Design and fabrication of electro-optic polymer modulators and switches

Electro-optic (EO) polymers are interesting materials for realising active functions in integrated optics devices, since they can have relatively high EO coefficients and they can be easily combined or integrated with several (passive) materials. EO interaction can be exploited for obtaining modulation or switching in polymer-based devices using several principles (e.g. Mach–Zehnder, Digital Optical Switch or tuned coupling to surface plasmons), which have been investigated and tested using a number of different materials. We compare these principles in view of several aspects of practical importance: realistic values of EO coefficients and wavelength-dependent attenuation, optical, electrical and chemical compatibility of substrate, guiding and cladding layers, channel definition by etching (inverted) ridge waveguides or by photo-bleaching, local and global poling methods, polarisation-dependence, and the design of efficient high-bandwidth travelling wave electrodes. In most of the investigated devices, we employ a waveguiding structure based on silicon and its oxynitrides, exploiting the fact that the refractive index of silicon oxynitride can be accurately adjusted over a wide range by adjusting its composition. We will discuss the practical difficulties encountered and show the obtained results with phase- and intensity modulators and switches.

[1]  L. Lüer,et al.  (Photo)conductivity of conjugated oligomer films: mobile charge carrier formation by oxygen , 1998 .

[2]  G. R. Möhlmann Polymeric optochips: splitters, switches and modulators , 1994 .

[3]  P. Günter,et al.  Novel electro-optic molecular cocrystals with ideal chromophoric orientation and large second-order optical nonlinearities , 1998 .

[4]  Sang‐Shin Lee,et al.  Polarization-Insensitive Digital Optical Switch Using an Electro-Optic Polymer Rib Waveguide , 1997, Organic Thin Films for Photonics Applications.

[5]  Mart B. J. Diemeer,et al.  Low-loss nonlinear optical polymeric waveguide materials and devices , 1995, Optics & Photonics.

[6]  Jung Y. Huang,et al.  Real-Time Poling Vapor Co-deposition of Dye-Doped Second-Order Nonlinear Optical Polymer Thin Films , 1997 .

[7]  Junshi Guo,et al.  Nonlinear optical crosslinked polymers and interpenetrating polymer networks containing azo-benzothiazole chromophore groups , 1998 .

[8]  Junya Kobayashi,et al.  Directional couplers using fluorinated polyimide waveguides , 1998 .

[9]  Alfred Driessen,et al.  Novel integrated optic intensity modulator based on mode coupling , 1994 .

[10]  H. Fetterman,et al.  Demonstration of 110 GHz electro-optic polymer modulators , 1997 .

[11]  Mart B. J. Diemeer,et al.  Photoinduced channel waveguide formation in nonlinear optical polymers , 1990 .

[12]  James H. Bechtel,et al.  Long-term stable direct current bias operation in electro-optic polymer modulators with an electrically compatible multilayer structure , 1997 .

[13]  P. Lambeck,et al.  Silicon oxynitride planar waveguiding structures for application in optical communication , 1998 .

[14]  C. Teng,et al.  Optical power handling properties of polymeric nonlinear optical waveguides , 1993 .

[15]  Gijsbertus J.M. Krijnen,et al.  Evaluation of polymer based third order nonlinear integrated optics devices , 1998 .

[16]  L. Hornak Polymers for lightwave and integrated optics : technology and applications , 1992 .

[17]  D. Reinhoudt,et al.  Novel calixarenes in thin films for efficient second harmonic generation , 1993 .