Kinetics and Products of Heterogeneous Hydroxyl Radical Oxidation of Isoprene Epoxydiol-Derived Secondary Organic Aerosol

[1]  B. Turpin,et al.  Isoprene Epoxydiol-Derived Sulfated and Nonsulfated Oligomers Suppress Particulate Mass Loss during Oxidative Aging of Secondary Organic Aerosol. , 2022, Environmental science & technology.

[2]  J. Offenberg,et al.  The C5–Alkene Triol Conundrum: Structural Characterization and Quantitation of Isoprene-Derived C5H10O3 Reactive Uptake Products , 2022, Environmental Science & Technology Letters.

[3]  Yue Zhang,et al.  Initial pH Governs Secondary Organic Aerosol Phase State and Morphology after Uptake of Isoprene Epoxydiols (IEPOX). , 2022, Environmental science & technology.

[4]  A. Laskin,et al.  Solid organic-coated ammonium sulfate particles at high relative humidity in the summertime Arctic atmosphere , 2022, Proceedings of the National Academy of Sciences of the United States of America.

[5]  Zhenfa Zhang,et al.  Morphology and Viscosity Changes after Reactive Uptake of Isoprene Epoxydiols in Submicrometer Phase Separated Particles with Secondary Organic Aerosol Formed from Different Volatile Organic Compounds , 2022, ACS Earth and Space Chemistry.

[6]  K. Bates,et al.  Aqueous Photochemistry of 2-Methyltetrol and Erythritol as Sources of Formic Acid and Acetic Acid in the Atmosphere , 2021, ACS Earth and Space Chemistry.

[7]  M. Mills,et al.  Future changes in isoprene-epoxydiol-derived secondary organic aerosol (IEPOX SOA) under the Shared Socioeconomic Pathways: the importance of physicochemical dependency , 2021 .

[8]  P. Rairoux,et al.  Decrease in sulfate aerosol light backscattering by reactive uptake of isoprene epoxydiols. , 2021, Physical chemistry chemical physics : PCCP.

[9]  R. Lindenmaier,et al.  Aerosol characteristics at the Southern Great Plains site during the HI-SCALE campaign , 2020, Atmospheric Chemistry and Physics.

[10]  K. Sellegri,et al.  A biogenic secondary organic aerosol source of cirrus ice nucleating particles , 2020, Nature Communications.

[11]  A. Ault.  Aerosol Acidity: Novel Measurements and Implications for Atmospheric Chemistry. , 2020, Accounts of chemical research.

[12]  P. Wach,et al.  Tracing the biogenic secondary organic aerosol markers in rain, snow and hail. , 2020, Chemosphere.

[13]  A. Ault,et al.  Simultaneous Optical Photothermal Infrared (O-PTIR) and Raman Spectroscopy of Submicrometer Atmospheric Particles , 2020, Microscopy and Microanalysis.

[14]  B. Turpin,et al.  Heterogeneous Hydroxyl Radical Oxidation of Isoprene-Epoxydiol-Derived Methyltetrol Sulfates: Plausible Formation Mechanisms of Previously Unexplained Organosulfates in Ambient Fine Aerosols , 2020, Environmental Science & Technology Letters.

[15]  M. Claeys,et al.  Structural characterization of lactone-containing MW 212 organosulfates originating from isoprene oxidation in ambient fine aerosol. , 2020, Environmental science & technology.

[16]  R. Fry,et al.  Isoprene-derived Secondary Organic Aerosol Induces the Expression of micro RNAs (miRNAs) Associated with Inflammatory/Oxidative Stress Response in Lung Cells. , 2019, Chemical research in toxicology.

[17]  D. Worsnop,et al.  Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles , 2019, ACS Earth and Space Chemistry.

[18]  G. Richmond,et al.  On the Rise: Experimental and Computational VSFS Studies of Pyruvic Acid and its Surface Active Oligomer Species at the Air-Water Interface. , 2019, The journal of physical chemistry. A.

[19]  D. Chandler,et al.  The Cooling Rate and Volatility Dependent Glass Forming Properties of Organic Aerosols Measured by Broadband Dielectric Spectroscopy. , 2019, Environmental science & technology.

