Crystallographic control of noble metal nanocrystals

Summary This review provides an overview of recent developments in the controlled synthesis of well-defined noble metal nanocrystals from the viewpoint of crystallographic control. Discussions are focused on the relationship between the shapes of noble metal nanocrystals and their internal and external crystal structures. Representative strategies for the crystallographic control of noble metal nanocrystals are introduced and discussed from the aspects of internal and external crystallographic control. Typical examples of the enhanced properties of noble metal nanocrystals by crystallographic control are highlighted.

[1]  Yun Tang,et al.  Tailoring properties and functionalities of metal nanoparticles through crystallinity engineering. , 2007, Nature materials.

[2]  Zhi-You Zhou,et al.  Electrochemical preparation of Pd nanorods with high-index facets. , 2009, Chemical communications.

[3]  M. Tsuji,et al.  Shape Evolution of Octahedral and Triangular Platelike Silver Nanocrystals from Cubic and Right Bipyramidal Seeds in DMF , 2009 .

[4]  Zhaoxiong Xie,et al.  Synthesis of trisoctahedral gold nanocrystals with exposed high-index facets by a facile chemical method. , 2008, Angewandte Chemie.

[5]  M. Chi,et al.  Core/shell Pd/FePt nanoparticles as an active and durable catalyst for the oxygen reduction reaction. , 2010, Journal of the American Chemical Society.

[6]  Daeha Seo,et al.  One-Dimensional Gold Nanostructures through Directed Anisotropic Overgrowth from Gold Decahedrons , 2009 .

[7]  Younan Xia,et al.  Synthesis and electrical characterization of silver nanobeams. , 2006, Nano letters.

[8]  Hong Yang,et al.  Designer platinum nanoparticles: Control of shape, composition in alloy, nanostructure and electrocatalytic property , 2009 .

[9]  L. Liz‐Marzán,et al.  N,N‐Dimethylformamide as a Reaction Medium for Metal Nanoparticle Synthesis , 2009, Colloidal Synthesis of Plasmonic Nanometals.

[10]  Shigang Sun,et al.  Direct electrodeposition of tetrahexahedral Pd nanocrystals with high-index facets and high catalytic activity for ethanol electrooxidation. , 2010, Journal of the American Chemical Society.

[11]  Zhong-Qun Tian,et al.  Epitaxial growth of heterogeneous metal nanocrystals: from gold nano-octahedra to palladium and silver nanocubes. , 2008, Journal of the American Chemical Society.

[12]  M. Toney,et al.  In situ and ex situ studies of platinum nanocrystals: growth and evolution in solution. , 2009, Journal of the American Chemical Society.

[13]  J. Lee,et al.  Tuning the crystallinity of Au nanoparticles. , 2010, Small.

[14]  Tian Ming,et al.  Growth of tetrahexahedral gold nanocrystals with high-index facets. , 2009, Journal of the American Chemical Society.

[15]  L. Lechuga,et al.  LSPR-based nanobiosensors , 2009 .

[16]  Younan Xia,et al.  Seed-mediated synthesis of Ag nanocubes with controllable edge lengths in the range of 30-200 nm and comparison of their optical properties. , 2010, Journal of the American Chemical Society.

[17]  Lan-sun Zheng,et al.  Syntheses and Properties of Micro/Nanostructured Crystallites with High‐Energy Surfaces , 2010 .

[18]  M. Natan,et al.  Hydroxylamine Seeding of Colloidal Au Nanoparticles. 3. Controlled Formation of Conductive Au Films , 2000 .

[19]  Shuyuan Zhang,et al.  Preparation of multiply twinned palladium particles with five-fold symmetry via a convenient solution route , 2002 .

[20]  Jianfang Wang,et al.  Plasmon–molecule interactions , 2010 .

[21]  Daeha Seo,et al.  Shape adjustment between multiply twinned and single-crystalline polyhedral gold nanocrystals: Decahedra, icosahedra, and truncated tetrahedra , 2008 .

[22]  Dingsheng Wang,et al.  Shape-dependent catalytic activity of silver nanoparticles for the oxidation of styrene. , 2006, Chemistry, an Asian journal.

[23]  M. H. Yeung,et al.  Growth of gold nanorods and bipyramids using CTEAB surfactant. , 2006, The journal of physical chemistry. B.

[24]  Jianfang Wang,et al.  Growth of gold bipyramids with improved yield and their curvature-directed oxidation. , 2007, Small.

[25]  L. Liz‐Marzán,et al.  Formation of Silver Nanoprisms with Surface Plasmons at Communication Wavelengths , 2006 .

