Optical trapping and alignment of single gold nanorods by using plasmon resonances.

We demonstrate three-dimensional trapping and orientation of individual Au nanorods by using laser light slightly detuned from their longitudinal plasmon mode. Detuning to the long-wavelength side of the resonance allows stable trapping for several minutes, with an exponential dependence of trapping time on laser power (consistent with a Kramer's escape process). Detuning to the short-wavelength side causes repulsion of the rods from the laser focus. Alignment of the long axis of the rods with the trapping laser polarization is observed as a suppression of rotational diffusion about the short axis.

[1]  Johannes Hohlbein,et al.  Recurrence and photon statistics in fluorescence fluctuation spectroscopy. , 2004, Physical review letters.

[2]  J. Gordon,et al.  Motion of atoms in a radiation trap , 1980 .

[3]  David Klenerman,et al.  Optically Biased Diffusion of Single Molecules Studied by Confocal Fluorescence Microscopy , 1998 .

[4]  John T Fourkas,et al.  Highly efficient multiphoton-absorption-induced luminescence from gold nanoparticles. , 2005, Nano letters.

[5]  Z. Kam,et al.  Absorption and Scattering of Light by Small Particles , 1998 .

[6]  David Grier,et al.  Processing carbon nanotubes with holographic optical tweezers. , 2004, Optics express.

[7]  Richard N. Zare,et al.  Biased Diffusion, Optical Trapping, and Manipulation of Single Molecules in Solution , 1996 .

[8]  John E. Wessel,et al.  Surface-enhanced optical microscopy , 1985 .

[9]  Elliot L. Elson,et al.  Fluorescence correlation spectroscopy : theory and applications , 2001 .

[10]  Hongxing Xu,et al.  Surface-plasmon-enhanced optical forces in silver nanoaggregates. , 2002, Physical review letters.

[11]  Matthew Pelton Comment on "Theoretical study of the optical manipulation of semiconductor nanoparticles under an excitonic resonance condition". , 2004, Physical review letters.

[12]  Mattias Goksör,et al.  Optical Spectroscopy of Single Trapped Metal Nanoparticles in Solution , 2004 .

[13]  H. Tiziani,et al.  Multi-functional optical tweezers using computer-generated holograms , 2000 .

[14]  D. Grier A revolution in optical manipulation , 2003, Nature.

[15]  B. Nikoobakht,et al.  種結晶を媒介とした成長法を用いた金ナノロッド(NR)の調製と成長メカニズム , 2003 .

[16]  Michael Vollmer,et al.  Optical properties of metal clusters , 1995 .

[17]  R. A. Kennedy,et al.  Forward-backward non-linear filtering technique for extracting small biological signals from noise , 1991, Journal of Neuroscience Methods.

[18]  Biman Bagchi,et al.  Needlelike motion of prolate ellipsoids in the sea of spheres , 2001 .

[19]  Rongchao Jin,et al.  Correlating second harmonic optical responses of single Ag nanoparticles with morphology. , 2005, Journal of the American Chemical Society.

[20]  Steven M. Block,et al.  Optical trapping of metallic Rayleigh particles. , 1994, Optics letters.

[21]  Mostafa A. El-Sayed,et al.  Preparation and Growth Mechanism of Gold Nanorods (NRs) Using Seed-Mediated Growth Method , 2003 .

[22]  Yael Roichman,et al.  Manipulation and assembly of nanowires with holographic optical traps. , 2005, Optics express.

[23]  L. Oddershede,et al.  Expanding the optical trapping range of gold nanoparticles. , 2005, Nano letters.

[24]  Hongxing Xu,et al.  Surface Plasmon Enhanced Optical Forces in Silver Nano-aggregates , 2003 .

[25]  Ultrafast resonant optical scattering from single gold nanorods: Large nonlinearities and plasmon saturation , 2006 .

[26]  David G Grier,et al.  Transport and fractionation in periodic potential-energy landscapes. , 2004, Physical review. E, Statistical, nonlinear, and soft matter physics.

[27]  Takuya Iida,et al.  Theoretical study of the optical manipulation of semiconductor nanoparticles under an excitonic resonance condition. , 2003, Physical review letters.

[28]  M. Nieto-Vesperinas,et al.  Optical forces on small particles: attractive and repulsive nature and plasmon-resonance conditions. , 2003, Journal of the Optical Society of America. A, Optics, image science, and vision.

[29]  D. Grier,et al.  Sorting mesoscopic objects with periodic potential landscapes: optical fractionation. , 2004, Physical review. E, Statistical, nonlinear, and soft matter physics.

[30]  Philippe Guyot-Sionnest,et al.  Mechanism of silver(I)-assisted growth of gold nanorods and bipyramids. , 2005, The journal of physical chemistry. B.

[31]  Chu,et al.  Experimental observation of optically trapped atoms. , 1986, Physical review letters.