Particulate and trace gas emissions from prescribed burns in southeastern U.S. fuel types: Summary of a 5-year project

Management of smoke from prescribed fires requires knowledge of fuel quantity and the amount and composition of the smoke produced by the fire to minimize adverse impacts on human health. A five-year study produced new emissions information for more than 100 trace gases and particulate matter in smoke for fuel types found in the southern United States of America using state-of-the-art instrumentation in both laboratory and field experiments. Emission factors for flaming, smoldering, and residual smoldering were developed. Agreement between laboratory and field-derived emission factors was generally good in most cases. Reference spectra of over 50 wildland fire gas-phase smoke components were added to a publicly-available database to support identification via infrared spectroscopy. Fuel loading for the field experiments was similar to previously measured fuels. This article summarizes the results of a five-year study to better understand the composition of smoke during all phases of burning for such forests.

[1]  T. Johnson,et al.  Gas-Phase Databases for Quantitative Infrared Spectroscopy , 2004, Applied spectroscopy.

[2]  J. Landers,et al.  The longleaf pine forests of the southeast: requiem or renaissance? , 1995 .

[3]  M. Andreae,et al.  Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols , 2006 .

[4]  J. Levine,et al.  Biomass Burning: A Driver for Global Change! , 1995 .

[5]  M. Andreae,et al.  Emission of trace gases and aerosols from biomass burning , 2001 .

[6]  C. McMahon,et al.  Polynuclear aromatic hydrocarbons in forest fire smoke , 1978 .

[7]  T. Johnson,et al.  Quantitative infrared absorption cross sections of isoprene for atmospheric measurements , 2014 .

[8]  Luisa T. M. Profeta,et al.  Case study of water-soluble metal containing organic constituents of biomass burning aerosol. , 2011, Environmental science & technology.

[9]  S. K. Akagi,et al.  Measurements of reactive trace gases and variable O3 formation rates in some South Carolina biomass burning plumes , 2012 .

[10]  W. Hao,et al.  Emissions of formaldehyde, acetic acid, methanol, and other trace gases from biomass fires in North Carolina measured by airborne Fourier transform infrared spectroscopy , 1999 .

[11]  D. Griffith,et al.  Open-path Fourier transform infrared studies of large-scale laboratory biomass fires , 1996 .

[12]  Michael E. Chang,et al.  Simulation of air quality impacts from prescribed fires on an urban area. , 2008, Environmental science & technology.

[13]  R. H. Groves,et al.  Fire and the Australian biota , 1981 .

[14]  F. Albini,et al.  Predicting fire behavior in palmetto-gallberry fuel complexes , 1978 .

[15]  Ana Isabel Miranda,et al.  Chapter 3 Characterizing Sources of Emissions from Wildland Fires , 2008 .

[16]  Timothy J. Johnson,et al.  Field measurements of trace gases emitted by prescribed fires in southeastern US pine forests using an open-path FTIR system , 2013 .

[17]  D. Griffith Synthetic Calibration and Quantitative Analysis of Gas-Phase FT-IR Spectra , 1996 .

[18]  Thomas A Blake,et al.  Absolute integrated intensities of vapor-phase hydrogen peroxide (H2O2) in the mid-infrared at atmospheric pressure , 2009, Analytical and bioanalytical chemistry.

[19]  G. W. Wendel,et al.  Forest Fuels on Organic and Associated Soils in the Coastal Plain of North Carolina , 2017 .

[20]  Scott L. Goodrick,et al.  Introduction to prescribed fires in Southern ecosystems , 2012 .

[21]  Timothy J. Johnson,et al.  An infrared spectral database for detection of gases emitted by biomass burning , 2010 .

[22]  Timothy J. Johnson,et al.  Quantitative infrared intensity studies of vapor-phase glyoxal, methylglyoxal, and 2,3-butanedione (diacetyl) with vibrational assignments. , 2011, The journal of physical chemistry. A.

[23]  I. R. Burling,et al.  Quantitative IR spectrum and vibrational assignments for glycolaldehyde vapor: glycolaldehyde measurements in biomass burning plumes. , 2013, The journal of physical chemistry. A.

[24]  E. L. Little Atlas of United States trees. , 1971 .

[25]  Yongqiang Liu,et al.  Wildland fire emissions, carbon, and climate: Plume rise, atmospheric transport, and chemistry processes , 2014 .

[26]  John U. White Long Optical Paths of Large Aperture , 1942 .

[27]  I. R. Burling,et al.  Laboratory measurements of trace gas emissions from biomass burning of fuel types from the southeastern and southwestern United States , 2010 .

[28]  Frank Heyward,et al.  The Relation of Fire to Stand Composition of Longleaf Pine Forests , 1939 .

[29]  Carolyn S. Brauer,et al.  Quantitative vapor-phase IR intensities and DFT computations to predict absolute IR spectra based on molecular structure: I. Alkanes , 2013 .

[30]  R. W. Johansen Ignition patterns & prescribed fire behavior in southern pine stands , 1987 .

[31]  Rachel A. Loehman,et al.  Wildland fire emissions, carbon, and climate: Seeing the forest and the trees – A cross-scale assessment of wildfire and carbon dynamics in fire-prone, forested ecosystems , 2014 .

[32]  I. R. Burling,et al.  Measurement of HONO, HNCO, and other inorganic acids by negative-ion proton-transfer chemical-ionization mass spectrometry (NI-PT-CIMS): application to biomass burning emissions , 2010 .

[33]  D. Griffith,et al.  Emissions from smoldering combustion of biomass measured by open‐path Fourier transform infrared spectroscopy , 1997 .

[34]  Cynthia Fowler,et al.  Human Health Impacts of Forest Fires in the Southern United States: A Literature Review , 2003 .

