Metal Nanoparticle-Catalyzed Hydrogen Generation from Liquid Chemical Hydrides

To address the global energy crisis, it is imperative to develop effective, renewable and clean energy carriers. As one of the most promising candidates, hydrogen has a high energy density and is e...

[1]  J. Fierro,et al.  Hydrogen production reactions from carbon feedstocks: fossil fuels and biomass. , 2007, Chemical reviews.

[2]  N. Panwar,et al.  Role of renewable energy sources in environmental protection: A review , 2011 .

[3]  Tao Zhang,et al.  A novel catalyst for hydrazine decomposition: molybdenum carbide supported on γ-Al2O3 , 2002 .

[4]  Qiang Xu,et al.  Nanomaterials derived from metal–organic frameworks , 2018 .

[5]  Tao Zhang,et al.  Catalytic Performance of Activated Carbon Supported Tungsten Carbide for Hydrazine Decomposition , 2008 .

[6]  Manos Mavrikakis,et al.  Ru-Pt core-shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen. , 2008, Nature materials.

[7]  Xin-bo Zhang,et al.  Hollow Ni-SiO2 nanosphere-catalyzed hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage , 2009 .

[8]  Tao Zhang,et al.  A novel approach for CO-free H2 production via catalytic decomposition of hydrazine , 2005 .

[9]  Y. Yamauchi,et al.  Synthesis of Bimetallic Au@Pt Nanoparticles with Au Core and Nanostructured Pt Shell toward Highly Active Electrocatalysts , 2010 .

[10]  A. Singh,et al.  Highly-dispersed surfactant-free bimetallic Ni–Pt nanoparticles as high-performance catalyst for hydrogen generation from hydrous hydrazine , 2014 .

[11]  A. Singh,et al.  Metal–Organic Framework Supported Bimetallic NiPt Nanoparticles as High‐performance Catalysts for Hydrogen Generation from Hydrazine in Aqueous Solution , 2013 .

[12]  Qiang Xu,et al.  Liquid-phase chemical hydrogen storage materials , 2012 .

[13]  Qiang Xu,et al.  Iron-nanoparticle-catalyzed hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage. , 2008, Angewandte Chemie.

[14]  Xin-bo Zhang,et al.  Room temperature hydrolytic dehydrogenation of ammonia borane catalyzed by Co nanoparticles , 2010 .

[15]  Qiang Xu,et al.  Monodispersed CuCo Nanoparticles Supported on Diamine‐Functionalized Graphene as a Non‐noble Metal Catalyst for Hydrolytic Dehydrogenation of Ammonia Borane , 2016 .

[16]  Shouheng Sun,et al.  Monodisperse AgPd alloy nanoparticles and their superior catalysis for the dehydrogenation of formic acid. , 2013, Angewandte Chemie.

[17]  R. Johnston,et al.  Nanoalloys: from theory to applications of alloy clusters and nanoparticles. , 2008, Chemical reviews.

[18]  Qiang Xu,et al.  Diamine-Alkalized Reduced Graphene Oxide: Immobilization of Sub-2 nm Palladium Nanoparticles and Optimization of Catalytic Activity for Dehydrogenation of Formic Acid , 2015 .

[19]  Qiang Xu,et al.  A high-performance hydrogen generation system: Transition metal-catalyzed dissociation and hydrolysis of ammonia-borane , 2006 .

[20]  T. Akita,et al.  Synergistic catalysis of Au@Ag core-shell nanoparticles stabilized on metal-organic framework. , 2011, Journal of the American Chemical Society.

[21]  Xin-bo Zhang,et al.  Co–SiO2 nanosphere-catalyzed hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage , 2010 .

[22]  Xin-bo Zhang,et al.  Magnetically recyclable Fe-Ni alloy catalyzed dehydrogenation of ammonia borane in aqueous solution under ambient atmosphere , 2009 .

