High-Pressure Trickle-Bed Reactors: A Review

A concise review of relevant experimental observations and modeling of high-pressure trickle-bed reactors, based on recent studies, is presented. The following topics are considered:  flow regime transitions, pressure drop, liquid holdup, gas−liquid interfacial area and mass-transfer coefficient, catalyst wetting efficiency, catalyst dilution with inert fines, and evaluation of trickle-bed models for liquid-limited and gas-limited reactions. The effects of high-pressure operation, which is of industrial relevance, on the physicochemical and fluid dynamic parameters are discussed. Empirical and theoretical models developed to account for the effect of high pressure on the various parameters and phenomena pertinent to the topics discussed are briefly described.

[1]  K. Østergaard Gas-Liquid-Particle Operations in Chemical Reaction Engineering* , 1968 .

[2]  H. Gierman Design of laboratory hydrotreating reactors: Scaling Down of Trickle-flow Reactors , 1988 .

[3]  J. Charpentier Gas-Liquid Reactors , 1978 .

[4]  Yuanxin Wu,et al.  Comparison of trickle-bed and upflow reactor performance at high pressure: Model predictions and experimental observations , 1996 .

[5]  Vito Specchia,et al.  Trickle-bed reactors: state of art and perspectives , 1992 .

[6]  F. Larachi,et al.  Mass transfer characteristics of fixed beds with cocurrent upflow and downflow. A special refence to the effect of pressure. , 1992 .

[7]  A. Vogelpohl,et al.  Effective interfacial area in irrigated packed columns , 1974 .

[8]  R. Koros Scale-Up Considerations for Mixed Phase Catalytic Reactors , 1981 .

[9]  Dimitris Tsamatsoulis,et al.  Simulation of non-ideal flow in a trickle bed hydrotreater by the cross-flow model , 1995 .

[10]  M. Duduković Catalyst effectiveness factor and contacting efficiency in trickle‐bed reactors , 1977 .

[11]  P. Trambouze Multiphase Catalytic Reactors in the Oil Industry: an Introduction , 1991 .

[12]  K. Westerterp,et al.  Interfacial Areas and Gas Hold-ups in Bubble Columns and Packed Bubble Columns at Elevated Pressures , 1989 .

[13]  S. Sundaresan,et al.  Time-dependent vertical gas—liquid flow in packed beds , 1992 .

[14]  Yuanxin Wu,et al.  Evaluation of trickle bed reactor models for a liquid limited reaction , 1996 .

[15]  A. Almstedt,et al.  Influence of pressure on the minimum fluidization velocity , 1991 .

[16]  V. Specchia,et al.  Hydrodynamics and solid‐liquid contacting effectiveness in trickle‐bed reactors , 1978 .

[17]  Gabriel Wild,et al.  Influence of gas density on the hydrodynamics of cocurrent gas-liquid upflow fixed bed reactors , 1994 .

[18]  A. Akgerman,et al.  Determination of wetting efficiencies for a trickle-bed reactor at high temperatures and pressures , 1987 .

[19]  J. M. Smith,et al.  Trickle‐bed reactors: A review , 1983 .

[20]  Sankaran Sundaresan,et al.  Onset of pulsing in two‐phase cocurrent downflow through a packed bed , 1988 .

[21]  Milorad P. Dudukovic,et al.  Pressure drop, liquid holdup, and flow regime transition in trickle flow , 1993 .

[22]  E. Talmor,et al.  Two‐phase downflow through catalyst beds: Part I. Flow maps , 1977 .

[23]  N. Fígoli,et al.  Colorimetric evaluation of the efficiency of liquid-solid contacting in trickle flow , 1988 .

[24]  Rüdiger Lange,et al.  Mass transfer in trickle-bed reactors at low reynolds number , 1981 .

[25]  N. Papayannakos,et al.  Axial dispersion and hold-up in a bench-scale trickle-bed reactor at operating conditions , 1994 .

[26]  Raghunath V. Chaudhari,et al.  Three Phase Catalytic Reactors , 1982 .

[27]  V. G. Rao,et al.  SOLID-LIQUID MASS-TRANSFER IN PACKED-BEDS WITH COCURRENT GAS-LIQUID DOWNFLOW , 1985 .

