Epitaxy as a Growth Factor in Urinary Calculi and Gallstones
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EPITAXY1 consists of the growth of one crystal, in one or more particular orientations, on a substrate of another, with a near geometrical fit between the respective networks which are in contact. Thus anthraquinone can grow on rocksalt2 and d- or l-camphor on d- or l-quartz3. That there is some influence of the structures themselves (apart from the geometry) has been proved, but it is of surprisingly minor importance3. There is also a dependence of the degree of misfit which can be tolerated on the degree of supersaturation of the solution from which the epitaxial crystals are deposited4.
[1] A. Rains. Gallstones: Causes and Treatment , 1965 .
[2] J. A. Carr. THE PATHOLOGY OF URINARY CALCULI: RADIAL STRIATION1 , 1953 .
[3] K. Juniper,et al. Biliary tract studies. I. X-ray diffraction analysis of gallstones; correlation with occurrence of microspheroliths in bile. , 1956, The American journal of medicine.
[4] D. Turnbull,et al. Nucleation of Ammonium Iodide Crystals from Aqueous Solutions , 1955 .