[35]  D. Wade,et al.  Combustion characteristics and emissions from burning organic soils , 1980 .

[36]  S. K. Akagi,et al.  Aerosol emissions from prescribed fires in the United States: A synthesis of laboratory and aircraft measurements , 2014 .

[37]  G. Achtemeier On the formation and persistence of superfog in woodland smoke , 2009 .

[38]  C. Rodríguez,et al.  Potential health impacts associated with peat smoke: a review , 2005 .

[39]  Robert S. Seymour,et al.  Maintaining Biodiversity in Forest Ecosystems: Principles of ecological forestry , 1999 .

[40]  I. R. Burling,et al.  Measurements of gas‐phase inorganic and organic acids from biomass fires by negative‐ion proton‐transfer chemical‐ionization mass spectrometry , 2010 .

[41]  D. Loftsgaarden,et al.  Evaluation of fire danger rating indexes using logistic regression and percentile analysis , 2003 .

[42]  Jesse K. Kreye,et al.  Effects of fuel load and moisture content on fire behaviour and heating in masticated litter-dominated fuels , 2013 .

[43]  Darold E. Ward,et al.  An Analysis of the Air Force Bomb Range Fire , 1973 .

[44]  S. K. Akagi,et al.  Coupling field and laboratory measurements to estimate the emission factors of identified and unidentified trace gases for prescribed fires , 2012 .

[45]  D. Byun,et al.  Review of the Governing Equations, Computational Algorithms, and Other Components of the Models-3 Community Multiscale Air Quality (CMAQ) Modeling System , 2006 .

[46]  Robert J. Yokelson,et al.  VOC identification and inter-comparison from laboratory biomass burning using PTR-MS and PIT-MS , 2011 .

[47]  E. Marino,et al.  Assessing fire propagation empirical models in shrub fuel complexes using wind tunnel data. , 2008 .

[48]  S. K. Akagi,et al.  Emission factors for open and domestic biomass burning for use in atmospheric models , 2010 .

[49]  Stephen S. Sackett,et al.  Scheduling Prescribed Burns for Hazard Reduction in the Southeast , 1975 .

[50]  I. R. Burling,et al.  Isocyanic acid in the atmosphere and its possible link to smoke-related health effects , 2011, Proceedings of the National Academy of Sciences.

[51]  R. Loehman,et al.  Wildland fire emissions, carbon, and climate: Science overview and knowledge needs , 2014 .

[52]  R. W. Johansen Prescribed burning with spot fires in the Georgia Coastal Plain , 1984 .

[53]  Patrick R. Zimmerman,et al.  Natural volatile organic compound emission rate estimates for U.S. woodland landscapes , 1994 .

[54]  C. Merril,et al.  Changes in gene expression accompanying chemically-induced malignant transformation of human fibroblasts. , 1982, Carcinogenesis.

[55]  S. K. Akagi,et al.  The Fire INventory from NCAR (FINN): a high resolution global model to estimate the emissions from open burning , 2010 .

[56]  W. H. Blackmarr,et al.  Seasonal and diurnal variation in moisture content of six species of pocosin shrubs , 1968 .

[57]  Gary L. Achtemeier,et al.  Fuels and fire behavior in chipped and unchipped plots: Implications for land management near the wildland/urban interface , 2006 .

[58]  Hugh E. Mobley Southern Forestry Smoke Management Guidebook , 1976 .

[59]  J. Randerson,et al.  Analysis of daily, monthly, and annual burned area using the fourth‐generation global fire emissions database (GFED4) , 2013 .

[60]  Carl W. Adkins,et al.  Flame characteristics of wind-driven surface fires , 1986 .

[61]  I. R. Burling,et al.  Development and validation of a portable gas phase standard generation and calibration system for volatile organic compounds , 2010 .

[62]  P. Crutzen,et al.  Biomass Burning in the Tropics: Impact on Atmospheric Chemistry and Biogeochemical Cycles , 1990, Science.

[63]  Thomas A Blake,et al.  Removing aperture-induced artifacts from Fourier transform infrared intensity values. , 2002, Applied optics.

[64]  David R. Weise,et al.  Evolution of trace gases and particles emitted by a chaparral fire in California , 2011 .

[65]  D. Ward Combustion Chemistry and Smoke , 2001 .

[66]  Brian K Gullett,et al.  Emission factors from aerial and ground measurements of field and laboratory forest burns in the southeastern US: PM2.5, black and brown carbon, VOC, and PCDD/PCDF. , 2013, Environmental science & technology.

[67]  S. K. Akagi,et al.  Airborne and ground-based measurements of the trace gases and particles emitted by prescribed fires in the United States , 2011 .

[68]  Wildland–urban interface fire behaviour and fire modelling in live fuels , 2010 .

[69]  P. Crutzen,et al.  Estimates of gross and net fluxes of carbon between the biosphere and the atmosphere from biomass burning , 1980 .

[70]  P. Bernath,et al.  Detection of elevated tropospheric hydrogen peroxide (H2O2) mixing ratios in atmospheric chemistry experiment (ACE) subtropical infrared solar occultation spectra , 2007 .

[71]  R. Ottmar,et al.  Baseline Measurements of Smoke Exposure Among Wildland Firefighters , 2004, Journal of occupational and environmental hygiene.

[72]  M. Carraway,et al.  Peat Bog Wildfire Smoke Exposure in Rural North Carolina Is Associated with Cardiopulmonary Emergency Department Visits Assessed through Syndromic Surveillance , 2011, Environmental health perspectives.

[73]  I. R. Burling,et al.  Laboratory characterization of PM emissions from combustion of wildland biomass fuels , 2013 .

[74]  Particulate Matter Emissions for Fires in the Palmetto-Gallberry Fuel Type , 1983 .