Origin and Evolution of the Um Egat and Dungash Orogenic Gold Deposits, Egyptian Eastern Desert: Evidence from Fluid Inclusions in Quartz

Shear zone-related, mesothermal gold deposits of Um Egat and Dungash in the Egyptian Eastern Desert are hosted by greenschist facies metavolcanic and/or metasedimentary rocks of Pan-African age. Both deposits comprise boudinaged quartz veins that show evidence of incipient recrystallization, and are similar in alteration style, structural control, and mineralogy. The ore mineralogy includes pyrite, arsenopyrite ± pyrrhotite ± chalcopyrite ± galena; gold occurs both in the veins, usually included in arsenopyrite, pyrite, or pyrrhotite next to fragments of altered country rocks, or disseminated in the alteration haloes. Arsenic in arsenopyrite and Aliv in chlorite geothermometers indicate that wall-rock alteration and ore mineral precipitation occurred at temperatures between 400° and 250°C. Fluid inclusions in vein quartz occur in clusters, or along trails. Three types of fluid inclusions were identified based on petrography and laser micro-Raman spectroscopy: (1) two-phase carbonic inclusions with CO2 + CH4 ± N2 ± H2O, (2) two-phase aqueous inclusions, and (3) three-phase aqueous-carbonic inclusions with CH4. Final melting of ice (Tmf) for most inclusions occurs at temperatures between −4° and 0°C, indicating a low salinity ( 300°C, but cluster into two distinct groups for each type of inclusion. Inclusions from the same trail or cluster are commonly characterized by different degrees of fill or different Th values. Field, petrographic, and microthermometric data suggest that low-salinity aqueous-carbonic fluids interacted with graphite-bearing metasedimentary rocks to form CH4 at T >400°C and P >3 kbars. These reduced fluids leached gold as they circulated through the metavolcanic rocks, carrying it in the form of bisulfide complexes. Interaction of these aqueous-carbonic fluids with the country rocks caused hydrothermal alteration and precipitated gold-bearing sulfides in the alteration zones. A drop of pressure during the migration of these fluids to shallower depths along the shear zones led to phase separation at T ≤300°C and P ≤2.3 kbars. Quartz crystallizing over a range of lower temperatures and pressures trapped carbonic and aqueous fluids as separate inclusions in clusters along pseudosecondary and secondary trails. Postdepositional deformation caused decrepitation of some inclusions, and the stretching and leakage of others, increasing Th to >250°C. Deformation also remobilized the gold, depositing it as globules of higher fineness in secondary sites.

[1]  B. Zoheir,et al.  The tectono-metamorphic evolution of the central part of the Neoproterozoic Allaqi–Heiani suture, south Eastern Desert of Egypt , 2007 .

[2]  S. Hagemann,et al.  The Bronzewing lode-gold deposit, Western Australia: P–T–X evidence for fluid immiscibility caused by cyclic decompression in gold-bearing quartz-veins , 2001 .

[3]  D. Klemm,et al.  Gold of the Pharaohs - 6000 years of gold mining in Egypt and Nubia , 2001 .

[4]  R. Bakker,et al.  A mechanism for preferential H2O leakage from fluid inclusions in quartz, based on TEM observations , 1994 .

[5]  R. Kerrich,et al.  Nitrogen isotope systematics of mesothermal lode gold deposits: Metamorphic, granitic, meteoric water, or mantle origin? , 1999 .

[6]  S. Scott,et al.  Phase relations involving arsenopyrite in the system Fe-As-S and their application , 1976 .

[7]  F. Ahmed,et al.  Setting of gold mineralization in the northern Red Sea Hills of Sudan , 1984 .

[8]  H. Harraz A genetic model for a mesothermal Au deposit: evidence from fluid inclusions and stable isotopic studies at El Sid Gold Mine, Eastern Desert, Egypt , 2000 .

[9]  J. Tullis Deformation of Granitic Rocks: Experimental Studies and Natural Examples , 2002 .

[10]  Nagy Shawky Botros,et al.  A new classification of the gold deposits of Egypt , 2004 .

[11]  C. Ramboz,et al.  Fluid immiscibility in natural processes: Use and misuse of fluid inclusion data: II. Interpretation of fluid inclusion data in terms of immiscibility , 1982 .

[12]  S. Sterner,et al.  Preferential water loss from synthetic fluid inclusions , 1993 .

[13]  R. Stern Petrogenesis and tectonic setting of late Precambrian ensimatic volcanic rocks, central eastern desert of Egypt , 1981 .

[14]  W. Maclean,et al.  Systematics of chlorite alteration at the Phelps Dodge massive sulfide deposit, Matagami, Quebec , 1987 .

[15]  S. Hagemann,et al.  Hydrothermal Fluid Evolution within the Cadillac Tectonic Zone, Abitibi Greenstone Belt, Canada: Relationship to Auriferous Fluids in Adjacent Second- and Third-Order Shear Zones , 2002 .