[26]  Jiye Fang,et al.  Superlattices with non-spherical building blocks , 2010 .

[27]  M. Maillard,et al.  Tuning the Size of Silver Nanodisks with Similar Aspect Ratios: Synthesis and Optical Properties , 2003 .

[28]  H. Yang,et al.  Roles of Twin Defects in the Formation of Platinum Multipod Nanocrystals , 2007 .

[29]  Manfred T. Reetz,et al.  Size-Selective Synthesis of Nanostructured Transition Metal Clusters , 1994 .

[30]  C. Murphy,et al.  Room temperature, high-yield synthesis of multiple shapes of gold nanoparticles in aqueous solution. , 2004, Journal of the American Chemical Society.

[31]  Xingyu Jiang,et al.  Formation of rectangularly shaped Pd/Au bimetallic nanorods: evidence for competing growth of the Pd shell between the 110 and 100 side facets of Au nanorods. , 2006, Nano letters.

[32]  Mostafa A. El-Sayed,et al.  Preparation and Growth Mechanism of Gold Nanorods (NRs) Using Seed-Mediated Growth Method , 2003 .

[33]  Tianyan You,et al.  A new shape of gold nanocrystals: singly twinned squashed dodecahedron , 2010 .

[34]  Catherine J. Murphy,et al.  Wet Chemical Synthesis of High Aspect Ratio Cylindrical Gold Nanorods , 2001 .

[35]  Gyoung Hwa Jeong,et al.  Polyhedral Au nanocrystals exclusively bound by {110} facets: the rhombic dodecahedron. , 2009, Journal of the American Chemical Society.

[36]  J. Lombardi,et al.  Growth of tetrahedral silver nanocrystals in aqueous solution and their SERS enhancement. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[37]  C. Mirkin,et al.  pH-switchable silver nanoprism growth pathways. , 2007, Angewandte Chemie.

[38]  Michael H. Huang,et al.  Seed-mediated synthesis of gold nanocrystals with systematic shape evolution from cubic to trisoctahedral and rhombic dodecahedral structures. , 2010, Langmuir : the ACS journal of surfaces and colloids.

[39]  Andrew R. Siekkinen,et al.  Synthesis of silver nanoplates at high yields by slowing down the polyol reduction of silver nitrate with polyacrylamide , 2007 .

[40]  M. H. Yeung,et al.  One-step synthesis of large-aspect-ratio single-crystalline gold nanorods by using CTPAB and CTBAB surfactants. , 2007, Chemistry.

[41]  Younan Xia,et al.  Size-dependence of surface plasmon resonance and oxidation for Pd nanocubes synthesized via a seed etching process. , 2005, Nano letters.

[42]  Philippe Guyot-Sionnest,et al.  Mechanism of silver(I)-assisted growth of gold nanorods and bipyramids. , 2005, The journal of physical chemistry. B.

[43]  Weiya Zhou,et al.  Tuning the Morphology of Gold Nanocrystals by Switching the Growth of {110} Facets from Restriction to Preference , 2008 .

[44]  Zhong Lin Wang,et al.  Luminescent and Raman active silver nanoparticles with polycrystalline structure. , 2008, Journal of the American Chemical Society.

[45]  J. Ying,et al.  A general phase-transfer protocol for metal ions and its application in nanocrystal synthesis. , 2009, Nature materials.

[46]  C. Murphy,et al.  Anisotropic metal nanoparticles: Synthesis, assembly, and optical applications. , 2005, The journal of physical chemistry. B.

[47]  Weiyang Li,et al.  Facile synthesis of five-fold twinned, starfish-like rhodium nanocrystals by eliminating oxidative etching with a chloride-free precursor. , 2010, Angewandte Chemie.

[48]  J. Ying,et al.  Phase transfer and its applications in nanotechnology. , 2011, Chemical Society reviews.

[49]  Younan Xia,et al.  Etching and growth: an intertwined pathway to silver nanocrystals with exotic shapes. , 2009, Angewandte Chemie.

[50]  Zhi-You Zhou,et al.  Platinum Metal Catalysts of High-Index Surfaces: From Single-Crystal Planes to Electrochemically Shape-Controlled Nanoparticles , 2008 .

[51]  Peidong Yang,et al.  Polyhedral silver nanocrystals with distinct scattering signatures. , 2006, Angewandte Chemie.

[52]  M. Natan,et al.  Seeding of Colloidal Au Nanoparticle Solutions. 2. Improved Control of Particle Size and Shape , 2000 .

