Enhancement of H2-sensing Properties of F-doped SnO2 Sensor by Surface Modification with SiO2

Effects of surface chemical modification with sodium silicate on the gas-sensing properties of F-doped SnO2 gas sensor designed and fabricated employing micro-electro mechanical system (MEMS) technology were investigated. Gas sensing properties of the sensor were checked against combustible gases like H2, CO, CH4 and C3H8 at a heater voltage of 0.7 V. The H2 sensitivity of the surface modified F-doped SnO2 micro sensor markedly increased and reached S = 175 which was found to be about 40 times more than that of unmodified sensor (S = ∼ 4.2). The increase in the sensitivity is discussed in terms of increased resistivity and reduced permeation of gaseous oxygen into the underlying sensing layer due to the surface modification of the sensor. The present micro-hydrogen sensor with enhanced sensitivity due to SiO2 incorporation is a low energy consuming portable sensor module that can be mass-produced using MEMS technology at low cost.

[1]  S. Seal,et al.  Effect of ultraviolet radiation exposure on room-temperature hydrogen sensitivity of nanocrystalline doped tin oxide sensor incorporated into microelectromechanical systems device , 2005 .

[2]  G. Campet,et al.  Conductive F-doped Tin Dioxide Sol−Gel Materials from Fluorinated β-Diketonate Tin(IV) Complexes. Characterization and Thermolytic Behavior , 2000 .

[3]  S. Han,et al.  Micro-bead of nano-crystalline F-doped SnO2 as a sensitive hydrogen gas sensor , 2005 .

[4]  S. Seal,et al.  Hydrogen-discriminating nanocrystalline doped-tin-oxide room-temperature microsensor , 2005 .

[5]  Craig A. Grimes,et al.  A Sentinel Sensor Network for Hydrogen Sensing , 2003 .

[6]  G. Ye,et al.  Fine-particle characterization — An important recycling tool , 2002 .

[7]  G. Coles,et al.  Laser-ablated nanocrystalline SnO2 material for low-level CO detection , 2003 .

[8]  Sudipta Seal,et al.  Synthesis and characterization of sol-gel derived nanocrystalline tin oxide thin film as hydrogen sensor , 2003 .

[9]  O Kiesewetter,et al.  Gas sensing properties of thin- and thick-film tin-oxide materials , 2001 .

[10]  Sudipta Seal,et al.  Micromachined nanocrystalline SnO2 chemical gas sensors for electronic nose , 2004 .

[11]  C. Feng,et al.  Effect of Gas Diffusion Process on Sensing Properties of SnO2 Thin Film Sensors in a SiO2 / SnO2 Layer‐Built Structure Fabricated by Sol‐Gel Process , 1994 .

[12]  V. C. Sahni,et al.  Passivated thick film catalytic type H2 sensor operating at low temperature , 2002 .

[13]  D. Kohl Surface processes in the detection of reducing gases with SnO2-based devices , 1989 .

[14]  Udo Weimar,et al.  Gas identification by modulating temperatures of SnO2-based thick film sensors , 1997 .

[15]  S. Seal,et al.  Nanocrystalline SnO gas sensors in view of surface reactions and modifications , 2002 .

[16]  Hong-Ming Lin,et al.  A novel SnO2 gas sensor doped with carbon nanotubes operating at room temperature , 2004 .

[17]  E. D. Cyan Handbook of Chemistry and Physics , 1970 .

[18]  M. Egashira,et al.  Hydrogen sensing properties of SnO2 subjected to surface chemical modification with ethoxysilanes , 2000 .

[19]  H. S. Wolff,et al.  iRun: Horizontal and Vertical Shape of a Region-Based Graph Compression , 2022, Sensors.

[20]  Sudipta Seal,et al.  Inverse-catalyst-effect observed for nanocrystalline-doped tin oxide sensor at lower operating temperatures , 2005, Sensors and Actuators B: Chemical.

[21]  Yude Wang,et al.  Mesostructured SnO2 as sensing material for gas sensors , 2004 .

[22]  S. Morrison,et al.  Semiconductor gas sensors , 1985 .