Transient electroluminescence from hole transporting emitting layer in nanosecond region

Transient electroluminescence (EL) for an organic thin film cell with a hole transporting emitting layer was observed by short voltage pulse measurements. For the cell with indium tin oxide/hole transporting emitting layer/Mg:Ag structure, we realized very fast response at a time about 20 ns. This response time has been the fastest in organic EL ever reported. In these measurements, we could observe carrier transit time. We found that this carrier transit time was attributed to that of holes in the emitting layer. The hole mobility in 120‐nm‐thick emitting layer was obtained to be 1±0.3×10−3 cm2/V s in the electric field region from 1 to 3 MV/cm. Furthermore, we could observe the fast EL decay component with a time constant of 3.0±1.5 ns, which was essentially attributed to the decay of singlet excited states.

[1]  R. N. Marks,et al.  Light-emitting diodes based on conjugated polymers , 1990, Nature.

[2]  H. Grubin The physics of semiconductor devices , 1979, IEEE Journal of Quantum Electronics.

[3]  D. Pai,et al.  Comparison of the drift mobility measured under transient and steady-state conditions in a prototypical hopping system , 1986 .

[4]  K. Yoshino,et al.  Time-Resolved Pulse Response of Electroluminescence in Poly(3-alkylthiophene) Diodes , 1992 .

[5]  Charles E. Swenberg,et al.  Electronic Processes in Organic Crystals , 1982 .

[6]  N. Kawasaki,et al.  Bright blue electroluminescence from hole transporting polycarbonate , 1992 .

[7]  C. Tang,et al.  Organic Electroluminescent Diodes , 1987 .

[8]  H. Bässler,et al.  Hole transport in bis(4‐N,N‐diethylamino‐2‐methylphenyl)‐4‐methylphenylmethane , 1991 .

[9]  A. Heeger,et al.  Visible light emission from semiconducting polymer diodes , 1991 .

[10]  Daniel Moses,et al.  Nanosecond transient electroluminescence from polymer light‐emitting diodes , 1992 .

[11]  R. Richert,et al.  Diffusion and drift of charge carriers in a random potential: Deviation from Einstein's law. , 1989, Physical review letters.

[12]  W. Helfrich,et al.  Transients of Volume‐Controlled Current and of Recombination Radiation in Anthracene , 1966 .

[13]  J. Palais,et al.  Fiber Optic COMMUNICATIONS , 1992 .

[14]  Tetsuo Tsutsui,et al.  Organic electroluminescent device having a hole conductor as an emitting layer , 1989 .

[15]  Hiroshi Tokailin,et al.  Transient behavior of organic thin film electroluminescence , 1992 .

[16]  M. Nohara,et al.  A New Series of Electroluminescent Organic Compounds , 1990 .

[17]  C. H. Chen,et al.  Electroluminescence of doped organic thin films , 1989 .