[23]  Xin-bo Zhang,et al.  Liquid-phase chemical hydrogen storage: catalytic hydrogen generation under ambient conditions. , 2010, ChemSusChem.

[24]  Xin-bo Zhang,et al.  Synthesis of longtime water/air-stable ni nanoparticles and their high catalytic activity for hydrolysis of ammonia-borane for hydrogen generation. , 2009, Inorganic chemistry.

[25]  Y. Yamauchi,et al.  Strategic Synthesis of Trimetallic Au@Pd@Pt Core−Shell Nanoparticles from Poly(vinylpyrrolidone)-Based Aqueous Solution toward Highly Active Electrocatalysts , 2011 .

[26]  Qiang Xu,et al.  Metal Nanoparticles Immobilized on Carbon Nanodots as Highly Active Catalysts for Hydrogen Generation from Hydrazine in Aqueous Solution , 2015 .

[27]  Ning Li,et al.  Catalytic Decomposition of Hydrazine on Iron Nitride Catalysts in Microreactor , 2004 .

[28]  T. Veziroglu,et al.  The properties of hydrogen as fuel tomorrow in sustainable energy system for a cleaner planet , 2005 .

[29]  O. Terasaki,et al.  Shape- and size-controlled synthesis in hard templates: sophisticated chemical reduction for mesoporous monocrystalline platinum nanoparticles. , 2011, Journal of the American Chemical Society.

[30]  Qiang Xu,et al.  Tandem Nitrogen Functionalization of Porous Carbon: Toward Immobilizing Highly Active Palladium Nanoclusters for Dehydrogenation of Formic Acid , 2017 .

[31]  R. Ludwig,et al.  Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst , 2011, Science.

[32]  P. Ramachandran,et al.  Preparation of ammonia borane in high yield and purity, methanolysis, and regeneration. , 2007, Inorganic chemistry.

[33]  Qiang Xu,et al.  Highly dispersed surfactant-free nickel nanoparticles and their remarkable catalytic activity in the hydrolysis of ammonia borane for hydrogen generation. , 2012, Angewandte Chemie.

[34]  M. Yin,et al.  Novel PdAu@Au/C Core-Shell Catalyst: Superior Activity and Selectivity in Formic Acid Decomposition for Hydrogen Generation , 2010 .

[35]  Qiang Xu,et al.  Immobilizing Extremely Catalytically Active Palladium Nanoparticles to Carbon Nanospheres: A Weakly-Capping Growth Approach. , 2015, Journal of the American Chemical Society.

[36]  Ashutosh Kumar Singh,et al.  Dendrimer‐Encapsulated Bimetallic Pt‐Ni Nanoparticles as Highly Efficient Catalysts for Hydrogen Generation from Chemical Hydrogen Storage Materials , 2013 .

[37]  Qiang Xu,et al.  High Catalytic Performance of MIL-101-Immobilized NiRu Alloy Nanoparticles towards the Hydrolytic Dehydrogenation of Ammonia Borane , 2016 .

[38]  M. Beller,et al.  Catalytic Generation of Hydrogen from Formic acid and its Derivatives: Useful Hydrogen Storage Materials , 2010 .

[39]  Qiang Xu,et al.  Catalytic hydrolysis of ammonia borane for chemical hydrogen storage , 2011 .

[40]  Qiang Xu,et al.  Nickel-palladium nanoparticle catalyzed hydrogen generation from hydrous hydrazine for chemical hydr , 2011 .

[41]  Qiang Xu,et al.  Quasi-MOF: Exposing Inorganic Nodes to Guest Metal Nanoparticles for Drastically Enhanced Catalytic Activity , 2018 .

[42]  G. Lu,et al.  Ammonia borane confined by a metal-organic framework for chemical hydrogen storage: enhancing kinetics and eliminating ammonia. , 2010, Journal of the American Chemical Society.

[43]  Qiang Xu,et al.  Immobilizing highly catalytically active noble metal nanoparticles on reduced graphene oxide: a non-noble metal sacrificial approach. , 2015, Journal of the American Chemical Society.

