(Acetonitrile-κN)aqua[N,N′-bis(pyridin-2-ylmethyl)ethane-1,2-diamine-κ4 N,N′,N′′,N′′′]zinc(II) perchlorate

The structure of acetonitrileaqua[1,2-bis(pyridin-2-ylmethyl)ethane-1,2-diamine]zinc(II) perchlorate contains a six-coordinate cation consisting of the tetradentate bispicen ligand, coordinated water, and coordinated acetonitrile with the latter two ligands adopting a cis configuration.

[1]  I. Bruno,et al.  Cambridge Structural Database , 2002 .

[2]  G. Sheldrick SHELXT – Integrated space-group and crystal-structure determination , 2015, Acta crystallographica. Section A, Foundations and advances.

[3]  G. Sheldrick Crystal structure refinement with SHELXL , 2015, Acta crystallographica. Section C, Structural chemistry.

[4]  K. Theopold,et al.  C-H bond activations by metal oxo compounds. , 2010, Chemical reviews.

[5]  M. White,et al.  Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation , 2010, Science.

[6]  G. Britovsek,et al.  Ligand topology variations and the importance of ligand field strength in non-heme iron catalyzed oxidations of alkanes. , 2007, Inorganic chemistry.

[7]  L. Que,et al.  Ligand topology effects on olefin oxidations by bio-inspired [FeII(N2Py2)] catalysts. , 2006, Chemistry.

[8]  G. Brudvig,et al.  Molecular Recognition in the Selective Oxygenation of Saturated C-H Bonds by a Dimanganese Catalyst , 2006, Science.

[9]  E. Rivière,et al.  Synthesis, Structure and Characterisation of a New Trinuclear Di‐μ‐phenolato‐μ‐carboxylato MnIIIMnIIMnIII Complex with a Bulky Pentadentate Ligand: Chemical Access to Mononuclear MnIV–OH Entities , 2005 .

[10]  C. Philouze,et al.  Synthesis, structure, and characterization of new mononuclear Mn(II) complexes. Electrochemical conversion into new oxo-bridged Mn(2)(III,IV) complexes. Role of chloride ions. , 2005, Inorganic chemistry.

[11]  L. Que,et al.  Olefin cis-dihydroxylation versus epoxidation by non-heme iron catalysts: two faces of an Fe(III)-OOH coin. , 2002, Journal of the American Chemical Society.

[12]  R. Butcher,et al.  Syntheses and structures of and catalysis of hydrolysis by Zn(II) complexes of chelating pyridyl donor ligands , 1999 .

[13]  R. Butcher,et al.  Synthesis, reactions and structure of a hydroxo-bridged dinuclear Zn(II) complex: modeling the hydrolytic zinc enzymes , 1996 .

[14]  D. Hodgson,et al.  Syntheses and characterization of binuclear manganese(III,IV) and -(IV,IV) complexes with ligands related to N,N'-bis(2-pyridylmethyl)-1,2-ethanediamine , 1991 .

[15]  Wei Zhang,et al.  Highly enantioselective epoxidation catalysts derived from 1,2-diaminocyclohexane , 1991 .

[16]  E. Pedersen,et al.  Binuclear bis(.mu.-oxo)dimanganese(III,IV) and -(IV,IV) complexes with N,N'-bis(2-pyridylmethyl)-1,2-ethanediamine , 1990 .

[17]  J. Donnelly Saint , 2018, Encyclopedia of Early Modern History Online.

[18]  E. Baran,et al.  Synthesis and Characterization of a Zinc(II) Complex of Bispicen , 2013 .

[19]  G. Sheldrick A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.