[53]  N. Jana,et al.  Gram-scale synthesis of soluble, near-monodisperse gold nanorods and other anisotropic nanoparticles. , 2005, Small.

[54]  Yue Yu,et al.  Seed-Mediated Synthesis of Monodisperse Concave Trisoctahedral Gold Nanocrystals with Controllable Sizes , 2010 .

[55]  C. Mirkin,et al.  Plasmon-mediated synthesis of silver triangular bipyramids. , 2009, Angewandte Chemie.

[56]  V. Kitaev,et al.  Direct structural transformation of silver platelets into right bipyramids and twinned cube nanoparticles: morphology governed by defects. , 2008, Chemical communications.

[57]  H. Kawasaki,et al.  Rapid synthesis of gold nanorods by the combination of chemical reduction and photoirradiation processes; morphological changes depending on the growing processes. , 2003, Chemical communications.

[58]  C. J. Johnson,et al.  Growth and form of gold nanorods prepared by seed-mediated, surfactant-directed synthesis , 2002 .

[59]  J. Bai,et al.  Controlled synthesis of gold nanobelts and nanocombs in aqueous mixed surfactant solutions. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[60]  Younan Xia,et al.  Nanocrystals with unconventional shapes--a class of promising catalysts. , 2007, Angewandte Chemie.

[61]  Zhong Lin Wang,et al.  Synthesis of Tetrahexahedral Platinum Nanocrystals with High-Index Facets and High Electro-Oxidation Activity , 2007, Science.

[62]  Younan Xia,et al.  A water-based synthesis of octahedral, decahedral, and icosahedral Pd nanocrystals. , 2007, Angewandte Chemie.

[63]  H. Atwater,et al.  Plasmonics for improved photovoltaic devices. , 2010, Nature materials.

[64]  Shigang Sun,et al.  Shape-controlled synthesis of gold nanoparticles in deep eutectic solvents for studies of structure-functionality relationships in electrocatalysis. , 2008, Angewandte Chemie.

[65]  Kyriakos Komvopoulos,et al.  Platinum nanoparticle shape effects on benzene hydrogenation selectivity. , 2007, Nano letters.

[66]  A. Walker,et al.  Monodisperse gold-copper bimetallic nanocubes: facile one-step synthesis with controllable size and composition. , 2010, Angewandte Chemie.

[67]  Robert M Dickson,et al.  Individual water-soluble dendrimer-encapsulated silver nanodot fluorescence. , 2002, Journal of the American Chemical Society.

[68]  Younan Xia,et al.  Right bipyramids of silver: a new shape derived from single twinned seeds. , 2006, Nano letters.

[69]  Daeha Seo,et al.  Polyhedral gold nanocrystals with O h symmetry: from octahedra to cubes. , 2006, Journal of the American Chemical Society.

[70]  N. Zheng,et al.  Amine-assisted synthesis of concave polyhedral platinum nanocrystals having {411} high-index facets. , 2011, Journal of the American Chemical Society.

[71]  C. Mirkin,et al.  Photoinduced Conversion of Silver Nanospheres to Nanoprisms , 2001, Science.

[72]  Daeha Seo,et al.  Directed surface overgrowth and morphology control of polyhedral gold nanocrystals. , 2008, Angewandte Chemie.

[73]  Lifeng Liu,et al.  Studies on silver nanodecahedrons synthesized by PVP-assisted N, N-dimethylformamide (DMF) reduction , 2006 .

[74]  L. Marks Experimental studies of small particle structures , 1994 .

[75]  Z. Tang,et al.  Selective synthesis of single-crystalline rhombic dodecahedral, octahedral, and cubic gold nanocrystals. , 2009, Journal of the American Chemical Society.

[76]  Cheng-Dah Chen,et al.  The Shape Transition of Gold Nanorods , 1999 .

[77]  Jian Zhang,et al.  Concave cubic gold nanocrystals with high-index facets. , 2010, Journal of the American Chemical Society.

[78]  Soshan Cheong,et al.  Shape control of platinum and palladium nanoparticles for catalysis. , 2010, Nanoscale.

[79]  V. Kitaev,et al.  Photochemical Synthesis of Monodisperse Size-Controlled Silver Decahedral Nanoparticles and Their Remarkable Optical Properties , 2008 .

[80]  Catherine J. Murphy,et al.  Wet chemical synthesis of silver nanorods and nanowiresof controllable aspect ratio , 2001 .

[81]  Younan Xia,et al.  Shape-Controlled Synthesis of Gold and Silver Nanoparticles , 2002, Science.

[82]  P. Jain,et al.  Au nanoparticles target cancer , 2007 .

