Spatial characterization of red and white skin potatoes using nano-second laser induced breakdown in air

We presents spectroscopic study of the plasma generated by a Q-switched Nd:YAG (1064 nm) laser irradiation of the flesh of red and white skin potatoes. From the spectra recorded with spectrometer (LIBS2500+, Ocean Optics, USA) 11 elements were identified in red skin potato, whereas, the white skin potato was found to have nine elements. Their relative concentrations were estimated using CF-LIBS method for the plasma in local thermodynamic equilibrium. The target was placed in ambient air at atmospheric pressure. The electron temperature and number density were calculated from Boltzmann plot and stark broadened line profile methods, respectively using Fe I spectral lines. The spatial distribution of plasma parameters were also studied which show a decreasing trend of 6770 K–4266 K and (3–2.0) × 10 16 cm -3 . Concentrations of the detected elements were monitored as a function of depth of the potatoes. Our study reveals a decreasing tendency in concentration of iron from top to the centre of potato’s flesh, whereas, the concentrations of other elements vary randomly.

[1]  S. Haq,et al.  Spectroscopic characterization of laser ablated silicon plasma , 2014 .

[2]  M. A. Baig,et al.  Quantitative studies of copper plasma using laser induced breakdown spectroscopy , 2011 .

[3]  G. Ramsay,et al.  The three-dimensional distribution of minerals in potato tubers. , 2011, Annals of botany.

[4]  T. Miano,et al.  Heavy metal concentrations in soils as determined by laser-induced breakdown spectroscopy (LIBS), with special emphasis on chromium. , 2009, Environmental research.

[5]  Matthieu Baudelet,et al.  Space-resolved analysis of trace elements in fresh vegetables using ultraviolet nanosecond laser-induced breakdown spectroscopy , 2008 .

[6]  Jagdish P. Singh,et al.  Laser‐Induced Breakdown Spectroscopy, Elemental Analysis , 2006 .

[7]  D. Cremers,et al.  Handbook of Laser-Induced Breakdown Spectroscopy: Cremers/Handbook of Laser-induced Breakdown Spectroscopy , 2006 .

[8]  Y. Yip,et al.  High-throughput determination of seven trace elements in food samples by inductively coupled plasma-mass spectrometry. , 2006, Journal of AOAC International.

[9]  J. Leblanc,et al.  Dietary exposure estimates of 18 elements from the 1st French Total Diet Study , 2005, Food additives and contaminants.

[10]  G. Doner,et al.  Evaluation of digestion procedures for the determination of iron and zinc in biscuits by flame atomic absorption spectrometry , 2004 .

[11]  J. A. Aguilera,et al.  Spatial characterization of laser-induced plasmas by deconvolution of spatially resolved spectra. , 2003, Applied optics.

[12]  J. Hermann,et al.  Local thermal equilibrium plasma modeling for analyses of gas-phase reactions during reactive-laser ablation , 2002 .

[13]  F. Barbosa,et al.  Determination of Cd and Pb in food slurries by GFAAS using cryogenic grinding for sample preparation , 2002, Analytical and bioanalytical chemistry.

[14]  David W. Hahn,et al.  On-line analysis of ambient air aerosols using laser-induced breakdown spectroscopy , 2001 .

[15]  Mohamed Chaker,et al.  Temporal characterization of femtosecond laser pulses induced plasma for spectrochemical analysis of aluminum alloys , 2001 .

[16]  Vincent Detalle,et al.  An evaluation of a commercial Échelle spectrometer with intensified charge-coupled device detector for materials analysis by laser-induced plasma spectroscopy , 2001 .

[17]  F. Krug,et al.  Lead determination in slurries of biological materials by ETAAS using a W-Rh permanent modifier , 2001, Fresenius' journal of analytical chemistry.

[18]  H. Griem Principles of Plasma Spectroscopy , 1997 .

[19]  Jim J. Chang,et al.  Laser‐plasma interaction during visible‐laser ablation of methods , 1996 .

[20]  B. Luk’yanchuk,et al.  An analytical model for three-dimensional laser plume expansion into vacuum in hydrodynamic regime , 1996 .

[21]  T. L. Thiem,et al.  Interaction of a Laser Beam with Metals. Part II: Space-Resolved Studies of Laser-Ablated Plasma Emission , 1992 .

[22]  G. Cristoforetti,et al.  Local Thermodynamic Equilibrium in Laser-Induced Breakdown Spectroscopy: Beyond the McWhirter criterion , 2010 .

[23]  M. Soylak,et al.  Determination of trace element contents of baby foods from Turkey , 2007 .

[24]  Y. Sahan,et al.  ICP-MS analysis of a series of metals (Namely: Mg, Cr, Co, Ni, Fe, Cu, Zn, Sn, Cd and Pb) in black and green olive samples from Bursa, Turkey , 2007 .

[25]  M. Soylak,et al.  Evaluation of trace element contents in canned foods marketed from Turkey , 2007 .

[26]  C. S. Kira,et al.  Determination of major and minor elements in dairy products through inductively coupled plasma optical emission spectrometry after wet partial digestion and neutron activation analysis , 2007 .

[27]  Israel Schechter,et al.  Laser-Induced Breakdown Spectroscopy (LIBS): Preface , 2006 .

[28]  Israel Schechter,et al.  Laser-induced breakdown spectroscopy (LIBS) : fundamentals and applications , 2006 .

[29]  L. Marinangeli,et al.  Investigation of LIBS feasibility for in situ planetary exploration: An analysis on Martian rock analogues , 2004 .

[30]  Ö. Elmacı,et al.  Trace element and heavy metal concentrations in fruits and vegetables of the Gediz River region , 2002 .