements , 2004 .

[13]  Bert Brunekreef,et al.  [Air pollution and health]. , 2018, Nederlands tijdschrift voor geneeskunde.

[14]  Imad A. Khalek,et al.  Nanoparticle growth during dilution and cooling of diesel exhaust: Experimental investigation and theoretical assessment , 2000 .

[15]  J. Schneider,et al.  Nucleation particles in diesel exhaust: composition inferred from in situ mass spectrometric analysis. , 2005, Environmental science & technology.

[16]  Leonidas Ntziachristos,et al.  Formation potential of vehicle exhaust nucleation mode particles on-road and in the laboratory , 2005 .

[17]  E. R. Jayaratne,et al.  Influence of diesel fuel sulfur on nanoparticle emissions from city buses. , 2006, Environmental science & technology.