Colorizing of the stainless steel surface by single-beam direct femtosecond laser writing

This paper reports on the colorizing of the stainless steel surface by controlling the irradiation conditions of a single-beam femtosecond laser. We change the color of the stainless steel surface by femtosecond laser induced periodic self-organized nanogratings or microgratings on the sample surface. Colorizing of metal surface by periodic microholes, produced by femtosecond laser, is achieved for the first time. The laser modified stainless steel surfaces show different colors under different incident or azimuthal angles of the incident light, which changes in color indicate the dependence of the metal color on the angles (incident and azimuthal) of the incident light. We report, for the first time, the changes of metal color due to the change of the azimuthal angles of the incident light. Furthermore, the changes in the color of the laser modified metal surfaces are mainly due to the excitation of surface plasmon polaritons (SPPs) on the metal surface. The resonant angle of SPPs is different for different wavelength of light. As a result, under different incident or azimuthal angles different wavelength of light is trapped on the surface depending on the resonance for that particular wavelength; light of other wavelengths react naturally and contributes for the color change of the stainless steel surfaces. Finally, we discovered that the nanostructures produced inside the self-organized nanogratings and microholes play important roles for the propagation of the SPPs in parallel with the nanogratings and mcroholes, which nanostructures are responsible for a complex SPPs excitation on the sample surface.

[1]  E. Popov Total absorption of light in metallic gratings : a comparative analysis of spectral dependence for shallow and deep grooves , 1989 .

[2]  B. Knyazev,et al.  Fresnel reflection in optical components and detectors for the terahertz frequency band , 2007 .

[3]  Chunlei Guo,et al.  Femtosecond Laser Nanostructuring of Metals , 2006 .

[4]  R. H. Ritchie,et al.  Surface-Plasmon Resonance Effect in Grating Diffraction , 1968 .

[5]  Chunlei Guo,et al.  Residual thermal effects in Al following single ns- and fs-laser pulse ablation , 2006 .

[6]  Chunlei Guo,et al.  Enhanced energy coupling in femtosecond laser-metal interactions at high intensities. , 2006, Optics express.

[7]  Chunlei Guo,et al.  Enhanced absorptance of gold following multipulse femtosecond laser ablation , 2005 .

[8]  C. Noguez Surface Plasmons on Metal Nanoparticles: The Influence of Shape and Physical Environment , 2007 .

[9]  Chunlei Guo,et al.  Colorizing metals with femtosecond laser pulses , 2008 .

[10]  A. Vorobyev,et al.  Shot-to-shot correlation of residual energy and optical absorptance in femtosecond laser ablation , 2006 .

[11]  Chunlei Guo,et al.  Metallic Light Absorbers Produced by Femtosecond Laser Pulses , 2010 .

[12]  P. Griffiths,et al.  Angular Dependence of Diffuse Reflectance Infrared Spectra. Part II: Effect of Polarization , 1987 .

[13]  Chunlei Guo,et al.  Ultrafast dynamics of femtosecond laser-induced periodic surface pattern formation on metals , 2005 .

[14]  Chunlei Guo,et al.  Effects of nanostructure-covered femtosecond laser-induced periodic surface structures on optical absorptance of metals , 2007 .

[15]  Chunlei Guo,et al.  Periodic ordering of random surface nanostructures induced by femtosecond laser pulses on metals , 2007 .

[16]  Chunlei Guo,et al.  Direct observation of enhanced residual thermal energy coupling to solids in femtosecond laser ablation , 2005 .

[17]  Francisco J. Garcia-Vidal,et al.  Localized surface plasmons in lamellar metallic gratings , 1999 .

[18]  Daniel Maystre,et al.  Brewster incidence for metallic gratings , 1976 .