[20]  Zhenfa Zhang,et al.  Reactive Uptake of Isoprene Epoxydiols Increases the Viscosity of the Core of Phase-Separated Aerosol Particles , 2019, ACS Earth and Space Chemistry.

[21]  B. Rosati,et al.  Effect of temperature on the formation of highly oxygenated organic molecules (HOMs) from alpha-pinene ozonolysis , 2019, Atmospheric Chemistry and Physics.

[22]  S. Martin,et al.  Increasing Isoprene Epoxydiol-to-Inorganic Sulfate Aerosol Ratio Results in Extensive Conversion of Inorganic Sulfate to Organosulfur Forms: Implications for Aerosol Physicochemical Properties. , 2019, Environmental science & technology.

[23]  Zhenfa Zhang,et al.  Heterogeneous OH oxidation of isoprene-epoxydiol-derived organosulfates: kinetics, chemistry and formation of inorganic sulfate , 2018, Atmospheric Chemistry and Physics.

[24]  Ibrahim M. Al-Naiema,et al.  Organosulfates in Atlanta, Georgia: anthropogenic influences on biogenic secondary organic aerosol formation , 2018, Atmospheric Chemistry and Physics.

[25]  J. Offenberg,et al.  Trends in the oxidation and relative volatility of chamber-generated secondary organic aerosol , 2018, Aerosol science and technology : the journal of the American Association for Aerosol Research.

[26]  S. Martin,et al.  Isoprene photo-oxidation products quantify the effect of pollution on hydroxyl radicals over Amazonia , 2018, Science Advances.

[27]  J. Seinfeld,et al.  Gas-Phase Reactions of Isoprene and Its Major Oxidation Products. , 2018, Chemical reviews.

[28]  Rachel L Merzel,et al.  Atomic Force Microscopy-Infrared Spectroscopy of Individual Atmospheric Aerosol Particles: Subdiffraction Limit Vibrational Spectroscopy and Morphological Analysis. , 2017, Analytical chemistry.

[29]  Francesco Ferrini,et al.  Isoprene Responses and Functions in Plants Challenged by Environmental Pressures Associated to Climate Change , 2017, Front. Plant Sci..

[30]  M. Petters,et al.  Hygroscopicity of Organic Compounds as a Function of Carbon Chain Length and Carboxyl, Hydroperoxy, and Carbonyl Functional Groups. , 2017, The journal of physical chemistry. A.

[31]  A. Lee,et al.  Rapid Aqueous-Phase Photooxidation of Dimers in the α-Pinene Secondary Organic Aerosol , 2017 .

[32]  U. Pöschl,et al.  Global distribution of particle phase state in atmospheric secondary organic aerosols , 2017, Nature Communications.

[33]  A. Nenes,et al.  Simulating Aqueous-Phase Isoprene-Epoxydiol (IEPOX) Secondary Organic Aerosol Production During the 2013 Southern Oxidant and Aerosol Study (SOAS). , 2017, Environmental science & technology.

[34]  H. Kjaergaard,et al.  Isomerization of Second-Generation Isoprene Peroxy Radicals: Epoxide Formation and Implications for Secondary Organic Aerosol Yields. , 2017, Environmental science & technology.

[35]  J. D. de Gouw,et al.  Volatility and lifetime against OH heterogeneous reaction of ambient isoprene-epoxydiols-derived secondary organic aerosol (IEPOX-SOA) , 2016 .

[36]  Lance Lee,et al.  The Reactive-Diffusive Length of OH and Ozone in Model Organic Aerosols. , 2016, The journal of physical chemistry. A.

[37]  M. Hallquist,et al.  High-Molecular Weight Dimer Esters Are Major Products in Aerosols from α-Pinene Ozonolysis and the Boreal Forest , 2016 .

[38]  M. Glasius,et al.  Effect of Organic Coatings, Humidity and Aerosol Acidity on Multiphase Chemistry of Isoprene Epoxydiols. , 2016, Environmental science & technology.

