ON THE pH DEPENDENCE OF G/sub reducing/ IN THE RADIATION CHEMISTRY OF AQUEOUS SOLUTIONS.

Alkaline N2O-saturated solutions of 2-D-2-propanol and ferri-ferrocyanide mixtures were irradiated. The results indicate that Gred, which is the sum of Geaq + GH = 3.3, is pH-independent in the range 11 – 14. The results do not indicate that Geaq and GH are pH-dependent.

[1]  M. Anbar,et al.  A compilation of specific bimolecular rate constants for the reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals with inorganic and organic compounds in aqueous solution , 1967 .

[2]  C. H. Cheek.  Radiation chemistry of aqueous nitrous oxide solutions , 1967 .

[3]  F. Dainton,et al.  Radical and molecular product yields in X-irradiated alkaline aqueous solutions , 1967 .

[4]  D. Walker.  The hydrated electron , 1967 .

[5]  Moïse Haissïnsky,et al.  Radiolyse γ de solutions de ferro- et ferri-cyanures de potassium - II. — Solutions acides dégazées. III. — Solutions alcalines , 1966 .

[6]  F. Dainton,et al.  Effects of solute concentration and pH on radical and molecular yields in X-irradiated aqueous solution , 1966 .

[7]  F. Dainton,et al.  The photolysis of aqueous systems at 1849 A I. Solutions containing nitrous oxide , 1965, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[8]  F. Dainton,et al.  The radiation chemistry of aqueous solutions of nitrous oxide , 1965, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[9]  E. Hayon.  Radical and molecular yields in the radiolysis of alkaline aqueous solutions , 1965 .

[10]  E. Hayon.  Solute scavenging effects in regions of high radical concentration produced in radiation chemistry , 1965 .

[11]  C. H. Cheek,et al.  Determination of Argon and Oxygen by Gas Chromatography. , 1964 .

[12]  C. H. Cheek,et al.  The Radiation-Induced Chain Reaction between Nitrous Oxide and Hydrogen in Aqueous Solutions1 , 1964 .

[13]  E. Hayon.  Mechanism of the Dependence of Yields upon pH and Solute Concentration in the γ-Irradiation of Water , 1964 .

[14]  C. M. Beck,et al.  THE RADIOLYSIS OF DEAERATED AQUEOUS SOLUTIONS OF 2-PROPANOL CONTAINING NITROUS OXIDE , 1964 .

[15]  F. Dainton,et al.  pH effects in the γ-radiolysis of aqueous solutions , 1963, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[16]  C. H. Cheek,et al.  THE RADIATION CHEMISTRY OF ALKALINE HYPOBROMITE SOLUTIONS , 1963 .

[17]  M. Simic,et al.  Nature and reactivity of the primary reducing species in the radiolysis of aqueous solutions , 1963 .

[18]  J. Rabani,et al.  Yield and Reactivity of Electrons and H Atoms in Irradiated Aqueous Solutions , 1962 .

[19]  F. Dainton,et al.  The Effect of pH on the Radical Yields in the γ-Radiolysis of Aqueous Systems , 1962, Nature.

[20]  F. Dainton,et al.  Forms of H and OH produced in the radiolysis of aqueous system , 1962, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[21]  C. H. Cheek,et al.  Determination of Dissolved Gases in Aqueous Solutions by Gas Chromatography. , 1962 .

[22]  J. Jortner,et al.  Role of Ferrous Hydride in the Oxidation of Ferrous Ion by Hydrogen Atoms , 1960, Nature.

[23]  G. Scholes,et al.  Effects of pH and the Nature of the Primary Species in the Radiolysis of Aqueous Solutions , 1960, Nature.