Environmental assessment of a road site built with MSWI residue.

A 23-year-old road built with MSWI residue (mix of fly and bottom ashes) was investigated through the environmental assessment of the residue, soils (adjacent to and underlying the road) and seepage waters. The pH and ANC(4.3) of the material indicate a low carbonation and a high alkaline stock. The material leaches few trace elements. The underlying road soil shows significant effects with respect to K and Na, attributable to the MSWI residue. Effects regarding Cd, Cr, Cu and Ni are observed, yet pollution thresholds are not exceeded. Compared to groundwater thresholds, the MSWI residue percolate is of poor to very poor quality (French reference system - FWQAS) in terms of pH, K, Na, Cl(-), F(-), As and Cu. It lies above the intervention values of the Dutch Soil Protection Act (DSPA) for Cu, Ni and Pb. Downstream, water from the road shoulder (W(Sdr)) is of very poor quality with respect to Na and Cl(-), and fair to poor quality regarding K. All other parameters comply with the best quality thresholds (FWQAS and DSPA). The high Cl(-) concentration of W(Sdr) would not fit for direct discharge in any watercourse. Toward a weakly-mineralised water, Cd and Cu would also be penalizing. The geometry of the road site creates penalizing conditions increasing the washing of the MSWI residue. The road structure does not cause downstream effect as regards trace elements, but effects exist for Cl(-), Na and K. Opposite downstream effects are observed (Ca, Mg, Mn and SO(4)(2-)) due to farming treatments and the nature of the local soil.

[1]  R. Comans,et al.  A consistent geochemical modelling approach for the leaching and reactive transport of major and trace elements in MSWI bottom ash , 2008 .

[2]  Nathalie Delville Etude mineralogique et physico-chimique des machefers d'incineration des ordures menageres (MIOM) en vue d'une utilisation en technique routiere , 2004 .

[3]  Jiri Hyks,et al.  Leaching from MSWI bottom ash: evaluation of non-equilibrium in column percolation experiments. , 2009, Waste management.

[4]  Defne Apul,et al.  A REVIEW OF WATER MOVEMENT IN THE HIGHWAY ENVIRONMENT: IMPLICATIONS FOR RECYCLED MATERIALS USE , 2002 .

[5]  D. Sparks Environmental Soil Chemistry , 1995 .

[6]  P. Baccini,et al.  Acid neutralizing capacity of municipal waste incinerator bottom ash. , 1995, Environmental science & technology.

[7]  H. Lo,et al.  The metal-leaching and acid-neutralizing capacity of MSW incinerator ash co-disposed with MSW in landfill sites. , 2007, Journal of hazardous materials.

[8]  D. François,et al.  Comportement mecanique et environnemental de deux chaussees anciennes realisees avec des machefers d'incineration d'ordures menageres , 2000 .

[9]  Bernd M. Rode,et al.  Dynamical properties of water molecules in the hydration shells of Na+ and K+: ab initio QM/MM molecular dynamics simulations , 2004 .

[10]  Kai Uwe Totsche,et al.  Effective rates of heavy metal release from alkaline wastes--quantified by column outflow experiments and inverse simulations. , 2008, Journal of contaminant hydrology.

[11]  D François,et al.  Monitoring of leachate at a test road using treated fly ash from municipal solid waste incinerator. , 2007, Journal of hazardous materials.

[12]  Michael Zwicky Hauschild,et al.  Environmental assessment of roads constructed with and without bottom ash from municipal solid waste incineration , 2006 .

[13]  C. Seguí,et al.  Characterization of bottom ash in municipal solid waste incinerators for its use in road base. , 2004, Waste management.

[14]  J. M. Chimenos,et al.  Short-term natural weathering of MSWI bottom ash. , 2000, Journal of hazardous materials.

[15]  Laurent Chateau Environmental acceptability of beneficial use of waste as construction material--state of knowledge, current practices and future developments in Europe and in France. , 2007, Journal of hazardous materials.

[16]  B. V. Raij,et al.  Rate processes of calcium, magnesium and potassium desorption from variable-charge soils by mixed ion-exchange resins , 1999 .

[17]  R. Comans,et al.  The leaching of major and trace elements from MSWI bottom ash as a function of pH and time , 2006 .

[18]  C. Pagotto Etude sur l'émission et le transfert dans les eaux et les sols des éléments traces métalliques et des hydrocarbures en domaine routier , 1999 .

[19]  J. Corté FRENCH DESIGN MANUAL FOR PAVEMENT STRUCTURES , 1997 .

[20]  D Croney,et al.  MOVEMENT AND DISTRIBUTION OF WATER IN SOIL IN RELATION TO HIGHWAY DESIGN AND PERFORMANCE , 1958 .

[21]  Patrice Piantone,et al.  Mineralogical study of secondary mineral phases from weathered MSWI bottom ash: implications for the modelling and trapping of heavy metals , 2004 .

[22]  Tien Fang Fwa,et al.  The Handbook of Highway Engineering , 2005 .

[23]  D. François Relargage en métaux de MIOM à différents stades de leur filière de valorisation , 2003 .

[24]  D. Manning,et al.  Manganese removal from mine waters - investigating the occurrence and importance of manganese carbonates , 2006 .

[25]  C. Fléhoc,et al.  Stable isotope evidence for the atmospheric origin of CO2 involved in carbonation of MSWI bottom ash , 2006 .

[26]  Jurate Kumpiene,et al.  Evaluation and prediction of emissions from a road built with bottom ash from municipal solid waste incineration (MSWI). , 2006, The Science of the total environment.

[27]  D. Bendz,et al.  Leaching of different elements from subbase layers of alternative aggregates in pavement constructions. , 2006, Journal of hazardous materials.

[28]  B. J. Alloway,et al.  Heavy metals in soils , 1990 .

[29]  Gaston Charlot Les réactions chimiques en solution : l'analyse qualitative minérale , 1969 .

[30]  Erik Kärrman,et al.  Environmental systems analysis of the use of bottom ash from incineration of municipal waste for road construction , 2006 .

[31]  M. Bonneau,et al.  Constituants et Propriétés du Sol , 1979 .

[32]  I. Szabolcs,et al.  Salt Affected Soils , 1988 .

[33]  Gaëlle Ducom,et al.  Carbon dioxide sequestration in municipal solid waste incinerator (MSWI) bottom ash. , 2006, Journal of hazardous materials.