[44]  Qiang Xu,et al.  Complete conversion of hydrous hydrazine to hydrogen at room temperature for chemical hydrogen storage. , 2009, Journal of the American Chemical Society.

[45]  Qiang Xu,et al.  Dehydrogenation of Ammonia Borane by Metal Nanoparticle Catalysts , 2016 .

[46]  T. Akita,et al.  A one-pot protocol for synthesis of non-noble metal-based core-shell nanoparticles under ambient conditions: toward highly active and cost-effective catalysts for hydrolytic dehydrogenation of NH3BH3. , 2011, Chemical communications.

[47]  Xin-bo Zhang,et al.  Bimetallic Au-Ni nanoparticles embedded in SiO2 nanospheres: synergetic catalysis in hydrolytic dehydrogenation of ammonia borane. , 2010, Chemistry.

[48]  Qiang Xu,et al.  Immobilization of Ultrafine Metal Nanoparticles to High-Surface-Area Materials and Their Catalytic Applications , 2016 .

[49]  Qiang Xu,et al.  Metal-Organic Frameworks for Energy Applications , 2017 .

[50]  Xin-bo Zhang,et al.  Preparation and catalysis of poly(N-vinyl-2-pyrrolidone) (PVP) stabilized nickel catalyst for hydrolytic dehydrogenation of ammonia borane , 2009 .

[51]  Qiang Xu,et al.  Effect of l-arginine on the catalytic activity and stability of nickel nanoparticles for hydrolytic dehydrogenation of ammonia borane , 2012 .

[52]  Qiang Xu,et al.  Porous metal-organic frameworks as platforms for functional applications. , 2011, Chemical communications.

[53]  A. Singh,et al.  Palladium silica nanosphere-catalyzed decomposition of formic acid for chemical hydrogen storage , 2012 .

[54]  T. Yonezawa,et al.  Structural analysis of polymer-protected palladium/platinum bimetallic clusters as dispersed catalysts by using extended x-ray absorption fine structure spectroscopy , 1991 .

[55]  Qiang Xu,et al.  Immobilizing highly catalytically active Pt nanoparticles inside the pores of metal-organic framework: a double solvents approach. , 2012, Journal of the American Chemical Society.

[56]  Qiang Xu,et al.  ZIF-8 immobilized nickel nanoparticles: highly effective catalysts for hydrogen generation from hydrolysis of ammonia borane. , 2012, Chemical communications.

[57]  Qiang Xu,et al.  Immobilizing metal nanoparticles to metal-organic frameworks with size and location control for optimizing catalytic performance. , 2013, Journal of the American Chemical Society.

[58]  A. Züttel,et al.  Hydrogen-storage materials for mobile applications , 2001, Nature.

[59]  Y. Himeda,et al.  Development of an Iridium‐Based Catalyst for High‐Pressure Evolution of Hydrogen from Formic Acid , 2016, ChemSusChem.

[60]  T. Akita,et al.  Strong metal–molecular support interaction (SMMSI): Amine-functionalized gold nanoparticles encapsulated in silica nanospheres highly active for catalytic decomposition of formic acid , 2012 .

[61]  Qiang Xu,et al.  Recent progress in synergistic catalysis over heterometallic nanoparticles , 2011 .

[62]  T. Akita,et al.  Toward Homogenization of Heterogeneous Metal Nanoparticle Catalysts with Enhanced Catalytic Performance: Soluble Porous Organic Cage as a Stabilizer and Homogenizer. , 2015, Journal of the American Chemical Society.

[63]  T. Akita,et al.  Synergistic catalysis of metal-organic framework-immobilized Au-Pd nanoparticles in dehydrogenation of formic acid for chemical hydrogen storage. , 2011, Journal of the American Chemical Society.

[64]  Tomoki Akita,et al.  One-step seeding growth of magnetically recyclable Au@Co core-shell nanoparticles: highly efficient catalyst for hydrolytic dehydrogenation of ammonia borane. , 2010, Journal of the American Chemical Society.

