论文信息 - Encapsulation of nitrophenol into AIPO4-5: Effect of isomers on optical second harmonic generations

Encapsulation of nitrophenol into AIPO4-5: Effect of isomers on optical second harmonic generations

Three isomers of nitrophenol molecules were loaded in one-dimensional channels of AlPO4-5 by vapor-phase diffusion process. The resulting materials (o-NP/,m-NP/ and p-NP/AlPO4-5) have been characterized by thermoanalytic and spectroscopic methods, and their nonlinear optical properties have been investigated in powder form. From the results, these materials were found to exhibit second harmonic generation (SHG). The order of SHG intensity was m-NP/AlPO4-5 < p-NP/AlPO4-5 < o-NP/AlPO4-5, and SHG intensity of o-NP/AlPO4-5 remarkably depended on amount of loadings.

[1] Goto,et al. Ferromagnetic properties of potassium clusters incorporated into zeolite LTA. , 1993, Physical review. B, Condensed matter.

[2] J. Caro,et al. Raman study on p-nitroaniline in channels of the molecular sieve AlPO4–5 , 1993 .

[3] J. Caro,et al. Optical characterization of organized adsorbates in zeolite microcrystals : Polarized absorption spectroscopy , 1996 .

[4] F. Marlow,et al. Raman Spectroscopic Investigation of the Physical State of para-Nitroaniline in Channels of the AIPO4-5 Molecular Sieve , 1994 .

[5] G. Stucky,et al. Inclusion tuning of nonlinear optical materials: switching the SHG of p-nitroaniline and 2-methyl-p-nitroaniline with molecular sieve hosts , 1988 .

[6] Jürgen Caro,et al. Optical second harmonic generation (SHG) on p-nitroaniline in large cyrstals of AIPO4-5 and ZSM-5 , 1992 .

[7] S. K. Kurtz,et al. A Powder Technique for the Evaluation of Nonlinear Optical Materials , 1968 .

[8] Goto,et al. Ferromagnetism of potassium clusters incorporated into zeolite LTA. , 1992, Physical review letters.

[9] J. Oudar,et al. Origin of the second-order optical susceptibilities of crystalline substituted benzene , 1975 .

[10] G. Stucky,et al. Polarized IR Spectra of p-Nitroaniline-Loaded AlP04-5 Single Crystals , 1995 .

[11] G. Stucky,et al. Inclusion tuning of nonlinear optical materials: SHG of organic guests in molecular sieve hosts , 1989 .