Mass transfer limitations during ultrafiltration of cheese whey with inorganic membranes

Abstract We studied the phenomena limiting the mass transfer of solvent and of solutes during ultrafiltration of sweet whey. The experimental variation in time of permeation rates and of rejection of soluble proteins are analyzed with various models, taking concentration polarization, adsorption, gelation or material deposition into account. Three steps were found to explain the flux decline: (1) the build up of a polarization layer, (2) membrane fouling by adsorption, (3) membrane fouling by material deposition. Furthermore, the rejection of proteins was found to depend on the kind of fouling and on the operating conditions.

[1]  J. Howell,et al.  ULTRAFILTRATION OF PROTEIN SOLUTIONS * , 1981 .

[2]  M. Doshi,et al.  Pressure-Independent Ultrafiltration—Is It Gel Limited or Osmotic Pressure Limited? , 1981 .

[3]  P. Aimar,et al.  Etude du transfert de matière lors de l'ultrafiltration de lactosérum doux sur membrane minérale , 1986 .

[4]  Anthony G. Fane,et al.  The dynamics of polarisation in unstirred and stirred ultrafiltration , 1984 .

[5]  Shoji Kimura,et al.  Fouling of cellulose acetate tubular reverse osmosis modules treating the industrial water in Tokyo , 1975 .

[6]  P. Ward,et al.  The separation of aryl acylamidase by cross flow microfiltration and the significance of enzyme/cell debris interaction☆ , 1984 .

[7]  E. Matthiasson The role of macromolecular adsorption in fouling of ultrafiltration membranes , 1983 .

[8]  A. Fane,et al.  Ultrafiltration of protein solutions through partially permeable membranes — the effect of adsorption and solution environment , 1983 .

[9]  J. Hermia,et al.  Constant Pressure Blocking Filtration Laws - Application To Power-law Non-newtonian Fluids , 1982 .

[10]  M. Clifton,et al.  Growth of the polarization layer in ultrafiltration with hollow-fibre membranes , 1984 .

[11]  L. Zeman Adsorption effects in rejection of macromolecules by ultrafiltration membranes , 1983 .

[12]  Anthony G. Fane,et al.  Ultrafiltration of suspensions , 1984 .

[13]  Clark K. Colton,et al.  The osmotic pressure of concentrated protein solutions: Effect of concentration and ph in saline solutions of bovine serum albumin , 1981 .

[14]  P. Aimar,et al.  Membrane— solute interactions: influence on pure solvent transfer during ultrafiltration , 1986 .

[15]  A. Fane,et al.  Flux decline in protein ultrafiltration , 1984 .

[16]  Alan S. Michaels,et al.  SOLUTE POLARIZATION AND CAKE FORMATION IN MEMBRANE ULTRAFILTRATION: CAUSES, CONSEQUENCES, AND CONTROL TECHNIQUES , 1970 .