[83]  L. Liz‐Marzán,et al.  The crystalline structure of gold nanorods revisited: evidence for higher-index lateral facets. , 2010, Angewandte Chemie.

[84]  G. Somorjai,et al.  Pt nanocrystals: shape control and Langmuir-Blodgett monolayer formation. , 2005, The journal of physical chemistry. B.

[85]  Guobao Xu,et al.  Seed-Mediated Growth of Nearly Monodisperse Palladium Nanocubes with Controllable Sizes , 2008 .

[86]  J. Lee,et al.  Monodisperse icosahedral Ag, Au, and Pd nanoparticles: size control strategy and superlattice formation. , 2009, ACS nano.

[87]  S. Nepijko,et al.  Pentagonal Symmetry and Disclinations in Small Particles , 1999 .

[88]  L. Liz‐Marzán,et al.  Growth of pentatwinned gold nanorods into truncated decahedra. , 2010, Nanoscale.

[89]  M. L. Curri,et al.  Photochemical Synthesis of Water-Soluble Gold Nanorods: The Role of Silver in Assisting Anisotropic Growth , 2009 .

[90]  Peidong Yang,et al.  Sub-10 nm platinum nanocrystals with size and shape control: catalytic study for ethylene and pyrrole hydrogenation. , 2009, Journal of the American Chemical Society.

[91]  B. Beaudoin,et al.  Homogeneous and heterogeneous nucleations in the polyol process for the preparation of micron and submicron size metal particles , 1989 .

[92]  H. Zeng,et al.  Controllable polyol synthesis of uniform palladium icosahedra: effect of twinned structure on deformation of crystalline lattices. , 2009, Angewandte Chemie.

[93]  Jae Hee Song,et al.  Photochemical synthesis of gold nanorods. , 2002, Journal of the American Chemical Society.

[94]  X. Gu,et al.  Shape controlled growth of gold nanoparticles by a solution synthesis. , 2005, Chemical communications.

[95]  M. C. Giménez,et al.  Theoretical Considerations of Electrochemical Phase Formation for an Ideal Frank-van der Merwe System Ag on Au(111) and Au(100) , 2002 .

[96]  C. Mirkin,et al.  Controlling anisotropic nanoparticle growth through plasmon excitation , 2003, Nature.

[97]  Peidong Yang,et al.  Shape Control of Colloidal Metal Nanocrystals , 2008 .

[98]  C. R. Chris Wang,et al.  Gold Nanorods: Electrochemical Synthesis and Optical Properties , 1997 .

[99]  Weiya Zhou,et al.  Gold nanorod-seeded growth of silver nanostructures: from homogeneous coating to anisotropic coating. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[100]  A. Alivisatos,et al.  Observation of Single Colloidal Platinum Nanocrystal Growth Trajectories , 2009, Science.

[101]  Joseph M. McLellan,et al.  Synthesis of palladium icosahedra with twinned structure by blocking oxidative etching with citric acid or citrate ions. , 2007, Angewandte Chemie.

[102]  Younan Xia,et al.  Chemical synthesis of novel plasmonic nanoparticles. , 2009, Annual review of physical chemistry.

[103]  Younan Xia,et al.  Synthesis and optical properties of silver nanobars and nanorice. , 2007, Nano letters.

[104]  Yadong Li,et al.  A seed-based diffusion route to monodisperse intermetallic CuAu nanocrystals. , 2010, Angewandte Chemie.

[105]  Bo Liu,et al.  Synthesis of nanocrystals with variable high-index Pd facets through the controlled heteroepitaxial growth of trisoctahedral Au templates. , 2010, Journal of the American Chemical Society.

[106]  Younan Xia,et al.  Polyol Synthesis of Uniform Silver Nanowires: A Plausible Growth Mechanism and the Supporting Evidence , 2003 .

[107]  P. Yang,et al.  Crystal Growth , 2004 .

[108]  Xiaodong Han,et al.  Synthesis of tetrahexahedral Au nanocrystals with exposed high-index surfaces. , 2010, Chemical communications.

[109]  Younan Xia,et al.  Shape-controlled synthesis of platinum nanocrystals for catalytic and electrocatalytic applications , 2009 .

[110]  Catherine J Murphy,et al.  Seeded high yield synthesis of short Au nanorods in aqueous solution. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[111]  Moon J. Kim,et al.  Synthesis and mechanistic study of palladium nanobars and nanorods. , 2007, Journal of the American Chemical Society.

[112]  Younan Xia,et al.  Synthesis of silver nanostructures with controlled shapes and properties. , 2007, Accounts of chemical research.