[16]  R. Bakker Package FLUIDS 1. Computer programs for analysis of fluid inclusion data and for modelling bulk fluid properties , 2003 .

[17]  M. Cathelineau Cation site occupancy in chlorites and illites as a function of temperature , 1988, Clay Minerals.

[18]  C. Teyssier,et al.  An evaluation of quartzite flow laws based on comparisons between experimentally and naturally deformed rocks , 2001 .

[19]  H. Harraz Fluid inclusions in the mesozonal gold deposit at Atud mine, Eastern Desert, Egypt , 2002 .

[20]  K. Stüwe,et al.  On the timing relationship between fluid production and metamorphism in metamorphic piles: Some implications for the origin of post-metamorphic gold mineralisation , 1993 .

[21]  R. Xavier,et al.  Fluid evolution and chemical controls in the Fazenda Maria Preta (FMP) gold deposit, Rio Itapicuru Greenstone Belt, Bahia, Brazil , 1999 .

[22]  A. Barker Post‐entrapment modification of fluid inclusions due to overpressure: evidence from natural samples , 1995 .

[23]  S. Scott Chemical behaviour of sphalerite and arsenopyrite in hydrothermal and metamorphic environments , 1983, Mineralogical Magazine.

[24]  N. S. Botros Metallogeny of gold in relation to the evolution of the Nubian Shield in Egypt , 2002 .

[25]  Brian D. Smith,et al.  Distinguishing barren and auriferous veins in the Sigma Mine, Val-d'Or, Quebec , 1993 .

[26]  J. R. Lang,et al.  Intrusion-related gold systems: the present level of understanding , 2001 .

[27]  E. Mikucki Hydrothermal transport and depositional processes in Archean lode-gold systems: A review , 1998 .

[28]  K. Khalil,et al.  Alteration Patterns Related to Hydrothermal Gold Mineralizaition in Meta‐andesites at Dungash Area, Eastern Desert, Egypt , 2001 .

[29]  P. Morgan Egypt in the framework of global tectonics , 1990 .

[30]  E. Oelkers,et al.  SUPCRT92: a software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000 ° C , 1992 .

[31]  C. Teyssier,et al.  Thermomechanical evolution of a ductile duplex , 1997 .

[32]  R. Heilbronner,et al.  Dynamic recrystallization of quartz: correlation between natural and experimental conditions , 2002, Geological Society, London, Special Publications.

[33]  H. B.,et al.  Mineral Deposits , 2018, Nature.

[34]  V. Sisson,et al.  Fluid inclusions in carpholite-bearing metasediments and blueschists from NE Oman Constraints on P-T evolution , 2004 .

[35]  B. Zoheir Gold mineralization in the Um El Tuyor area, South Eastern Desert, Egypt , 2004 .

[36]  D. Groves,et al.  Fluid Chemical Evolution as a Factor in Controlling the Distribution of Gold at the Archean Golden Crown Lode Gold Deposit, Murchison Province, Western Australia , 2002 .

[37]  F. Robert,et al.  Gold Deposits in Metamorphic Belts: Overview of Current Understanding,Outstanding Problems, Future Research, and Exploration Significance , 2003 .

[38]  J. Dubessy,et al.  vX properties of CH 4 -CO 2 and CO 2 -N 2 fluid inclusions; modelling for T<31 degrees C and P<400 bars , 1994 .

[39]  H. Helgeson,et al.  Calculation of the thermodynamic and geochemical consequences of nonideal mixing in the system H2O-CO2-NaCl on phase relations in geologic systems: Equation of state for H2O-CO2-NaCl fluids at high pressures and temperatures , 1983 .

[40]  K. Khalil,et al.  Genesis of the gold mineralization at the Dungash gold mine area, Eastern Desert, Egypt: a mineralogical microchemical study , 2003 .

[41]  J. Naden,et al.  Role of methane and carbon dioxide in gold deposition , 1989, Nature.

[42]  D. K. Davies,et al.  Mineralogical Association of Canada: Short Course Handbook , 1981 .

[43]  E. L. Johnson,et al.  Syndeformational fluid trapping in quartz: determining the pressure-temperature conditions of deformation from fluid inclusions and the formation of pure CO2 fluid inclusions during grain-boundary migration , 1995 .

[44]  R. Bodnar,et al.  Do fluid inclusions in high-grade metamorphic terranes preserve peak metamorphic density during retrograde decompression? , 1995 .

[45]  Yinqi Li,et al.  Fluid Inclusion and Noble Gas Studies of the Dongping Gold Deposit, Hebei Province, China: A Mantle Connection for Mineralization? , 2003 .

[46]  Richard J. Goldfarb,et al.  Orogenic gold deposits : A proposed classification in the context of their crustal distribution and relationship to other gold deposit types , 1998 .

[47]  A. Afifi,et al.  MINFILE; a microcomputer program for storage and manipulation of chemical data on minerals , 1988 .

[48]  R. Bakker Adaptation of the Bowers and Helgeson (1983) equation of state to the H2O–CO2–CH4–N2–NaCl system , 1999 .