Chemical reduction of graphene oxide using green reductants

Graphene has exceptional physical, chemical, mechanical, thermal and optical properties which offer huge potential for applications in various sectors. Chemical oxidation of graphite to graphene oxide followed by the reduction process is the commonly used method for mass scale production of graphene or reduced graphene oxide (RGO). Among the large number of chemical reducing agents used to prepare RGO or graphene, the most efficient reductant is hydrazine. It is toxic in nature and harmful to the environment, thus it is in high demand to use green reductants for RGO synthesis. We understand that due to high demand of graphene/graphene oxide/reduced graphene oxide recently and which is expected to be more in future, green synthesis methods are extremely important. In this article, we have studied the synthesis methods, characterization and the possible mechanism for green reduction, especially by ascorbic acid. This article could possibly motivate the researcher worldwide to innovate new green methods for mass scale production of graphene based materials.

[1]  Jinbin Liu,et al.  Toward a universal "adhesive nanosheet" for the assembly of multiple nanoparticles based on a protein-induced reduction/decoration of graphene oxide. , 2010, Journal of the American Chemical Society.

[2]  M. B. Davies,et al.  Vitamin C: Its Chemistry and Biochemistry , 1991 .

[3]  Yurii B. Shvetsov,et al.  Common Genetic Variation In Cellular Transport Genes and Epithelial Ovarian Cancer (EOC) Risk , 2015, PloS one.

[4]  S. Stankovich,et al.  Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide , 2007 .

[5]  Zhuyin Sui,et al.  Easy and green synthesis of reduced graphite oxide-based hydrogels , 2011 .

[6]  Yu Cao,et al.  Selective band gap manipulation of graphene oxide by its reduction with mild reagents , 2015 .

[7]  S. Bose,et al.  Dual role of glycine as a chemical functionalizer and a reducing agent in the preparation of graphene: an environmentally friendly method , 2012 .

[8]  W. Tremel,et al.  Green Approach for the Effective Reduction of Graphene Oxide Using Salvadora persica L. Root (Miswak) Extract , 2015, Nanoscale Research Letters.

[9]  H. Bustamante,et al.  Surfactant modified graphene oxide laminates for filtration , 2017 .

[10]  Omid Akhavan,et al.  Escherichia coli bacteria reduce graphene oxide to bactericidal graphene in a self-limiting manner , 2012 .

[11]  S. Aștilean,et al.  A new green, ascorbic acid-assisted method for versatile synthesis of Au–graphene hybrids as efficient surface-enhanced Raman scattering platforms , 2013 .

[12]  Kuo-Chuan Ho,et al.  Dye-sensitized solar cells with reduced graphene oxide as the counter electrode prepared by a green photothermal reduction process. , 2014, Chemphyschem : a European journal of chemical physics and physical chemistry.

[13]  M. Yoshimura,et al.  Graphene and graphene oxide for desalination. , 2016, Nanoscale.

[14]  Niranjan Karak,et al.  Green reduction of graphene oxide by aqueous phytoextracts , 2012 .

[15]  D. Pullini,et al.  Green-Reduction of Covalently Functionalized Graphene Oxide with Varying Stoichiometry , 2013 .

[16]  Kian Ping Loh,et al.  Hydrothermal Dehydration for the “Green” Reduction of Exfoliated Graphene Oxide to Graphene and Demonstration of Tunable Optical Limiting Properties , 2009 .

[17]  S. Bose,et al.  A green approach for the reduction of graphene oxide by wild carrot root , 2012 .

[18]  B. Cao,et al.  Green synthesis of carbon nanotube–graphene hybrid aerogels and their use as versatile agents for water purification , 2012 .

[19]  Quantization of ascorbic acid in ayurvedic amla capsule by various analytical techniques , 2013 .

[20]  Zhiqiang Wang,et al.  Environment-Friendly Method To Produce Graphene That Employs Vitamin C and Amino Acid , 2010 .

[21]  K. Sattler,et al.  Ultralight carbon nanofoam from naphtalene-mediated hydrothermal sucrose carbonization , 2015 .

[22]  Hui‐Ming Cheng,et al.  The reduction of graphene oxide , 2012 .

[23]  Fang Qian,et al.  Microbial reduction of graphene oxide by Shewanella , 2011 .

[24]  Mahmoud Amouzadeh Tabrizi,et al.  Green-synthesis of reduced graphene oxide nanosheets using rose water and a survey on their characteristics and applications , 2013 .

[25]  Y. Gogotsi,et al.  Highly controllable and green reduction of graphene oxide to flexible graphene film with high strength , 2013 .

[26]  S. K. Srivastava,et al.  Green synthesis of graphene. , 2013, Journal of nanoscience and nanotechnology.

[27]  S. Reich,et al.  Raman spectroscopy of graphite , 2004, Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences.

[28]  Fangfang Wu,et al.  Graphene oxide: the mechanisms of oxidation and exfoliation , 2012, Journal of Materials Science.

[29]  E. Samulski,et al.  Synthesis of water soluble graphene. , 2008, Nano letters.

[30]  Zhe Zhang,et al.  Sodium citrate: A universal reducing agent for reduction / decoration of graphene oxide with au nanoparticles , 2011 .

[31]  R. Ruoff,et al.  All-organic vapor sensor using inkjet-printed reduced graphene oxide. , 2010, Angewandte Chemie.

[32]  Jitao Chen,et al.  Reduction of graphene oxide at room temperature with vitamin C for RGO–TiO2 photoanodes in dye-sensitized solar cell , 2015 .