[113]  Michael J. Natan,et al.  Hydroxylamine Seeding of Colloidal Au Nanoparticles in Solution and on Surfaces , 1998 .

[114]  N. Jana Nanorod shape separation using surfactant assisted self-assembly. , 2003, Chemical communications.

[115]  C. Murphy,et al.  One-dimensional colloidal gold and silver nanostructures. , 2006, Inorganic chemistry.

[116]  C. Mirkin,et al.  Photomediated synthesis of silver triangular bipyramids and prisms: the effect of pH and BSPP. , 2010, Journal of the American Chemical Society.

[117]  Younan Xia,et al.  Shape-controlled synthesis of metal nanostructures: the case of silver. , 2005, Chemistry.

[118]  Andrey L Rogach,et al.  Nonspherical Noble Metal Nanoparticles: Colloid‐Chemical Synthesis and Morphology Control , 2010, Advanced materials.

[119]  M. Grzelczak,et al.  Influence of silver ions on the growth mode of platinum on gold nanorods , 2006 .

[120]  G. Brunklaus,et al.  Tuning Plasmonic Properties by Alloying Copper into Gold Nanorods , 2009 .

[121]  G. Somorjai,et al.  Nanoscale advances in catalysis and energy applications. , 2010, Nano letters.

[122]  M. Yacamán,et al.  The role of twinning in shape evolution of anisotropic noble metal nanostructures , 2006 .

[123]  Michael H. Huang,et al.  Au nanocube-directed fabrication of Au-Pd core-shell nanocrystals with tetrahexahedral, concave octahedral, and octahedral structures and their electrocatalytic activity. , 2010, Journal of the American Chemical Society.

[124]  C. Lofton,et al.  Mechanisms Controlling Crystal Habits of Gold and Silver Colloids , 2005 .

[125]  Gabor A. Somorjai,et al.  Formation of Hollow Nanocrystals Through the Nanoscale Kirkendall Effect , 2004, Science.

[126]  N. Zheng,et al.  Controlled formation of concave tetrahedral/trigonal bipyramidal palladium nanocrystals. , 2009, Journal of the American Chemical Society.

[127]  L. Liz‐Marzán,et al.  Chemical sharpening of gold nanorods: the rod-to-octahedron transition. , 2007, Angewandte Chemie.

[128]  Shouheng Sun,et al.  A general approach to the size- and shape-controlled synthesis of platinum nanoparticles and their catalytic reduction of oxygen. , 2008, Angewandte Chemie.

[129]  T. C. Green,et al.  Shape-Controlled Synthesis of Colloidal Platinum Nanoparticles , 1996, Science.

[130]  Younan Xia,et al.  Shape‐Controlled Synthesis of Pd Nanocrystals in Aqueous Solutions , 2009 .

[131]  Luis M. Liz-Marzán,et al.  Synthesis of Silver Nanoprisms in DMF , 2002 .

[132]  Ling Zhang,et al.  Shape-controlled synthesis of single-crystalline palladium nanocrystals. , 2010, ACS nano.

[133]  Vladimir Kitaev,et al.  Synthesis of size-controlled faceted pentagonal silver nanorods with tunable plasmonic properties and self-assembly of these nanorods. , 2009, ACS nano.

[134]  Ling Zhang,et al.  Seed-mediated growth of palladium nanocrystals: the effect of pseudo-halide thiocyanate ions. , 2011, Nanoscale.

[135]  Younan Xia,et al.  Polyol Synthesis of Silver Nanoparticles: Use of Chloride and Oxygen to Promote the Formation of Single-Crystal, Truncated Cubes and Tetrahedrons , 2004 .

[136]  Yiping Zhao,et al.  Novel nanostructures for SERS biosensing , 2008 .

[137]  J. Solla-Gullón,et al.  Pd adatom decorated (100) preferentially oriented Pt nanoparticles for formic acid electrooxidation. , 2010, Angewandte Chemie.

[138]  Benito Rodríguez-González,et al.  Synthesis and Optical Properties of Gold Nanodecahedra with Size Control , 2006 .

[139]  Jianping Xie,et al.  Protein-directed synthesis of highly fluorescent gold nanoclusters. , 2009, Journal of the American Chemical Society.

[140]  L. Liz‐Marzán,et al.  Bending contours in silver nanoprisms. , 2006, The journal of physical chemistry. B.

[141]  Younan Xia,et al.  Shape-controlled synthesis of metal nanocrystals: simple chemistry meets complex physics? , 2009, Angewandte Chemie.