[39]  J. D. de Gouw,et al.  Modeling the radical chemistry in an oxidation flow reactor: radical formation and recycling, sensitivities, and the OH exposure estimation equation. , 2016, The journal of physical chemistry. A.

[40]  D. Jacob,et al.  Aqueous-phase mechanism for secondary organic aerosol formation from isoprene: application to the Southeast United States and co-benefit of SO2 emission controls. , 2015, Atmospheric chemistry and physics.

[41]  A. Goldstein,et al.  Characterization of a real-time tracer for isoprene epoxydiols-derived secondary organic aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements , 2015 .

[42]  Michael Schulz,et al.  Evaluation of observed and modelled aerosol lifetimes using radioactive tracers of opportunity and an ensemble of 19 global models , 2015 .

[43]  J. Seinfeld,et al.  Formation of Low Volatility Organic Compounds and Secondary Organic Aerosol from Isoprene Hydroxyhydroperoxide Low-NO Oxidation. , 2015, Environmental science & technology.

[44]  J. Jimenez,et al.  Real-time measurements of secondary organic aerosol formation and aging from ambient air in an oxidation flow reactor in the Los Angeles area , 2015 .

[45]  P. Shepson,et al.  Aqueous Processing of Atmospheric Organic Particles in Cloud Water Collected via Aircraft Sampling. , 2015, Environmental science & technology.

[46]  J. R. Hite,et al.  Fine-particle water and pH in the southeastern United States , 2014 .

[47]  Zhenfa Zhang,et al.  Light-absorbing oligomer formation in secondary organic aerosol from reactive uptake of isoprene epoxydiols. , 2014, Environmental science & technology.

[48]  M. Salamone,et al.  Reaction Pathways of Alkoxyl Radicals. The Role of Solvent Effects on C–C Bond Fragmentation and Hydrogen Atom Transfer Reactions , 2014, Synlett.

[49]  A. Goldstein,et al.  Role of Water and Phase in the Heterogeneous Oxidation of Solid and Aqueous Succinic Acid Aerosol by Hydroxyl Radicals , 2014 .

[50]  J. Seinfeld,et al.  Gas phase production and loss of isoprene epoxydiols. , 2014, The journal of physical chemistry. A.

[51]  Jian Wang,et al.  CCN Activity of Organic Aerosols Observed Downwind of Urban Emissions during CARES , 2013 .

[52]  Stephen J. Fuller,et al.  Molecular composition of biogenic secondary organic aerosols using ultrahigh resolution mass spectrometry: comparing laboratory and field studies , 2013 .

[53]  P. Shepson,et al.  Organosulfates in cloud water above the Ozarks' isoprene source region , 2013 .

[54]  D. Luecken,et al.  Epoxide pathways improve model predictions of isoprene markers and reveal key role of acidity in aerosol formation. , 2013, Environmental science & technology.

[55]  Marc J. Assael,et al.  Reference Correlation of the Viscosity of Squalane from 273 to 373 K at 0.1 MPa , 2013 .

[56]  A. Hofzumahaus,et al.  Missing OH source in a suburban environment near Beijing: observed and modelled OH and HO 2 concentrations in summer 2006 , 2013 .

[57]  Curtis Marcott,et al.  AFM–IR: Combining Atomic Force Microscopy and Infrared Spectroscopy for Nanoscale Chemical Characterization , 2012, Applied spectroscopy.

[58]  L. Emmons,et al.  The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions , 2012 .

[59]  Jared D. Smith,et al.  OH-initiated heterogeneous aging of highly oxidized organic aerosol. , 2012, The journal of physical chemistry. A.

[60]  J. Seinfeld,et al.  Modeling the gas-particle partitioning of secondary organic aerosol: the importance of liquid-liquid phase separation , 2012 .

[61]  E. Edgerton,et al.  Isoprene epoxydiols as precursors to secondary organic aerosol formation: acid-catalyzed reactive uptake studies with authentic compounds. , 2012, Environmental science & technology.

[62]  Ulrich Pöschl,et al.  Gas uptake and chemical aging of semisolid organic aerosol particles , 2011, Proceedings of the National Academy of Sciences.

