Effect of Precatalyst Oxidation State in C–N Cross-Couplings with 2-Phosphinoimidazole-Derived Bimetallic Pd(I) and Pd(II) Complexes

[1]  Stacey J. Smith,et al.  Experiment and Theory of Bimetallic Pd-Catalyzed α-Arylation and Annulation for Naphthalene Synthesis , 2021, ACS Catalysis.

[2]  A. Frontier,et al.  Merging Strategy, Improvisation, and Conversation to Solve Problems in Target Synthesis. , 2021, Accounts of chemical research.

[3]  Hajime Ito,et al.  A Glove-Box- and Schlenk-Line-Free Protocol for Solid-State C–N Cross-Coupling Reactions Using Mechanochemistry , 2020, ACS Sustainable Chemistry & Engineering.

[4]  T. Sperger,et al.  Catalysis with Palladium(I) Dimers , 2020, Angewandte Chemie.

[5]  Stacey J. Smith,et al.  Monosubstituted, Anionic Imidazolyl Ligands from N−H NHC Precursors and Their Activity in Pd‐Catalyzed Cross‐Coupling Reactions , 2020 .

[6]  N. Hazari,et al.  Differences in the Performance of Allyl Based Palladium Precatalysts for Suzuki-Miyaura Reactions. , 2020, Advanced synthesis & catalysis.

[7]  Qiong Gu,et al.  Palladium catalyzed C–C and C–N bond forming reactions: an update on the synthesis of pharmaceuticals from 2015–2020 , 2020 .

[8]  K. H. Shaughnessy.  Development of Palladium Precatalysts that Efficiently Generate LPd(0) Active Species , 2020, Israel Journal of Chemistry.

[9]  J. Hartwig,et al.  Mechanistic Studies of Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides with Carbon Monoxide and Ammonia. , 2018, Journal of the American Chemical Society.

[10]  B. Gupton,et al.  Palladium-Catalyzed C–H Amination of C(sp2) and C(sp3)–H Bonds: Mechanism and Scope for N-Based Molecule Synthesis , 2018 .

[11]  Yuji Koga,et al.  Dinuclear Nickel(I) and Palladium(I) Complexes for Highly Active Transformations of Organic Compounds , 2018, Molecules.

[12]  Thomas J. Colacot,et al.  Understanding the Unusual Reduction Mechanism of Pd(II) to Pd(I): Uncovering Hidden Species and Implications in Catalytic Cross-Coupling Reactions. , 2017, Journal of the American Chemical Society.

[13]  N. Hazari,et al.  Well-defined nickel and palladium precatalysts for cross-coupling. , 2017, Nature reviews. Chemistry.

[14]  R. Mach,et al.  Pd-Catalyzed Synthesis of Piperazine Scaffolds Under Aerobic and Solvent-Free Conditions. , 2016, Organic letters.

[15]  Stephen L. Buchwald,et al.  Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions , 2016, Chemical reviews.

[16]  T. Scattolin,et al.  Air-Stable Dinuclear Iodine-Bridged Pd(I) Complex - Catalyst, Precursor, or Parasite? The Additive Decides. Systematic Nucleophile-Activity Study and Application as Precatalyst in Cross-Coupling , 2015 .

[17]  N. Hazari,et al.  Design of a Versatile and Improved Precatalyst Scaffold for Palladium-Catalyzed Cross-Coupling: (η3-1-tBu-indenyl)2(μ-Cl)2Pd2 , 2015 .

[18]  N. Hazari,et al.  Insight into the efficiency of cinnamyl-supported precatalysts for the Suzuki-Miyaura reaction: observation of Pd(I) dimers with bridging allyl ligands during catalysis. , 2014, Journal of the American Chemical Society.

[19]  S. Buchwald,et al.  Design and Preparation of New Palladium Precatalysts for C-C and C-N Cross-Coupling Reactions. , 2012, Chemical science.

[20]  Fabien Proutière,et al.  Reactivity and stability of dinuclear Pd(I) complexes: studies on the active catalytic species, insights into precatalyst activation and deactivation, and application in highly selective cross-coupling reactions. , 2012, Journal of the American Chemical Society.

[21]  Tetsuro Murahashi,et al.  Oxidative dinuclear addition of a PdI-PdI moiety to arenes: generation of μ-η3:η3-arene-Pd(II)2 species. , 2011, Journal of the American Chemical Society.

