Ferroelectric Domain Structures and Electrical Properties of Fine-Grained Lead-Free Sodium Potassium Niobate Ceramics

Piezoelectric ceramics of the composition Na0.5K0.5NbO3 (NKN) with grain sizes in the range of 0.2–1 μm were fabricated by spark plasma sintering. Ferroelectric domain size decreases with decreasing grain size and non-180° ferroelectric domains walls were still visible in 200 nm sized grains. The Curie point of the ceramics was grain size independent. This suggests that the critical grain size for a single domain single grain structure for NKN is 99.5% theoretical density) to be made at T≥850°C. For the dense ceramics (grain size ≥350 nm), the room temperature dielectric constant and coercive field increased with decreasing grain size. The remnant polarization was grain size independent. The material sintered at 850°C is a very good candidate for lead-free piezoelectric applications because of its high piezoelectric constant (d33=160 ± 2 pC/N).

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