[65]  H. Pang,et al.  Encapsulating highly catalytically active metal nanoclusters inside porous organic cages , 2018, Nature Catalysis.

[66]  A. Singh,et al.  Noble-metal-free bimetallic nanoparticle-catalyzed selective hydrogen generation from hydrous hydrazine for chemical hydrogen storage. , 2011, Journal of the American Chemical Society.

[67]  Qiang Xu,et al.  Room temperature hydrogen generation from aqueous ammonia-borane using noble metal nano-clusters as highly active catalysts , 2007 .

[68]  A. Singh,et al.  Temperature-induced selectivity enhancement in hydrogen generation from Rh–Ni nanoparticle-catalyzed decomposition of hydrous hydrazine , 2012 .

[69]  Qiang Xu,et al.  Synthesis of Highly Active Sub-Nanometer Pt@Rh Core-Shell Nanocatalyst via a Photochemical Route: Porous Titania Nanoplates as a Superior Photoactive Support. , 2017, Small.

[70]  Qiang Xu,et al.  Dendrimer‐Encapsulated Cobalt Nanoparticles as High‐Performance Catalysts for the Hydrolysis of Ammonia Borane , 2014 .

[71]  Etsuko Fujita,et al.  Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures , 2012, Nature Chemistry.

[72]  Rosario Miceli,et al.  Perspective on hydrogen energy carrier and its automotive applications , 2014 .

[73]  Qiang Xu,et al.  A portable hydrogen generation system : Catalytic hydrolysis of ammonia-borane , 2007 .

[74]  Feng Tao,et al.  Reaction-Driven Restructuring of Rh-Pd and Pt-Pd Core-Shell Nanoparticles , 2008, Science.

[75]  Qiang Xu,et al.  Temperature-Induced Enhancement of Catalytic Performance in Selective Hydrogen Generation from Hydrous Hydrazine with Ni-Based Nanocatalysts for Chemical Hydrogen Storage , 2011 .

[76]  T. Akita,et al.  One-step synthesis of magnetically recyclable Au/Co/Fe triple-layered core-shell nanoparticles as highly efficient catalysts for the hydrolytic dehydrogenation of ammonia borane , 2011 .

[77]  Xin-bo Zhang,et al.  Room-temperature hydrogen generation from hydrous hydrazine for chemical hydrogen storage. , 2009, Journal of the American Chemical Society.

[78]  E. Bielinski,et al.  Lewis acid-assisted formic acid dehydrogenation using a pincer-supported iron catalyst. , 2014, Journal of the American Chemical Society.

[79]  P. Dyson,et al.  Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media , 2014, Nature Communications.

[80]  Qiang Xu,et al.  Bimetallic nickel-iridium nanocatalysts for hydrogen generation by decomposition of hydrous hydrazine. , 2010, Chemical communications.

[81]  Qiang Xu,et al.  Highly active AuCo alloy nanoparticles encapsulated in the pores of metal-organic frameworks for hydrolytic dehydrogenation of ammonia borane. , 2014, Chemical communications.

[82]  Qiang Xu,et al.  Metal-Nanoparticle-Catalyzed Hydrogen Generation from Formic Acid. , 2017, Accounts of chemical research.

[83]  Qiang Xu,et al.  Catalytic activities of non-noble metals for hydrogen generation from aqueous ammonia-borane at room temperature , 2006 .

[84]  Qiang Xu,et al.  Bimetallic Ni-Pt nanocatalysts for selective decomposition of hydrazine in aqueous solution to hydrogen at room temperature for chemical hydrogen storage. , 2010, Inorganic Chemistry.

[85]  Qiang Xu,et al.  Synergistic Catalysis over Bimetallic Alloy Nanoparticles , 2013 .

[86]  Qiang Xu,et al.  Synergistic catalysis of Au-Co@SiO2 nanospheres in hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage , 2012 .