Hydrothermal Pretreatment: Process Modeling and Economic Assessment Within the Framework of Biorefinery Processes

Techno-economic evaluation of processes based on hydrothermal pretreatment is needed to set the current status and to identify processing bottlenecks that need to be addressed to make these processes viable. Having suitable models to carry simulations is a prerequisite for conducting such evaluations. The goal of this chapter is to discuss different approaches that can be used to model and simulate hydrothermal pretreatment processes using commercial process simulators. A discussion on possible flowsheets, as well as different ways to model biomass and chemical reactions, is presented. Rather than simply listing the different possibilities, the focus is on the rationale behind the selection of unit operations and models and the consequences each selection has. A brief discussion on possible improvements to be made to the current state-of-the-art models is also presented. Toward the end, the chapter provides a review of different criteria and usual assumptions that are made to calculate costs of biorefinery processes, and a summary of these costs for those flowsheets has analyzed inclusion of hydrothermal pretreatment.

[1]  A. Contin,et al.  Complementare/Lezione 2/Top Value-Added Chemicals from Biomass, Volume II: Results of Screening for Potential, Candidates from Biorefinery Lignin, PNNL-16983 (2007) , 2012 .

[2]  S. Ramakrishnan,et al.  Chemical and Physicochemical Pretreatment of Lignocellulosic Biomass: A Review , 2011, Enzyme research.

[3]  Savita Kaul,et al.  Fuels and Chemicals from Lignocellulosic Biomass: An Integrated Biorefinery Approach , 2015 .

[4]  P. Daoutidis,et al.  Process synthesis of biorefineries: Optimization of biomass conversion to fuels and chemicals , 2014 .

[5]  R. Elander,et al.  Process and economic analysis of pretreatment technologies. , 2005, Bioresource technology.

[6]  Christos T. Maravelias,et al.  Catalytic conversion of lignocellulosic biomass to fuels: Process development and technoeconomic evaluation , 2012 .

[7]  M. Cardoso,et al.  Bioenergy II: Furfural Destruction Kinetics during Sulphuric Acid-Catalyzed Production from Biomass , 2009 .

[8]  Fengqi You,et al.  Global optimization for sustainable design and synthesis of algae processing network for CO2 mitigation and biofuel production using life cycle optimization , 2014 .

[9]  Gavin Towler,et al.  Chemical engineering design : principles, practice, and economics of plant and process design , 2008 .

[10]  Hasan Jameel,et al.  Converting Eucalyptus biomass into ethanol: Financial and sensitivity analysis in a co-current dilute acid process. Part II , 2011 .

[11]  Nilay Shah,et al.  Multiscale modelling of biomass pretreatment for biofuels production , 2009 .

[12]  Eric C. D. Tan,et al.  Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons: Dilute-Acid and Enzymatic Deconstruction of Biomass to Sugars and Biological Conversion of Sugars to Hydrocarbons , 2013 .

[13]  Mahmoud M. El-Halwagi,et al.  A comparison of pretreatment methods for bioethanol production from lignocellulosic materials , 2012 .

[14]  James M. Douglas,et al.  Conceptual Design of Chemical Processes , 1988 .

[15]  M. Delwiche,et al.  Methods for Pretreatment of Lignocellulosic Biomass for Efficient Hydrolysis and Biofuel Production , 2009 .

[16]  Charles E Wyman,et al.  The impact of dilute sulfuric acid on the selectivity of xylooligomer depolymerization to monomers. , 2008, Carbohydrate research.

[17]  C. Cardona,et al.  Process Simulation of Fuel Ethanol Production from Lignocellulosics using Aspen Plus , 2011 .

[18]  J. R. Hess,et al.  Process Design and Economics for Conversion of Lignocellulosic Biomass to Ethanol , 2011 .

[19]  Kelly N. Ibsen,et al.  Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis for Corn Stover , 2002 .

[20]  Rudolf Toman,et al.  Polysaccharides from the bark of the white willow (salix alba L.): structure of a galactan , 1972 .

[21]  Steven R. Thomas,et al.  Process and technoeconomic analysis of leading pretreatment technologies for lignocellulosic ethanol production using switchgrass. , 2011, Bioresource technology.