[63]  J. Seinfeld,et al.  Measurements of isoprene-derived organosulfates in ambient aerosols by aerosol time-of-flight mass spectrometry - part 1: single particle atmospheric observations in Atlanta. , 2011, Environmental science & technology.

[64]  Chih-Chung Chang,et al.  Observation and modelling of OH and HO 2 concentrations in the Pearl River Delta 2006: a missing OH source in a VOC rich atmosphere , 2011 .

[65]  D. Worsnop,et al.  Eddy covariance measurements with high-resolution time-of-flight aerosol mass spectrometry: a new approach to chemically resolved aerosol fluxes , 2010 .

[66]  I. Barmpadimos,et al.  Relating hygroscopicity and composition of organic aerosol particulate matter , 2010 .

[67]  Jared D. Smith,et al.  Chemical sinks of organic aerosol: kinetics and products of the heterogeneous oxidation of erythritol and levoglucosan. , 2010, Environmental science & technology.

[68]  J. Seinfeld,et al.  Characterization and quantification of isoprene-derived epoxydiols in ambient aerosol in the southeastern United States. , 2010, Environmental science & technology.

[69]  John H. Seinfeld,et al.  Organic aerosol components observed in Northern Hemispheric datasets from Aerosol Mass Spectrometry , 2010 .

[70]  J. Seinfeld,et al.  Reactive intermediates revealed in secondary organic aerosol formation from isoprene , 2009, Proceedings of the National Academy of Sciences.

[71]  J. Seinfeld,et al.  Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene , 2009, Science.

[72]  Jared D. Smith,et al.  The heterogeneous reaction of hydroxyl radicals with sub-micron squalane particles: a model system for understanding the oxidative aging of ambient aerosols , 2009 .

[73]  D. Blake,et al.  Airborne measurement of OH reactivity during INTEX-B , 2008 .

[74]  John H Seinfeld,et al.  Effect of acidity on secondary organic aerosol formation from isoprene. , 2007, Environmental science & technology.

[75]  Armin Sorooshian,et al.  Evidence for organosulfates in secondary organic aerosol. , 2007, Environmental science & technology.

[76]  R. Monson,et al.  The interacting effects of elevated atmospheric CO2 concentration, drought and leaf-to-air vapour pressure deficit on ecosystem isoprene fluxes , 2005, Oecologia.

[77]  Ivan Kourtchev,et al.  Characterization of oxygenated derivatives of isoprene related to 2-methyltetrols in Amazonian aerosols using trimethylsilylation and gas chromatography/ion trap mass spectrometry. , 2005, Rapid communications in mass spectrometry : RCM.

[78]  J. Jimenez,et al.  Characterization of urban and rural organic particulate in the Lower Fraser Valley using two Aerodyne Aerosol Mass Spectrometers , 2004 .

[79]  M. Andreae,et al.  Formation of Secondary Organic Aerosols Through Photooxidation of Isoprene , 2004, Science.

[80]  R. Monson,et al.  Increased CO2 uncouples growth from isoprene emission in an agriforest ecosystem , 2003, Nature.

[81]  J. E. Bennett,et al.  Product Studies of the Mutual Termination Reactions of sec-Alkylperoxy Radicals: Evidence for Non-Cyclic Termination , 1974 .

[82]  Glen A. Russell,et al.  Deuterium-isotope Effects in the Autoxidation of Aralkyl Hydrocarbons. Mechanism of the Interaction of PEroxy Radicals1 , 1957 .

[83]  M. Kulmala,et al.  Nucleation and Atmospheric Aerosols , 2007 .

[84]  under a Creative Commons License. Atmospheric Chemistry , 2006 .

[85]  J. Seinfeld,et al.  Appendix H : Particle Phase Acidity and Oligomer Formation in Secondary Organic Aerosol , 2006 .

[86]  Evert Ljungström,et al.  Impact of humidity on the ozone initiated oxidation of limonene, delta3-carene, and alpha-pinene. , 2006, Environmental science & technology.

[87]  J. Seinfeld,et al.  Atmospheric Chemistry and Physics Changes in Organic Aerosol Composition with Aging Inferred from Aerosol Mass Spectra , 2022 .