论文信息 - Factors influencing solvent adduct formation by calixarenes in the solid state.

Factors influencing solvent adduct formation by calixarenes in the solid state.

Structural studies of seven very differently functionalised derivatives of calix[4]arene have been used to provide an analysis of the numerous factors which may influence solvent adduct formation by calixarenes. Evidence is presented that even where a solvent guest is included within the calixarene cavity, interactions solely within the cavity cannot be seen as the sole influences upon the guest position and orientation.

[1] A. Bilyk,et al. Systematic structural coordination chemistry of p-tert-butyltetrathiacalix[4]arene: 1. Group 1 elements and congeners. , 2001, Inorganic chemistry.

[2] G. Enright,et al. Weak Intermolecular Interactions and Molecular Recognition: Structure and Dynamics of the Benzene and Pyridine p-tert-Butylcalix[4]arene Inclusions† , 1999 .

[3] J. Atwood,et al. Anion Binding within the Cavity of π-Metalated Calixarenes , 1997 .

[4] G. Enright,et al. Solid-State NMR and Diffraction Studies of a Tunable p-tert-Butylcalix[4]arene·Guest Structure§ , 1997 .

[5] D. Reinhoudt,et al. Transduction of selective recognition of heavy metal ions by chemically modified field effect transistors (CHEMFETs) , 1992 .

[6] D. Reinhoudt,et al. Ethanol complex of 1,3-diethoxy-p-tert-butylcalix[4]arene , 1992 .

[7] Fumio Hamada,et al. X-ray diffraction evidence for aromatic π hydrogen bonding to water , 1991, Nature.