A New Hydrogen Sensor Based on SNS Fiber Interferometer with Pd/WO3 Coating

This paper presents a new hydrogen sensor based on a single mode–no core–single mode (SNS) fiber interferometer structure. The surface of the no core fiber (NCF) was coated by Pd/WO3 film to detect the variation of hydrogen concentration. If the hydrogen concentration changes, the refractive index of the Pd/WO3 film as well as the boundary condition for light propagating in the NCF will all be changed, which will then cause a shift into the resonant wavelength of interferometer. Therefore, the hydrogen concentration can be deduced by measuring the shift of the resonant wavelength. Experimental results demonstrated that this proposed sensor had a high detection sensitivity of 1.26857 nm/%, with good linearity and high accuracy (maximum 0.0055% hydrogen volume error). Besides, it also possessed the advantages of simple structure, low cost, good stability, and repeatability.

[1]  O. Frazao,et al.  A Review of Palladium-Based Fiber-Optic Sensors for Molecular Hydrogen Detection , 2012, IEEE Sensors Journal.

[2]  E. Obermeier,et al.  Heat-conduction microsensor based on silicon technology for the analysis of two- and three-component gas mixtures , 1993 .

[3]  C. C. Chan,et al.  Chitosan/PAA based fiber-optic interferometric sensor for heavy metal ions detection , 2016 .

[4]  X. Bevenot,et al.  Surface plasmon resonance hydrogen sensor using an optical fibre , 2000, International Conference on Optical Fibre Sensors.

[5]  S. Fardindoost,et al.  Detecting hydrogen using graphene quantum dots/WO3 thin films , 2016 .

[6]  Minghong Yang,et al.  Water photolysis effect on the long-term stability of a fiber optic hydrogen sensor with Pt/WO3 , 2016, Scientific Reports.

[7]  Roghayeh Ghasempour,et al.  Pd doped WO3 films prepared by sol–gel process for hydrogen sensing , 2010 .

[8]  Yong Zhao,et al.  Investigation of the high sensitivity RI sensor based on SMS fiber structure , 2014 .

[9]  Stephen R. Turnock,et al.  Assessing the potential of hybrid energy technology to reduce exhaust emissions from global shipping , 2012 .

[10]  Minghong Yang,et al.  Using Pd/WO3 composite thin films as sensing materials for optical fiber hydrogen sensors , 2010 .

[11]  W. Colella,et al.  Cleaning the Air and Improving Health with Hydrogen Fuel-Cell Vehicles , 2005, Science.

[12]  A. Mehta,et al.  Wavelength tunable fiber lens based on multimode interference , 2004, Journal of Lightwave Technology.

[13]  Minghong Yang,et al.  In-line Mach-Zehnder Interferometer and FBG with Pd film for simultaneous hydrogen and temperature detection , 2014 .

[14]  Minghong Yang,et al.  Performance of fiber Bragg grating hydrogen sensor coated with Pt-loaded WO3 coating , 2014 .

[15]  David S. Ginley,et al.  Hydrogen sensing with palladium‐coated optical fibers , 1988 .

[16]  Yong Zhao,et al.  Applications of Modal Interferences in Optical Fiber Sensors Based on Mismatch Methods , 2015 .

[17]  G. R. Astbury,et al.  Spontaneous ignition of hydrogen leaks: A review of postulated mechanisms , 2007 .

[18]  W. Peng,et al.  Multi-point fiber-optic refractive index sensor by using coreless fibers , 2016 .

[19]  A reflective intensity modulated fiber tilt angle sensor based on an all-photonic crystal fiber interferometer , 2016 .

[20]  Yong Zhao,et al.  Photonic crystal fiber modal interferometer with Pd/WO3 coating for real-time monitoring of dissolved hydrogen concentration in transformer oil. , 2016, The Review of scientific instruments.

[21]  Michael A. Butler,et al.  Micromirror optical-fiber hydrogen sensor , 1994 .

[22]  Minghong Yang,et al.  Fiber optic hydrogen sensors: a review , 2014 .

[23]  Ulrich Banach,et al.  Hydrogen Sensors - A review , 2011 .

[24]  Min Wang,et al.  Optical Fiber Grating Hydrogen Sensors: A Review , 2017, Sensors.

[25]  Yong Zhao,et al.  Hydrogen sensor based on high-birefringence fiber loop mirror with sol-gel Pd/WO3 coating , 2017 .

[26]  I. Dincer Renewable energy and sustainable development: a crucial review , 2000 .

[27]  Alex A. Kazemi,et al.  Highly sensitive hydrogen sensors using palladium coated fiber optics with exposed cores and evanescent field interactions , 1999 .

[28]  Ghenadii Korotcenkov,et al.  Review of electrochemical hydrogen sensors. , 2009, Chemical reviews.

[29]  T. A. Jones,et al.  The principles of the detection of flammable atmospheres by catalytic devices , 1973 .

[30]  Minghong Yang,et al.  Greatly etched fiber Bragg grating hydrogen sensor with Pd/Ni composite film as sensing material , 2012 .

[31]  Fiber optic hydrogen sensor based on an etched Bragg grating coated with palladium. , 2015, Applied optics.