[33]  Andre K. Geim,et al.  Electric Field Effect in Atomically Thin Carbon Films , 2004, Science.

[34]  Kasturi Muthoosamy,et al.  Exceedingly biocompatible and thin-layered reduced graphene oxide nanosheets using an eco-friendly mushroom extract strategy , 2015, International journal of nanomedicine.

[35]  J. Tascón,et al.  Environmentally friendly approaches toward the mass production of processable graphene from graphite oxide , 2011 .

[36]  Lina Shi,et al.  Fabrication and Characteristics of Reduced Graphene Oxide Produced with Different Green Reductants , 2015, PloS one.

[37]  Y. Nishina,et al.  Graphene oxide: The new membrane material , 2015 .

[38]  Mi-Hee Kim,et al.  Biocompatible reduced graphene oxide prepared by using dextran as a multifunctional reducing agent. , 2011, Chemical communications.

[39]  C. Lai,et al.  Green preparation of reduced graphene oxide using a natural reducing agent , 2015 .

[40]  S. Ray Application and Uses of Graphene Oxide and Reduced Graphene Oxide , 2015 .

[41]  A. Hirsch,et al.  Graphene oxide: efficiency of reducing agents. , 2013, Chemical communications.

[42]  Xianzhong Sun,et al.  Electrochemical reduction of graphene oxide films: Preparation, characterization and their electrochemical properties , 2012 .

[43]  Jacek Klinowski,et al.  Structure of Graphite Oxide Revisited , 1998 .

[44]  Jiali Zhang,et al.  Reduction of graphene oxide via L-ascorbic acid. , 2010, Chemical communications.

[45]  Tapas Kuila,et al.  Simultaneous bio-functionalization and reduction of graphene oxide by baker's yeast , 2012 .

[46]  Jun‐Jie Zhu,et al.  Ultrasound assisted reduction of graphene oxide to graphene in L-ascorbic acid aqueous solutions: kinetics and effects of various factors on the rate of graphene formation. , 2014, Ultrasonics sonochemistry.

[47]  Ya‐Ping Sun,et al.  Supercritical fluid conversion of graphene oxides , 2012 .

[48]  C. Chia,et al.  University of Malaya from the Selectedworks of Huang Nay Ming Simple Room-temperature Preparation of High- Yield Large-area Graphene Oxide Simple Room-temperature Preparation of High-yield Large-area Graphene Oxide , 2022 .

[49]  H. A. Yusr,et al.  Comparative Study on Methods for Preparation of Gold Nanoparticles , 2012 .

[50]  M. Salavati‐Niasari,et al.  Green synthesis and characterization of graphene nanosheets , 2015 .

[51]  B. Guo,et al.  Hydrolysable tannin as environmentally friendly reducer and stabilizer for graphene oxide , 2011 .

[52]  D. Fadhel Spectrophotometric Determination of Ascorbic Acid in Aqueous Solutions , 2012 .

[53]  K. Cen,et al.  Green preparation of reduced graphene oxide for sensing and energy storage applications , 2014, Scientific Reports.

[54]  M. Maaza,et al.  Free-Green Synthesis and Dynamics of Reduced Graphene Sheets via Sun Light Irradiation , 2015 .

[55]  Hua‐Yu Zhang,et al.  Preparation and characterization of reduced graphene oxide using ascorbic acid and sodium citrate as binary reductant , 2017 .

[56]  H. Metselaar,et al.  The green reduction of graphene oxide , 2016 .

[57]  J. Tascón,et al.  Vitamin C Is an Ideal Substitute for Hydrazine in the Reduction of Graphene Oxide Suspensions , 2010 .

[58]  M. Fathy,et al.  Optimizing the preparation parameters of GO and rGO for large-scale production , 2016, Journal of Materials Science.

[59]  H. Asgharzadeh,et al.  Fast and fully-scalable synthesis of reduced graphene oxide , 2015, Scientific Reports.

[60]  Jie Yin,et al.  Facile synthesis of soluble graphene via a green reduction of graphene oxide in tea solution and its biocomposites. , 2011, ACS applied materials & interfaces.

[61]  H. Bustamante,et al.  Mechanism of water transport in graphene oxide laminates , 2016, Chemical science.

[62]  D. Pullini,et al.  Influence of synthesis conditions on properties of green-reduced graphene oxide , 2013, Journal of Nanoparticle Research.

[63]  James M Tour,et al.  Reduction of graphene oxide via bacterial respiration. , 2010, ACS nano.

[64]  E. Andrijanto,et al.  Facile synthesis of graphene from graphite using ascorbic acid as reducing agent , 2016 .

[65]  Jingye(李景烨) Li,et al.  Flexible graphene fibers prepared by chemical reduction-induced self-assembly , 2014 .

[66]  Die Reduktion von Graphitoxyd mit Schwefelwasserstoff , 1934 .

[67]  A. Buasri,et al.  Preparation and Characterization of Reduced Graphene Oxide Sheets via Water-Based Exfoliation and Reduction Methods , 2013 .

[68]  Yongsheng Chen,et al.  Graphene-based conducting inks for direct inkjet printing of flexible conductive patterns and their applications in electric circuits and chemical sensors , 2011 .

[69]  Lidong Li,et al.  An environment-friendly preparation of reduced graphene oxide nanosheets via amino acid , 2011, Nanotechnology.

[70]  Shaojun Dong,et al.  Reducing sugar: new functional molecules for the green synthesis of graphene nanosheets. , 2010, ACS nano.