Effect of hydrogen on the superplasticity of Ti40 alloy with large grains

Abstract Thermohydrogen processing (THP) is an attractive approach which uses hydrogen as a temporary element in titanium alloys to modify the microstructure/mechanical properties and workability. In this article, the influence of hydrogen on the superplasticity of single β phase Ti40 (Ti–25V–15Cr–0.2Si) alloy with hydrogenation had been investigated in the temperature range of 840–920 °C and strain rate of 5 × 10 −4 –1 × 10 −2  s −1 . The maximum elongation of 478% was obtained at 920 °C, 5 × 10 −4  s −1 with 0.3 wt.% H. A significant refinement of average grain size in Ti40– x H alloys during superplastic deformation was found and the grain sizes became much finer with the increase of hydrogen content. The superplastic deformation mechanism of Ti40– x H alloy with large grains could be explained by dynamic recovery and recrystallization.

[1]  Francis H. Froes,et al.  Thermohydrogen processing of titanium alloys , 1999 .

[2]  H. Hou,et al.  Low Temperature Superplasticity of Titanium Alloy Processed by Thermohydrogen Treatment , 2007 .

[3]  Bin Guo,et al.  The effect of hydrogen on the strengthening and softening of Ti–6Al–4V alloy , 2008 .

[4]  R. Boyer An overview on the use of titanium in the aerospace industry , 1996 .

[5]  H. Yoshimura,et al.  Ultra-fine-grain refinement and superplasticity of titanium alloys obtained through protium treatment , 2002 .

[6]  Qiang Zhou,et al.  Crystallographic and magnetic properties of Nd1+xFe10Mo2Ny , 1995 .

[7]  C. Hammond,et al.  Superplastic deformation properties of β-Ti alloys , 1987 .

[8]  D. Shan,et al.  Precipitation behavior and microstructural characteristics of hydrogenated β-Ti40 alloys , 2009 .

[9]  N. D. Reca,et al.  Autodifusion de titanio beta y hafnio beta , 1968 .

[10]  F. Sun,et al.  Superplastic phenomenon in a large-grained TiAl alloy , 2001 .

[11]  J. Jonas,et al.  Effect of phase composition and hydrogen level on the deformation behavior of titanium-hydrogen alloys , 1996 .

[12]  R. Ji,et al.  The microstructural modification, lattice defects and mechanical properties of hydrogenated/dehydrogenated α-Ti , 1996 .

[13]  J. Jonas,et al.  Elastic moduli of titanium-hydrogen alloys in the temperature range 20 °C to 1100 °C , 1996 .

[14]  Zhang Shaoqing,et al.  Effect of hydrogen on the superplasticity and microstructure of Ti-6Al-4V alloy , 1995 .

[15]  D. Jiang,et al.  Superplasticity of single-phase Ni–45Al intermetallics with large grains , 2002 .

[16]  S. H. Zhang,et al.  Hydrogen-induced hardening and softening of a β-titanium alloy , 2009 .

[17]  Hao Zhang,et al.  The effect of hydrogen on the strength and superplastic deformation of beta-titanium alloys , 1996 .

[18]  Stan R. Seagle,et al.  The state of the USA titanium industry in 1995 , 1996 .

[19]  V. Gavriljuk,et al.  Mechanism of hydrogen-induced phase transformations in metals and alloys , 1997 .

[20]  F. Froes,et al.  Hydrogen as a temporary alloying element in titanium alloys: thermohydrogen processing , 2004 .