Pressure and Temperature Dependence of the Hydrogen Oxidation and Evolution Reaction Kinetics on Pt Electrocatalysts via PEMFC-based Hydrogen-Pump Measurements

[1]  M. Mavrikakis,et al.  How coverage influences thermodynamic and kinetic isotope effects for H2/D2 dissociative adsorption on transition metals , 2020, Catalysis Science & Technology.

[2]  K. Ayers,et al.  Perspectives on Low-Temperature Electrolysis and Potential for Renewable Hydrogen at Scale. , 2019, Annual review of chemical and biomolecular engineering.

[3]  Yasumasa Fujii,et al.  A review of four case studies assessing the potential for hydrogen penetration of the future energy system , 2019, International Journal of Hydrogen Energy.

[4]  C. Radke,et al.  Fuel-Cell Catalyst-Layer Resistance via Hydrogen Limiting-Current Measurements , 2019, Journal of The Electrochemical Society.

[5]  Y. Chen,et al.  Anode Aging during PEMFC Start-Up and Shut-Down: H2-Air Fronts vs Voltage Cycles , 2018 .

[6]  Hubert A. Gasteiger,et al.  Cathode Loading Impact on Voltage Cycling Induced PEMFC Degradation: A Voltage Loss Analysis , 2018 .

[7]  Graham T. Smith,et al.  Support induced charge transfer effects on electrochemical characteristics of Pt nanoparticle electrocatalysts , 2017, Journal of Electroanalytical Chemistry.

[8]  Gregor S. Harzer,et al.  Tailoring Catalyst Morphology towards High Performance for Low Pt Loaded PEMFC Cathodes , 2018 .

[9]  H. Gasteiger,et al.  Origin of Superior HOR/HER Activity of Bimetallic Pt-Ru Catalysts in Alkaline Media Identified via Ru@Pt Core-Shell Nanoparticles , 2018 .

[10]  Yushan Yan,et al.  Perspective—Towards Establishing Apparent Hydrogen Binding Energy as the Descriptor for Hydrogen Oxidation/Evolution Reactions , 2018 .

[11]  A. Kucernak,et al.  Design principles for platinum nanoparticles catalysing electrochemical hydrogen evolution and oxidation reactions: edges are much more active than facets , 2017 .

[12]  K. Karan.  PEFC catalyst layer: Recent advances in materials, microstructural characterization, and modeling , 2017 .

[13]  H. Gasteiger,et al.  Analysis of Voltage Losses in PEM Water Electrolyzers with Low Platinum Group Metal Loadings , 2017 .

[14]  Vincent De Andrade,et al.  Hybrid approach combining multiple characterization techniques and simulations for microstructural analysis of proton exchange membrane fuel cell electrodes , 2017 .

[15]  H. Yano,et al.  Highly Active, CO-Tolerant, and Robust Hydrogen Anode Catalysts: Pt–M (M = Fe, Co, Ni) Alloys with Stabilized Pt-Skin Layers , 2017 .

[16]  H. Gasteiger,et al.  Influence of the Gas Diffusion Layer Compression on the Oxygen Transport in PEM Fuel Cells at High Water Saturation Levels , 2017 .

[17]  Gregor S. Harzer,et al.  The Key to High Performance Low Pt Loaded Electrodes , 2017 .

[18]  Anthony Kucernak,et al.  General Models for the Electrochemical Hydrogen Oxidation and Hydrogen Evolution Reactions: Theoretical Derivation and Experimental Results under Near Mass-Transport Free Conditions , 2016 .

[19]  Anusorn Kongkanand,et al.  The Priority and Challenge of High-Power Performance of Low-Platinum Proton-Exchange Membrane Fuel Cells. , 2016, The journal of physical chemistry letters.

[20]  Yushan Yan,et al.  Universal dependence of hydrogen oxidation and evolution reaction activity of platinum-group metals on pH and hydrogen binding energy , 2016, Science Advances.

[21]  Katherine C. Elbert,et al.  Elucidating Hydrogen Oxidation/Evolution Kinetics in Base and Acid by Enhanced Activities at the Optimized Pt Shell Thickness on the Ru Core , 2015 .

[22]  H. Gasteiger,et al.  Influence of the Gas Diffusion Layer Compression on the Oxygen Mass Transport in PEM Fuel Cells , 2015 .

[23]  A. Kucernak,et al.  Properties of the hydrogen oxidation reaction on Pt/C catalysts at optimised high mass transport conditions and its relevance to the anode reaction in PEFCs and cathode reactions in electrolysers , 2015 .

[24]  Y. Ishikawa,et al.  Electrochemical Hydrogen Oxidation on Pt(100): a Combined Direct Molecular Dynamics/Density Functional Theory Study , 2015, Electrocatalysis.

[25]  Jingguang G. Chen,et al.  Correlating hydrogen oxidation and evolution activity on platinum at different pH with measured hydrogen binding energy , 2015, Nature Communications.

[26]  Hubert A. Gasteiger,et al.  Hydrogen Oxidation and Evolution Reaction Kinetics on Carbon Supported Pt, Ir, Rh, and Pd Electrocatalysts in Acidic Media , 2015 .

[27]  H. Gasteiger,et al.  New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism , 2014 .

[28]  E. Gileadi,et al.  Defining the transfer coefficient in electrochemistry: An assessment (IUPAC Technical Report) , 2014 .

