Asymmetric hydrogenation of α- and β-enamido phosphonates: rhodium(I)/monodentate phosphoramidite catalyst.

A Rh—monodentate phosphoramidite complex efficiently catalyzes the asymmetric hydrogenation of α-enamido phosphonates (I), (III), (V) and (VII) to give the corresponding α-aminophosphonates in excellent enantioselectivities (88 up to <99% e.e.).

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