[28]  J. Smith,et al.  Trickle‐bed reactor performance. Part II. Reaction studies , 1975 .

[29]  J. Charpentier,et al.  Some liquid holdup experimental data in trickle-bed reactors for foaming and nonfoaming hydrocarbons , 1975 .

[30]  Charles N. Satterfield,et al.  Trickle‐bed reactors , 1975 .

[31]  The effect of pressure on minimum fluidisation velocity , 1984 .

[32]  O. Molerus,et al.  Resistance of particle beds at Reynolds numbers up to Re ≈ 104 , 1989 .

[33]  H. Shulman,et al.  Performance of packed columns. II. Wetted and effective‐interfacial areas, gas ‐ and liquid‐phase mass transfer rates , 1955 .

[34]  Faïçal Larachi,et al.  Experimental study of a trickle-bed reactor operating at high pressure: two-phase pressure drop and liquid saturation , 1991 .

[35]  M. A. Latifi,et al.  Liquid—solid mass transfer in a packed bed with downward cocurrent gas—liquid flow: An organic liquid phase with high Schmidt number , 1988 .

[36]  N. Midoux,et al.  FLOW PATTERN, PRESSURE LOSS AND LIQUID HOLDUP DATA IN GAS-LIQUID DOWNFLOW PACKED BEDS WITH FOAMING AND NONFOAMING HYDROCARBONS , 1976 .

[37]  M P Duduković,et al.  Recent advances in the analysis and design of trickle-bed reactors , 1987 .

[38]  J. M. Smith,et al.  Oxidation of sulfur dioxide in a trickle-bed reactor , 1981 .

[39]  J. Levec,et al.  Solid‐liquid mass transfer in packed beds with cocurrent downward two‐phase flow , 1990 .

[40]  J. Smith,et al.  Trickle-Bed Oxidation Reactors , 1978 .

[41]  R. Reid,et al.  The Properties of Gases and Liquids , 1977 .

[42]  Gilbert F. Froment,et al.  Hydrodesulfurization of dibenzothiophene on a CoMo/Al2O3 catalyst : Reaction network and kinetics , 1996 .

[43]  Milorad P. Dudukovic,et al.  A comparison of current models for isothermal trickle-bed reactors. Application to a model reaction system , 1984 .

[44]  André Laurent,et al.  Effet de la pression sur la transition ruisselant-pulsé dans les réacteurs catalytiques à lit fixe arrosé , 1993 .

[45]  S. N. Upadhyay,et al.  Particle-Fluid Mass Transfer in Fixed and Fluidized Beds , 1977 .

[46]  Milorad P. Dudukovic,et al.  Trickle-Bed Reactors: Dynamic Tracer Tests, Reaction Studies, and Modeling of Reactor Performance , 1982 .

[47]  Mahmoud Saada FLUID MECHANICS OF CO-CURRENT TWO-PHASE FLOW IN PACKED BEDS: PRESSURE DROP AND LIQUID HOLDUP STUDIES , 1975 .

[48]  H. Hofmann,et al.  Multiphase Catalytic Packed-Bed Reactors , 1978 .

[49]  Pierre Trambouze,et al.  Two-phase flow catalytic reactor, influence of hydrodynamics on selectivity , 1995 .

[50]  P. F. Way,et al.  The role of the liquid phase in the performance of a trickle bed reactor , 1972 .

[51]  Milorad P. Dudukovic,et al.  Pressure drop and liquid holdup in high pressure trickle-bed reactors , 1994 .

[52]  P. Galtier,et al.  Liquid flow non-idealities and hold-up in a pilot scale packed bed reactor with cocurrent gas-liquid upflow , 1996 .

[53]  Milorad P. Dudukovic,et al.  Catalyst bed dilution for improving catalyst wetting in laboratory trickle‐bed reactors , 1996 .

[54]  Milorad P. Dudukovic,et al.  Trickle‐bed reactors: Liquid diffusional effects in a gas‐limited reaction , 1987 .

[55]  PRESSURE DROP IN FLOW OF A NEARLY CRITICAL FLUID THROUGH PACKED BEDS OF SPHERES , 1990 .