[29]  Juan P. Torreglosa,et al.  Hierarchical energy management system for stand-alone hybrid system based on generation costs and cascade control , 2014 .

[30]  H. Gasteiger,et al.  Kinetics of the Hydrogen Oxidation/Evolution Reaction on Polycrystalline Platinum in Alkaline Electrolyte Reaction Order with Respect to Hydrogen Pressure , 2014 .

[31]  K. Kudo,et al.  Model for investigation of oxygen transport limitation in a polymer electrolyte fuel cell , 2013 .

[32]  R. Ahluwalia,et al.  Kinetics of Hydrogen Oxidation and Hydrogen Evolution Reactions on Nanostructured Thin-Film Platinum Alloy Catalyst , 2013 .

[33]  K. Yager,et al.  Effect of Confinement on Structure, Water Solubility, and Water Transport in Nafion Thin Films , 2012 .

[34]  Wenbin Gu,et al.  Impact of Platinum Loading and Catalyst Layer Structure on PEMFC Performance , 2012 .

[35]  Yi Yu,et al.  A review on performance degradation of proton exchange membrane fuel cells during startup and shutdown processes: Causes, consequences, and mitigation strategies , 2012 .

[36]  H. Takenaka,et al.  Properties of Nafion membranes under PEM water electrolysis conditions , 2011 .

[37]  A. Weber,et al.  Modeling Low-Platinum-Loading Effects in Fuel-Cell Catalyst Layers , 2011 .

[38]  Yunsheng Ma,et al.  Revisiting H/Pt(111) by a combined experimental study of the H-D exchange reaction and first-principles calculations , 2011 .

[39]  G. Lindbergh,et al.  Hydrogen oxidation reaction on thin platinum electrodes in the polymer electrolyte fuel cell , 2010 .

[40]  H. Gasteiger,et al.  Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes , 2010 .

[41]  Thomas Bligaard,et al.  Modeling the Electrochemical Hydrogen Oxidation and Evolution Reactions on the Basis of Density Functional Theory Calculations , 2010 .

[42]  K. Neyerlin,et al.  Measurement of Oxygen Transport Resistance in PEM Fuel Cells by Limiting Current Methods , 2009 .

[43]  K. Aoki,et al.  Temperature-dependence of hydrogen oxidation reaction rates and CO-tolerance at carbon-supported Pt, Pt-Co, and Pt-Ru catalysts. , 2009, Physical Chemistry, Chemical Physics - PCCP.

[44]  S. Fletcher.  Tafel slopes from first principles , 2009 .

[45]  S. D. Fraser,et al.  Polarization study of a PEMFC with four reference electrodes at hydrogen starvation conditions , 2008 .

[46]  Mahlon Wilson,et al.  Scientific aspects of polymer electrolyte fuel cell durability and degradation. , 2007, Chemical reviews.

[47]  J. Jorné,et al.  Study of the Exchange Current Density for the Hydrogen Oxidation and Evolution Reactions , 2007 .

[48]  J. Jorné,et al.  Cathode Catalyst Utilization for the ORR in a PEMFC Analytical Model and Experimental Validation , 2007 .

[49]  J. Nørskov,et al.  Computational high-throughput screening of electrocatalytic materials for hydrogen evolution , 2006, Nature materials.

[50]  T. Springer,et al.  Dual-Pathway Kinetic Equation for the Hydrogen Oxidation Reaction on Pt Electrodes , 2006 .

[51]  María R. Gennero de Chialvo,et al.  Hydrogen diffusion effects on the kinetics of the hydrogen electrode reaction. Part I. Theoretical aspects , 2004 .

[52]  Wei-Mon Yan,et al.  Analysis of thermal and water management with temperature-dependent diffusion effects in membrane of proton exchange membrane fuel cells , 2004 .

[53]  Hubert A. Gasteiger,et al.  Dependence of PEM fuel cell performance on catalyst loading , 2004 .

[54]  Hubert A. Gasteiger,et al.  Handbook of fuel cells : fundamentals technology and applications , 2003 .

[55]  B. Conway,et al.  Relation of energies and coverages of underpotential and overpotential deposited H at Pt and other metals to the ‘volcano curve’ for cathodic H2 evolution kinetics , 2000 .

[56]  H. Gasteiger,et al.  Characterization of High‐Surface‐Area Electrocatalysts Using a Rotating Disk Electrode Configuration , 1998 .

[57]  Philip N. Ross,et al.  TEMPERATURE-DEPENDENT HYDROGEN ELECTROCHEMISTRY ON PLATINUM LOW-INDEX SINGLE-CRYSTAL SURFACES IN ACID SOLUTIONS , 1997 .

[58]  Donald W. Kirk,et al.  Electrocatalysis of the hydrogen oxidation and of the oxygen reduction reactions of Pt and some alloys in alkaline medium , 1987 .

[59]  G. Ertl,et al.  Adsorption of hydrogen on a Pt(111) surface , 1976 .

[60]  P. Stonehart,et al.  Reaction pathways and poisons—II: The rate controlling step for electrochemical oxidation of hydrogen on Pt in acid and poisoning of the reaction by CO , 1975 .

[61]  F. Will.  Hydrogen Adsorption on Platinum Single Crystal Electrodes I . Isotherms and Heats of Adsorption , 1965 .