[22]  J. Passchier,et al.  Rapid carbonylative coupling reactions using palladium(I) dimers: applications to 11CO-radiolabelling for the synthesis of PET tracers. , 2011, Organic & biomolecular chemistry.

[23]  T. Ritter,et al.  Palladium(III) in Synthesis and Catalysis. , 2011, Topics in organometallic chemistry.

[24]  B. Saha,et al.  Bimetallic catalysis involving dipalladium(I) and diruthenium(I) complexes. , 2010, Chemistry.

[25]  J. Kampf,et al.  Oxidation of a cyclometalated Pd(II) dimer with "CF3+": formation and reactivity of a catalytically competent monomeric Pd(IV) aquo complex. , 2010, Journal of the American Chemical Society.

[26]  J. Steed,et al.  Reduction of a chelating bis(NHC) palladium(II) complex to [{mu-bis(NHC)}2Pd2H]+: a terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions. , 2010, Angewandte Chemie.

[27]  Johannes E. M. N. Klein,et al.  Bimetallic palladium catalysis: direct observation of Pd(III)-Pd(III) intermediates. , 2009, Journal of the American Chemical Society.

[28]  M. Sanford,et al.  Synthetic and mechanistic studies of Pd-catalyzed C-H arylation with diaryliodonium salts: evidence for a bimetallic high oxidation state Pd intermediate. , 2009, Journal of the American Chemical Society.

[29]  T. Ritter,et al.  Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation. , 2009, Nature chemistry.

[30]  P. Lahuerta,et al.  Multifaceted palladium catalysts towards the tandem diboration-arylation reactions of alkenes. , 2008, Chemistry.

[31]  J. Hartwig,et al.  Alpha-arylation of esters catalyzed by the Pd(I) dimer {[P(t-Bu)3]PdBr}2. , 2008, Organic letters.

[32]  T. Hor,et al.  Suzuki coupling catalyzed by a homoleptic Pd(I)-Pd(I) solvento complex , 2007 .

[33]  S. Buchwald,et al.  A palladium-catalyzed regiospecific synthesis of N-aryl benzimidazoles. , 2007, Angewandte Chemie.

[34]  M. Neuburger,et al.  Palladium-catalyzed allylic substitution: reversible formation of allyl-bridged dinuclear palladium(I) complexes. , 2007, Angewandte Chemie.

[35]  R. Finke,et al.  Is it homogeneous Pt(II) or heterogeneous Pt(0)n catalysis? Evidence that Pt(1,5-COD)Cl2 and Pt(1,5-COD)(CH3)2 plus H2 form heterogeneous, nanocluster plus bulk-metal Pt(0) hydrogenation catalysts , 2006 .

[36]  Christopher W. Jones,et al.  On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review , 2006 .

[37]  Timothy E. Barder.  Synthesis, structural, and electron topographical analyses of a dialkylbiaryl phosphine/arene-ligated palladium(I) dimer: enhanced reactivity in Suzuki-Miyaura coupling reactions. , 2006, Journal of the American Chemical Society.

[38]  S. Buchwald,et al.  Efficient pd-catalyzed amination of heteroaryl halides. , 2005, Organic letters.

[39]  M. Sanford,et al.  Palladium-catalyzed oxygenation of unactivated sp3 C-H bonds. , 2004, Journal of the American Chemical Society.

[40]  L. Shimon,et al.  Unsaturated Pd(0), Pd(I), and Pd(II) complexes of a new methoxy-substituted benzyl phosphine. Aryl-X (X = Cl, I) oxidative addition, C-O cleavage, and Suzuki-Miyaura coupling of aryl chlorides , 2004 .

[41]  J. Hartwig,et al.  Reductive elimination of aryl halides upon addition of hindered alkylphosphines to dimeric arylpalladium(II) halide complexes , 2004 .

[42]  J. Hartwig,et al.  Unparalleled rates for the activation of aryl chlorides and bromides: coupling with amines and boronic acids in minutes at room temperature. , 2002, Angewandte Chemie.

[43]  D. Mingos,et al.  Synthesis and structural characterisation of [Pd2(µ-Br)2(PBut3)2], an example of a palladium(I)–palladium(I) dimer , 1996 .

[44]  J. Hartwig,et al.  Structural Characterization and Simple Synthesis of {Pd[P(o-Tol)3]2}. Spectroscopic Study and Structural Characterization of the Dimeric Palladium(II) Complexes Obtained by Oxidative Addition of Aryl Bromides and Their Reactivity with Amines , 1995 .