[56]  Milorad P. Dudukovic,et al.  A phenomenological model for pressure drop, liquid holdup, and flow regime transition in gas-liquid trickle flow , 1992 .

[57]  Michael P. Harold,et al.  Bimolecular exothermic reaction with vaporization in the half-wetted slab catalyst , 1993 .

[58]  M. Crine,et al.  Recent Trends in the Modelling of Catalytic Trickle-Bed Reactors , 1983 .

[59]  O. M. Martinez,et al.  Effectiveness Factor of Partially Wetted Catalyst Particles: Evaluation and Application to the Modeling of Trickle Bed Reactors , 1988 .

[60]  J. Charpentier Recent progress in two phase gas—liquid mass transfer in packed beds , 1976 .

[61]  Klaas R. Westerterp,et al.  Hydrodynamics in a cocurrent gas-liquid trickle bed at elevated pressures , 1991 .

[62]  V. Specchia,et al.  Oxidation of ethyl alcohol in trickle bed reactors: Analysis of the conversion rate , 1985 .

[63]  Klaas R. Westerterp,et al.  The transition between trickle flow and pulse flow in a cocurrent gas—liquid trickle-bed reactor at elevated pressures , 1990 .

[64]  G. Baldi,et al.  Solid-Liquid Mass Transfer in Concurrent Two-Phase Flow through Packed Beds , 1978 .

[65]  K. Westerterp,et al.  Residence time distribution and hold-up in a cocurrent upflow packed bed reactor at elevated pressure , 1990 .

[66]  Milorad P. Dudukovic,et al.  Multiphase Reactors: Models and Experimental Verification , 1991 .

[67]  F. Stüber,et al.  Modelling of three phase catalytic upflow reactor: A significant chemical determination of liquid-solid and gas-liquid mass transfer coefficients , 1996 .

[68]  Kazuo Endo,et al.  CHARACTERISTICS OF GAS-FLUIDISED BEDS UNDER PRESSURE , 1981 .

[69]  G. Baldi Design and Scale-Up of Trickle Bed Reactors. Solid-Liquid Contacting Effetiveness , 1981 .

[70]  A. Germain Industrial Applications of Three Phase Catalytic Fixed Bed Reactors , 1983 .

[71]  P. Trambouze Engineering of Hydrotreating Processes , 1992 .

[72]  P. Galtier,et al.  Hydrodynamic effects in bench scale hydrotreaters operating in cocurrent gas-liquid upflow mode , 1992 .

[73]  S. Ergun Fluid flow through packed columns , 1952 .

[74]  K. Chao,et al.  Correlation of solubility of hydrogen in hydrocarbon solvents , 1981 .

[75]  Nicholas P. Cheremisinoff,et al.  Handbook of fluids in motion , 1983 .

[76]  André Laurent,et al.  A new, improved pressure drop correlation for trickle-bed reactors , 1988 .

[77]  H. Landeghem Multiphase reactors : mass transfer and modeling , 1980 .

[78]  D. Mears,et al.  The role of axial dispersion in trickle-flow laboratory reactors , 1971 .

[79]  S. T. Sie Scale Effects in Laboratory and Pilot-Plant Reactors for Trickle-Flow Processes , 1991 .

[80]  G. Baldi Heat Transfer in Gas-Liquid-Solid Reactors , 1981 .

[81]  Milorad P. Dudukovic,et al.  Catalyst wetting efficiency in trickle-bed reactors at high pressure , 1995 .

[82]  Klaas R. Westerterp,et al.  The influence of pressure on the liquid hold-up in a cocurrent gas-liquid trickle-bed reactor operating at low gas velocities , 1991 .

[83]  A. Zoulalian,et al.  Study and modelling of catalytic sulfur dioxide oxidation in “verlifix” three phase reactor , 1992 .

[84]  G. Baldi Hydrodynamics of Multiphase Reactors , 1981 .

[85]  Koichi Mabuchi,et al.  Oxidation of ethanol in gas‐liquid cocurrent upflow and downflow reactors , 1984 .

[86]  S. Toyama,et al.  An experimental investigation of minimum fluidization velocity at elevated temperatures and pressures , 1985 .

[87]  Ka Ming Ng,et al.  Experimental study of reaction in trickle-bed reactors with liquid maldistribution , 1993 .