[22]  Zhenhong Yuan,et al.  Kinetic study of hydrolysis of xylan and agricultural wastes with hot liquid water. , 2009, Biotechnology advances.

[23]  Jürgen Puls,et al.  Chemistry and biochemistry of hemicelluloses: Relationship between hemicellulose structure and enzymes required for hydrolysis , 1997 .

[24]  J. Riley,et al.  Preliminary estimate of the cost of ethanol production for ssf technology , 1992 .

[25]  G. Murthy,et al.  Impact of pretreatment and downstream processing technologies on economics and energy in cellulosic ethanol production , 2011, Biotechnology for biofuels.

[26]  Stephen R. Decker,et al.  Hydrolysis of Cellulose and Hemicellulose , 2004 .

[27]  Akshay D. Patel,et al.  Techno-economic analysis of 5-nonanone production from levulinic acid. , 2010 .

[28]  David R Shonnard,et al.  Kinetic characterization for dilute sulfuric acid hydrolysis of timber varieties and switchgrass. , 2008, Bioresource technology.

[29]  George Stephanopoulos,et al.  A Novel Approach for the Identification of Economic Opportunities within the Framework of a Biorefinery , 2015 .

[30]  Jerome F. Saeman,et al.  Kinetics of Wood Saccharification - Hydrolysis of Cellulose and Decomposition of Sugars in Dilute Acid at High Temperature , 1945 .

[31]  V. Putsche,et al.  Development of an ASPEN PLUS physical property database for biofuels components , 1996 .

[32]  George Stephanopoulos,et al.  Optimization of Lignocellulosic Waste Biorefinery using Multi-Actor Multi-Objective Mathematical Framework , 2016 .

[33]  Adriano V. Ensinas,et al.  A New Proposal of Cellulosic Ethanol to Boost Sugarcane Biorefineries: Techno-Economic Evaluation , 2014 .

[34]  C. Wyman,et al.  Pretreatment: the key to unlocking low‐cost cellulosic ethanol , 2008 .

[35]  Julián A. Quintero,et al.  Fuel ethanol production from sugarcane and corn: Comparative analysis for a Colombian case , 2008 .

[36]  D. L. Williams,et al.  Kinetics of Furfural Destruction in Acidic Aqueous Media , 1948 .

[37]  Christiane Laine,et al.  Structures of hemicelluloses and pectins in wood and pulp , 2005 .

[38]  Gürkan Sin,et al.  Dynamic modeling and validation of a biomass hydrothermal pretreatment process—a demonstration scale study , 2015 .

[39]  J. Parajó,et al.  Hydrothermal processing of lignocellulosic materials , 1999, Holz als Roh- und Werkstoff.

[40]  George Stephanopoulos,et al.  Evaluation of the production of lipids for fuels and proteins from microalgae by decomposition of the processing network , 2016 .

[41]  M. Soledad Diaz,et al.  Dynamic Modeling and Parameter Estimation for Unit Operations in Lignocellulosic Bioethanol Production , 2013 .

[42]  George Stephanopoulos,et al.  Design of multi‐actor distributed processing systems: A game‐theoretical approach , 2016 .

[43]  Christos T. Maravelias,et al.  An optimization-based assessment framework for biomass-to-fuel conversion strategies , 2013 .

[44]  David K. Johnson,et al.  Top Value-Added Chemicals from Biomass - Volume II—Results of Screening for Potential Candidates from Biorefinery Lignin , 2007 .

[45]  Klaus D. Timmerhaus,et al.  Plant design and economics for chemical engineers , 1958 .

[46]  Nilay Shah,et al.  Multiscale modelling of hydrothermal biomass pretreatment for chip size optimization. , 2009, Bioresource technology.

[47]  Andrew G. Hashimoto,et al.  Modeling and optimization of the dilute-sulfuric-acid pretreatment of corn stover, poplar and switchgrass , 1997 .

[48]  Rubens Maciel Filho,et al.  Integrated versus stand-alone second generation ethanol production from sugarcane bagasse and trash. , 2012, Bioresource technology.