[88]  Gabriel Wild,et al.  A new, improved liquid hold-up correlation for trickle-bed reactors , 1990 .

[89]  Yuanxin Wu,et al.  Reproducible Technique for Packing Laboratory-Scale Trickle-Bed Reactors with a Mixture of Catalyst and Fines , 1995 .

[90]  Ioannis G. Kevrekidis,et al.  Dynamics of pulsing flow in trickle beds , 1990 .

[91]  F. Larachi,et al.  Gas-liquid mass transfer in high pressure trickle-bed reactors: Experiments and modelling , 1996 .

[92]  H. C. Henry,et al.  Scale Up of Pilot Plant Data for Catalytic Hydroprocessing , 1973 .

[93]  M. Orhan Tarhan Catalytic reactor design , 1983 .

[94]  Vito Specchia,et al.  Pressure drop and liquid holdup for two-phase concurrent flow in packed beds , 1977 .

[95]  S. C. Saxena,et al.  The properties of a dolomite bed of a range of particle sizes and shapes at minimum fluidization , 1976 .

[96]  Ka Ming Ng,et al.  A model for flow regime transitions in cocurrent down‐flow trickle‐bed reactors , 1986 .

[97]  J. Smith,et al.  Oxidation of acetic acid solutions in a trickle-bed reactor , 1976 .

[98]  R. Missen,et al.  Trickle‐bed reactors: Tracer study of liquid holdup and wetting efficiency at high temperature and pressure , 1991 .

[99]  F. Larachi,et al.  Pressure effects on gas-liquid interfacial areas in cocurrent trickle-flow reactors , 1992 .

[100]  Rmm Rob Diks,et al.  Verification studies of a simplified model for the removal of dichloromethane from waste gases using a biological trickling filter , 1991 .

[101]  Robert R. Hudgins,et al.  Steady-State models for SO2 oxidation in a trickle-bed reactor , 1990 .

[102]  N. Midoux,et al.  Hydrodynamics and interfacal areas in downward cocurrent gas-iquid flow through fixed beds - Influence of the nature of the liquid. , 1982 .

[103]  Milorad P. Dudukovic,et al.  Evaluation of liquid‐solid contacting in trickle‐bed reactors by tracer methods , 1981 .

[104]  Gabriel Wild,et al.  The Hydrodynamic Characteristics of Cocurrent Downflow and Cocurrent Upflow Gas-Liquid-Solid Catalytic Fixed Bed Reactors: the Effect of Pressure , 1991 .

[105]  Yatish T. Shah,et al.  Gas-liquid-solid reactor design , 1979 .

[106]  K. Onda,et al.  Effect of Packing Materials on the Wetted Surface Area , 1967 .

[107]  Faïçal Larachi,et al.  Some experimental liquid saturation results in fixed-bed reactors operated under elevated pressure in cocurrent upflow and downflow of the gas and the liquid , 1991 .

[108]  J. van Klinken,et al.  Catalyst dilution for improved performance of laboratory trickle-flow reactors , 1980 .

[109]  K. Ng,et al.  A MODEL FOR PULSING FLOW IN COCURRENT DOWN-FLOW TRICKLE-BED REACTORS , 1986 .

[110]  K. Westerterp,et al.  The influence of the reactor pressure on the hydrodynamics in a cocurrent gas-liquid trickle-bed reactor , 1990 .

[111]  Milorad P. Dudukovic,et al.  A new tracer method for determination of liquid‐solid contacting efficiency in trickle‐bed reactors , 1976 .

[112]  A. Gianetto,et al.  Modelling of trickle bed reactors , 1986 .

[113]  Gilbert F. Froment,et al.  Kinetic Modeling and Reactor Simulation in Hydrodesulfurization of Oil Fractions , 1994 .

[114]  M. Duduković,et al.  Comparison of Upflow and Downflow Two-Phase Flow Packed-Bed Reactors with and without Fines: Experimental Observations , 1996 .

[115]  S. Sundaresan Mathematical modeling of pulsing flow in large trickle beds , 1987 .

[116]  R. Lockhart Proposed Correlation of Data for Isothermal Two-Phase, Two-Component Flow in Pipes , 1949 .